Skip to main content
Log in

Chemical Modification and Tribological Evaluation of Pure Rice Bran Oil as Base Stocks for Biodegradable Lubricants

  • Original Contribution
  • Published:
Journal of The Institution of Engineers (India): Series E Aims and scope Submit manuscript

Abstract

Vegetable oils act as a potential base stock for biodegradable lubricants. They possess better biodegradability, high flash point, high viscosity index and excellent lubrication properties. They also have some limitations like low thermal and oxidation stability, poor low-temperature properties and narrow range of viscosities. These limitations can be easily altered by chemically modifying vegetable oils or by using additives into these oils. This research work focused on the chemical modification of pure rice bran oil by epoxidation process. The epoxidized product of rice bran oil was then subjected to ring-opening process using different acids such as butanoic acid, benzoic acid and lauric acid. The tribological properties, flash temperature parameter and energy consumption in a four-ball tester for pure rice bran oil (RBO), epoxidized and ring-opened products of RBO were studied. It was noted that the evaluated properties of chemically modified products of RBO were better compared to pure RBO.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. S.S. Nair, K.P. Nair, P.K. Rajendrakumar, Evaluation of physicochemical, thermal and tribological properties of sesame oil (Sesamum indicum L.): a potential agricultural crop base stock for eco-friendly industrial lubricants. Int. J. Agric. Resour. Gov. Ecol. 13(1), 77–90 (2017)

    Google Scholar 

  2. S. Rani, M.L. Joy, K. Prabhakaran Nair, Evaluation of physiochemical and tribological properties of rice bran oil—biodegradable and potential base stoke for industrial lubricants. Ind. Crops Prod. 65, 328–333 (2015)

    Article  Google Scholar 

  3. L.R. Rudnick, Synthetics, Mineral Oils, and Bio-based Lubricants”, Chemistry and Technology, 2nd edn. (CRC Press, Boca Raton, 2013)

    Book  Google Scholar 

  4. N.J. Fox, G.W. Stachowiak, Vegetable oil-based lubricants—a review of oxidation. Tribol. Int. 40, 1035–1046 (2007)

    Article  Google Scholar 

  5. S. Asadauskas, J.M. Perez, J.L. Duda, Oxidative stability and anti-wear properties of high oleic vegetable oils. Lubr. Eng. 52, 877–882 (1996)

    Google Scholar 

  6. N.H. Jayadas, K.P. Nair, Coconut oil as base oil for industrial lubricants—evaluation and modification of thermal, oxidative and low temperature properties. Tribol. Int. 39, 873–878 (2006)

    Article  Google Scholar 

  7. A. Adhvaryu, Z. Liu, S.Z. Erhan, Synthesis of novel alkoxylated triacylglycerols and their lubricant base oil properties. Ind. Crops Prod. 21, 113–119 (2005)

    Article  Google Scholar 

  8. R. Sirsam, D. Hansora, G.A. Usmani, A mini-review on solid acid catalyst for esterification reactions. J. Inst. Eng. India Ser. E (2016). https://doi.org/10.1007/s40034-016-0078-4

    Article  Google Scholar 

  9. S. Niju, M. Kirthikaa, S. Arrthi, P. Dharani, S. Ramya, M. Balajii, Fish-bone-doped sea shell for biodiesel production from waste cooking oil. J. Inst. Eng. India Ser. E (2019). https://doi.org/10.1007/s40034-019-00154-0

    Article  Google Scholar 

  10. X. Hang, H. Yang, Model for a cascade continuous epoxidation process. J. Am. Oil Chem. Soc. 76, 89–92 (1999)

    Article  Google Scholar 

  11. A. Adhvaryu, S.Z. Erhan, Epoxidized soybean oil as a potential source of high-temperature lubricants. Ind. Crops Prod. 15, 247–254 (2002)

    Article  Google Scholar 

  12. W. Xuedong, X. Zhang, S. Yang, H. Chen, D. Wang, The study of epoxidized rapeseed oil used as a potential biodegradable lubricant. JAOCS 77, 561–563 (2000)

    Article  Google Scholar 

  13. S. Arumugam, G. Sriram, L. Subadhra, Synthesis, chemical modification and tribological evaluation of plant oil as bio-degradable low temperature lubricant. Procedia Eng. 38, 1508–1517 (2012)

    Article  Google Scholar 

  14. P.G. Nihul, S.T. Mhaske, V.V. Shertukde, Epoxidized rice bran oil (ERBO) as a plasticizer for poly (vinyl chloride) (PVC). Iran. Polym. J. 23, 599–608 (2014)

    Article  Google Scholar 

  15. V.B. Borugadda, V.V. Goud, Response surface methodology for optimization of bio- lubricant basestock synthesis from high free fatty acids castor oil. Energy Sci Eng 3(4), 371–383 (2015)

    Article  Google Scholar 

  16. A. Campanella, E. Rustoy et al., Lubricants from chemically modified vegetable oils. Biores. Technol. 101, 245–254 (2010)

    Article  Google Scholar 

  17. N.A. Zainal, N.W.M. Zulkifli, M. Gulzar, H.H. Masjuki, A review on the chemistry, production, and technological potential of bio based Lubricants. Renew. Sustain. Energy Rev. 82, 80–102 (2018)

    Article  Google Scholar 

  18. M.M. Rahman, M. Rasul, N.M. Sayeed Hassan, Study on the tribological characteristics of Australian native first generation and second generation biodiesel fuel. Energies 10, 55 (2017). https://doi.org/10.3390/en10010055

    Article  Google Scholar 

  19. Y. Singh, Tribological behavior as lubricant additive and physicochemical characterization of jatropha oil blends. Friction 3(4), 320–332 (2015)

    Article  Google Scholar 

  20. E. Sneha, S. Rani, M. Arif, Evaluation of lubricant properties of vegetable oils as base oil for industrial lubricant. IOP Conf. Ser. Mater. Sci. Eng. 624, 012022 (2019)

    Article  Google Scholar 

Download references

Acknowledgements

The authors would like to sincerely acknowledge the financial assistance from Kerala State Council for Science, Technology and Environment [KSCSTE] for carrying out the research work. The author would also like to acknowledge CERD of A.P.J. Abdul Kalam Technological University, Tvpm, Kerala, for providing Ph.D fellowship.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to S. Rani.

Ethics declarations

Conflict of interest

The author(s) declared no potential conflicts of interest with respect to the research, authorship and/or publication of this article.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Thampi, A.D., John, A.R., Rani, S. et al. Chemical Modification and Tribological Evaluation of Pure Rice Bran Oil as Base Stocks for Biodegradable Lubricants. J. Inst. Eng. India Ser. E 102, 11–16 (2021). https://doi.org/10.1007/s40034-020-00174-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s40034-020-00174-1

Keywords

Navigation