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Study on Agglomeration Conditions and Reactivity of Carbon–Silicon Composite Agglomerate

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Abstract

In this paper, the wasted quartz and coal waste fines were made into carbon–silicon composite agglomerates. The effect of particle size for raw material, moisture content, molding pressure, and curing time on the strength and reactivity of carbon–silicon composites agglomerates at high temperature were studied. From the experimental results, it can be seen that the proper molding pressure, moisture, curing time, and the smaller particle size of the raw material can significantly increase agglomerates strength. For the raw material with particle size of 75 μm, the moisture content is 8 wt%, the molding pressure is 320 MPa, the cold strength of the agglomerate can be 30.7 MPa, and the hot strength is 12.6 MPa with crushing strength rate and the powdering rate of 97.02% and 0.52%, respectively. It is observed that the strength of the carbon–silicon composite agglomerate tends to be stabilized when the curing time reaches 30 days. The high-temperature reactivity study of carbon–silicon composite agglomerate shows that after the chemical reaction, the main component of the agglomerate is β-SiC. The adequate carbon type and carbon content will reduce the gas loss of SiO2 from the agglomerate. It is possible that the reaction rate in the agglomerate is improved by using composite bonding.

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References

  1. Martynov SA, Bazhin VY (2019) Improving the control efficiency of metallurgical silicon production technology. J Phys: Conf Ser 1399(4):044040. https://doi.org/10.1088/1742-6596/1399/4/044040

    Article  CAS  Google Scholar 

  2. Siddique R, Chahal N (2011) Use of silicon and ferrosilicon industry by-products (silica fume) in cement paste and mortar. Resour Conserv Recy 55(8):739–744. https://doi.org/10.1016/j.resconrec.2011.03.004

    Article  Google Scholar 

  3. Kondratiev VV, Karlina AI, Guseva EA, Konstantinova MV, Kleshnin AA (2018) Processing and application of ultra disperse wastes of silicon production in construction. IOP Conf: Mater Sci Eng 463(3):032048. https://doi.org/10.1088/1757-899X/463/3/032068

    Article  Google Scholar 

  4. Schei A, Tuseth JK, Tveit H (1998) Production of high silicon alloys. Tapir Forlag, Trondheim

    Google Scholar 

  5. Agarwal A, Pad U (1999) Influence of pellet composition and structure on carbothermic reduction of silica. Metall Mater Trans B 30:295–306. https://doi.org/10.1007/s11663-999-0059-9

    Article  Google Scholar 

  6. Li F, Tangstad M (2017) Carbothermal reduction of quartz with carbon from natural gas. Metall Mater Trans B 48(2):853–869. https://doi.org/10.1007/s11663-016-0887-3

    Article  CAS  Google Scholar 

  7. Li F, Tangstad M (2018) Kinetic modelling of the reaction rate for quartz and carbon pellet. Metall Mater Trans B 49:1101–1108. https://doi.org/10.1007/s11663-018-1203-1

    Article  CAS  Google Scholar 

  8. El-Hussiny NA, Shalabi ME (2011) A self-reduced intermediate product from iron and steel plants waste materials using a briquetting process. Powder Technol 205(1–3):217–223. https://doi.org/10.1016/j.powtec.2010.09.017

    Article  CAS  Google Scholar 

  9. Yang YB, Zhong Q, Li Q, Jiang T, Ge J (2014) Technology of cold briquetting with powdery material of silicon smelting. Min Metall Engi 34 (2):87–90. https://kns.cnki.net/kcms/detail/detail.aspx?FileName=KYGC201402026&DbName=CJFQ2014.

  10. Lohmeier L, Thaler C, Harrisx C, Wollenberg R, Schröder HW (2020) Briquetting of fine-grained residues from iron and steel production using organic and inorganic binders. Steel Res Int 91:2000238. https://doi.org/10.1002/srin.202000238

    Article  CAS  Google Scholar 

  11. Yang N, Yu XH, Xie G (2015) Study on preparation of carbonaceous pelletizing in industrial silicon production. Adv Mater Res 1094:82–85. https://doi.org/10.4028/www.scientific.net/AMR.1094.82

    Article  Google Scholar 

  12. Riva L, Nielsen HK, Skreiberg Ø, Wang L, Bartocci P, Barbanera M, Bidini G, Fantozzi F (2019) Analysis of optimal temperature, pressure and binder quantity for the production of biocarbon pellet to be used as a substitute for coke. Appl Energ 256(3):113933. https://doi.org/10.1016/j.apenergy.2019.113933

    Article  CAS  Google Scholar 

  13. National Technical Committee for Steel Standardization (2009) Coke for metallurgy-determination of mechanical strength GB/T 2006–2008. China Standard Press, Beijing

    Google Scholar 

  14. Former Institute of Information Standards of the Ministry of Metallurgical Industry (2009) Coke-determination of shatter strength GB/T 4511.2–1999. China Standards Press, Beijing

    Google Scholar 

  15. Shaibani M, Eshraghi N, Ghambari M (2013) Sintering of grey cast iron powder recycled via jet milling. Mater Des 47:174–178. https://doi.org/10.1016/J.MATDES.2012.11.058

    Article  Google Scholar 

  16. Huang C, Dai X, Shi C, Shi L (2021) A comprehensive experimental study on immiscible displacements in porous media: effects of capillary forces, viscous forces, wettability and pore geometries. J Therm Sci 30:1–13. https://doi.org/10.1007/S11630-021-1424-5

    Article  Google Scholar 

  17. Jovanovic V, Knežević DN, Sekulić Ž, Kragović M, Stojanović JN, Mihajlović S, Nišić D, Radulovic D, Petrov M (2017) Effects of bentonite binder dosage on the properties of green limestone pellets. Hem Ind 71(00):135–144. https://doi.org/10.2298/HEMIND160210023J

    Article  Google Scholar 

  18. Zhang H, Liu C, Lu M, Yu H (2021) Kinetic model research on drying characteristics of artificial magnetite green pellet. J Cent South Univ 28:89–99. https://doi.org/10.1007/s11771-021-4588-y

    Article  Google Scholar 

  19. Ramos DC, Carneiro AD, Tangstad M, Pereira BL, Saadieh R, Oliveira AC, Vital BR (2021) Reactivity assessment of charcoal for use in silicon production. Eur J Wood Wood Prod 79:537. https://doi.org/10.1007/S00a107-021-01683-5

    Article  CAS  Google Scholar 

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Funding

This work was supported by the [National Science Foundation of China #1] under Grant [No. 51904140], [National Science Foundation of Gansu province China #2] under Grant [No. 20JR10RA176], and [Hongliu Outstanding Young Talent Support Program from Lanzhou University of Technology #3].

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Correspondence to Fei Li.

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The contributing editor for this article was Veena Sahajwalla.

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Li, F., Sun, Z. & Yan, F. Study on Agglomeration Conditions and Reactivity of Carbon–Silicon Composite Agglomerate. J. Sustain. Metall. 8, 1831–1840 (2022). https://doi.org/10.1007/s40831-022-00608-7

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  • DOI: https://doi.org/10.1007/s40831-022-00608-7

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