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Role of the Surface Acid–Base Properties of Silver Catalysts in the Partial Oxidation of Ethylene Glycol

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Abstract

The acid–base properties of a bulk silver catalyst and silver catalysts supported on various carriers for the partial oxidation of ethylene glycol were studied. A relationship between the catalytic activity and the concentration of surface acid sites in the catalysts was found. A mechanism was proposed for the participation of Lewis acid sites in the reaction of partial ethylene glycol oxidation to glyoxal.

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Authors and Affiliations

  1. Tomsk Polytechnical Institute, Tomsk, 634034, Russia

    G. A. Voronova

  2. Tomsk State University, Tomsk, 634050, Russia

    O. V. Vodyankina & V. N. Belousova

  3. Siberian Division, Russian Academy of Sciences, Institute of Petrochemistry, Tomsk, 634055, Russia

    E. V. Bezrukov & L. N. Kurina

  4. Tomsk State University, Tomsk, 634050, Russia

    L. N. Kurina

Authors
  1. G. A. Voronova
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  2. O. V. Vodyankina
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  3. V. N. Belousova
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  4. E. V. Bezrukov
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  5. L. N. Kurina
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Voronova, G.A., Vodyankina, O.V., Belousova, V.N. et al. Role of the Surface Acid–Base Properties of Silver Catalysts in the Partial Oxidation of Ethylene Glycol. Kinetics and Catalysis 44, 652–656 (2003). https://doi.org/10.1023/A:1026194006426

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  • DOI: https://doi.org/10.1023/A:1026194006426

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