Skip to main content
Log in

Evaluation of Cogeneration Potential for a Sulphuric Acid Recovery (SAR) Plant

  • Short Technical Note
  • Published:
Process Integration and Optimization for Sustainability Aims and scope Submit manuscript

Abstract

Utilisation of excess high-grade heat is useful in creating value-added opportunities in a process. In this technical note, cogeneration of steam and power through combined heat and power (CHP) scheme was evaluated for a sulphur acid recovery (SAR) plant based in the UK. The evaluation was performed using a recently established automated targeting model (ATM). Due to inconsistent feed stream condition, the establishment of relationship between the economic feature and the feed stream concentration is essential in assisting the plant authority in understanding the overall performance of the CHP scheme in the SAR plant.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

References

  • Bandyopadhyay S, Varghese J, Bansal V (2010) Targeting for cogeneration potential through total site integration. Appl Therm Eng 30:6–14

    Article  Google Scholar 

  • Chen C-L, Lin C-Y (2011) Design and optimization of steam distribution systems for steam power plants. Ind Eng Chem Res 50(13):8097–8109

    Article  Google Scholar 

  • Dhole VR, Linnhoff B (1993) Total site targets for fuel, co-generation, emissions, and cooling. Comput Chem Eng 17:S101–S109

    Article  Google Scholar 

  • Diban P, Foo DCY (2018) A pinch-based automated targeting technique for heating medium system. ENERGY 166:193–212. https://doi.org/10.1016/j.energy.2018.09.100

    Article  Google Scholar 

  • El-Halwagi MM, Foo DCY (2014) Process synthesis and integration. In Seidel A, Bickford M (Ed.) Kirk-Othmer Encyclopedia of Chemical Technology. John Wiley & Sons

  • El-Halwagi M, Harell D, Spriggs HD (2009) Targeting cogeneration and waste utilization through process integration. Appl Energy 86:880–887

    Article  Google Scholar 

  • El-Halwagi MM, Manousiouthakis V (1990) Automatic synthesis of mass-exchange networks with single component targets. Chem Eng Sci 9:2813–2831 45

    Article  Google Scholar 

  • Ganapathy V (1996) Heat-recovery steam generators: understand the basics. Chemical Engineering Progress 92(8):32–45

  • Ghannadzadeh A, Perry S, Smith R (2012) Cogeneration targeting for site utility systems. Appl Therm Eng 43:60–66

    Article  Google Scholar 

  • Klemeš J, Dhole VR, Raissi K, Perry SJ, Puigjaner L (1997) Targeting and design methodology for reduction of fuel, power and CO2 on total sites. Appl Therm Eng 17:993–1003

    Article  Google Scholar 

  • Liew PY, Theo WL, Wan Alwi SR, Lim JS, Abdul Manan Z, Klemeš JJ, Varbanov PS (2017) Total site heat integration planning and design for industrial, urban and renewable systems. Renew Sust Energ Rev 68:964–985

    Article  Google Scholar 

  • Linnhoff B, Flower JR (1978a) Synthesis of heat exchanger networks: I. Systematic generation of energy optimal networks. AICHE J 24:633–642

    Article  Google Scholar 

  • Linnhoff B, Flower JR (1978b) Synthesis of heat exchanger networks: synthesis of heat exchanger networks: II. Evolutionary generation of networks with various criteria of optimality. AICHE J 24:642–654

    Article  Google Scholar 

  • Mohan T, El-Halwagi MM (2007) An algebraic targeting approach for effective utilization of biomass in combined heat and power systems through process integration. Clean Techn Environ Policy 9:13–25

    Article  Google Scholar 

  • Ng DKS, Foo DCY, Tan RR (2009a) Automated targeting technique for single-component resource conservation networks—part 1: direct reuse/recycle. Ind Eng Chem Res 48(16):7637–7646

    Article  Google Scholar 

  • Ng DKS, Foo DCY, Tan RR (2009b) Automated targeting technique for single-component resource conservation networks—part 2: single pass and partitioning waste interception systems. Ind Eng Chem Res 48(16):7647–7661

    Article  Google Scholar 

  • Ng RTL, Loo JSW, Ng DKS, Foo DCY, Kim J-K, Tan RR (2017) Targeting for cogeneration potential and steam allocation for steam distribution network. Appl Therm Eng 113:1610–1621

    Article  Google Scholar 

  • Smith, R. (2016). Chemical process design and integration (2nd Ed.). West Sussex: John Wiley

  • Sun L, Doyle S, Smith R (2014) Graphical cogeneration analysis for site utility systems. Clean Techn Environ Policy 16:1235–1243

    Article  Google Scholar 

  • Umeda T, Itoh J, Shiroko K (1978) Heat exchanger system synthesis. Chem Eng Prog 74(July):70

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Dominic C. Y. Foo.

Ethics declarations

Conflict of Interest

The authors declare that they have no conflict of interest.

Appendix – Data for heat integration studies

Appendix – Data for heat integration studies

Data to perform heat integration for the SAR plant are given in Tables 5, 6, 7 and 8.

Table 5 Data for Scenario 1: 63 wt% sulphur content
Table 6 Data for Scenario 2: 65 wt% sulphur content
Table 7 Data for Scenario 3: 67 wt% sulphur content
Table 8 Data for Scenario 4: 69 wt% sulphur content

To calculate the flow rate of VHPS produced from excess heat in the HRSG, \( \dot{m} \) (kg/h), Eq. 10 is used. The HRSG is assumed to have an efficiency, ηHRSG of 85% (Ganapathy 1996).

$$ \dot{m}=\frac{\eta_{HRSG}\ \Delta {H}_{excess}}{H_{VHPS}\ } $$
(10)

where ∆Hexcess is the excess heat (kJ/h), and specific enthalpy of VHPS, HVHPS = 2989.35 kJ/kg (assuming superheated steam is produced at T = 340 °C and P = 80 bar(a)).

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Yeo, Z.M., Foo, D.C.Y. Evaluation of Cogeneration Potential for a Sulphuric Acid Recovery (SAR) Plant. Process Integr Optim Sustain 3, 413–421 (2019). https://doi.org/10.1007/s41660-018-0072-z

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s41660-018-0072-z

Keywords

Navigation