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Stabilization of [2.2]paracyclophane anion as a result of transannular interaction

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Abstract

Topological analysis of the electron density distribution in the [2.2]paracyclophane radical anion and radical cation based on the results of B3PW91/6-31+G(d) calculations revealed that reduction of the electron affinity energy down to –0.5 eV (more than a twofold decrease compared to benzene) is a result of transannular interaction between the benzene rings.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation, Russia

    I. V. Fedyanin, K. A. Lyssenko, Z. A. Starikova & M. Yu. Antipin

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  1. I. V. Fedyanin
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  2. K. A. Lyssenko
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  3. Z. A. Starikova
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  4. M. Yu. Antipin
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Fedyanin, I.V., Lyssenko, K.A., Starikova, Z.A. et al. Stabilization of [2.2]paracyclophane anion as a result of transannular interaction. Russian Chemical Bulletin 53, 1153–1158 (2004). https://doi.org/10.1023/B:RUCB.0000042267.48995.77

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  • DOI: https://doi.org/10.1023/B:RUCB.0000042267.48995.77

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