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Crystal structure of bis(2,3,5-trimethylpyridine N-oxide) 2,4,6-trinitrophenolate: Cation complex tied by the extremely strong OHO hydrogen bonding

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Abstract

The salt of bis(2,3,5-trimethylpyridine N-oxide) 2,4,6-trinitrophenolate, C22H25N5O9, crystallizes in monoclinic space group C2/c with a=12.411(2)Å, b=15.326(3)Å, c=13.559(3)Å, β=113.13(1)°, V=2371.8(8)Å3, Z=4, D c=1.410 mg/m3, F(000)=1056. The molecule of 2,3,5-trimethylpyridine N-oxide is protonated. Two pyridine N-oxide molecules are linked by extremely strong OHO hydrogen bonding (2.378(4)Å) to form a cation complex. CHO hydrogen bonding and π–π interactions also play important role in stablizing the structure of the salt.

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Authors and Affiliations

  1. College of Pharmaceutical Science, Zhejiang University of Technology, Hangzhou, 310014, Peoples Republic of China

    Zhi Min Jin, Zu Guang Li & Zai Su Jin

  2. Department of Chemistry, Zhejiang University, Hangzhou, Peoples Republic of China

    Xiao Feng Li & Mao Lin Hu

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  1. Zhi Min Jin
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  2. Zu Guang Li
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  3. Xiao Feng Li
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  4. Mao Lin Hu
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  5. Zai Su Jin
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Jin, Z.M., Li, Z.G., Li, X.F. et al. Crystal structure of bis(2,3,5-trimethylpyridine N-oxide) 2,4,6-trinitrophenolate: Cation complex tied by the extremely strong OHO hydrogen bonding. Journal of Chemical Crystallography 34, 653–655 (2004). https://doi.org/10.1023/B:JOCC.0000047637.06637.bb

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  • DOI: https://doi.org/10.1023/B:JOCC.0000047637.06637.bb

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