Abstract
The effects of the pretreatments of Cu/ZnO-based catalysts prepared by a coprecipitation method on their activities for the water–gas shift reaction at 523K were investigated. The activity of a Cu/ZnO/ZrO2/Al2O3 catalyst for the water–gas shift reaction was less affected by calcination at temperatures ranging from 673-973K and by H2 treatment at 573 or 723K than that of a Cu/ZnO/Al2O3 catalyst. The catalyst activity could be correlated mainly to the Cu surface area of the catalyst.
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References
D. S. Newsome, Catal. Rev. Sci. Eng. 21 (1980) 275.
C. Rhodes, G. J. Hutchings and A. M. Ward, Catal. Today 23 (1995) 43.
M. J. Gines, N. Amadeo, M. Laborde and C. R. Apesteguia, Appl. Catal. A131 (1995) 283.
A. A. G. Lima, M. Nele, E. L. Moreno and H. M. C. Andrade, Appl. Catal., A171 (1998) 31.
J. R. Mellor, N. J. Coville, S. H. Durbach and R. G. Copperthwaite, Appl. Catal., A171 (1998) 273.
O. Hinrichsen, T. Genter and M. Muhler, in Studies in Surface Science and Catalysis, A. Corma, F. V. Melo, S. Mendioroz and J. L. G. Fierro (eds), Vol. 130D (Elsevier Science B.V., 2000) pp. 3825–3830.
J. Wu and M. Saito, J. Catal. 195 (2000) 420.
M. Saito, T. Fujitani, M. Takeuchi and T. Watanabe, Appl. Catal. A138 (1996) 311.
G. C. Chinchen, C. M. Hay, H. D. Vandervell and K. C. Waugh, J. Catal. 103 (1987) 79.
M. Saito, J. Wu, K. Tomoda, I. Takahara and K. Murata, Catal. Lett. 83 (2002) 1.
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Saito, M., Tomoda, K., Takahara, I. et al. Effects of Pretreatments of Cu/ZnO-Based Catalysts on Their Activities for the Water–Gas Shift Reaction. Catalysis Letters 89, 11–13 (2003). https://doi.org/10.1023/A:1024792014792
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DOI: https://doi.org/10.1023/A:1024792014792