Abstract
In this article, we first introduce and discuss the fundamental science of carbon nanomaterials (especially nanotubes and graphene) and the different technological applications from using these materials. We then discuss the first works of Brazilians scientists, done in collaboration with scientists of other countries and, in particular, the role of Prof. M. S. Dresselhaus from MIT, US, in the development of the nanocarbon science in Brazil. We briefly discuss some experimental and theoretical works about nanotubes and graphene done in Brazil in the late 1990s and early 2000s, and the formation of the first Brazilian network on carbon nanotubes in 2005. We present the activities of the National Institute of Science and Technology (INCT) in Carbon Nanomaterials (CN) created in 2009. A scientometric analysis is used to describe the INCT-CN network formation. Finally, we present the Center of Technology in Nanomaterials (CTNano) installed at UFMG, where pilot plants were developed to produce graphene and nanotubes at large scales, and the work being done at the center in collaboration with companies aiming to solve specific technological problems and to create bridges between the academic and the industrial sectors.
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References
S. Iijima, Helical microtubules of graphitic carbon. Nature 354, 56–58 (1991)
K.S. Novoselov, A.K. Geim, S.V. Morozov, D. Jiang, Y. Zhang, S.V. Dubonos, I.V. Grigorieva, A.A. Firsov, Electric field effect in atomically thin carbon films. Science 306, 666–669 (2004)
A.K. Geim, K.S. Novoselov, The rise of graphene. Nat. Mater. 6, 183–191 (2007)
R. Saito, G. Dresselhaus, M.S. Dresselhaus, Physical properties of carbon nanotubes, 1st edn. (Imperial College Press, London, 1998), p. 259
P. Ludvig, J.M. Calixto, L.O. Ladeira, I.C.P. Gaspar, Using converter dust to produce low cost cementitious composites by in situ carbon nanotube and nanofiber synthesis. Materials 4, 575–584 (2011)
W.A. de Heer, A. Châtelain, D. Ugarte, A carbon nanotube field-emission electron source. Science 270, 1179–1180 (1995)
W.A. de Heer, J. Bonard, K. Fauth, A. Chatelain, L. Forro, D. Ugarte, Electron field emitters based on carbon nanotube films. Adv. Mater. 9, 87–89 (1997)
D. Ugarte, A. Châtelain, W.A. de Heer, Nanocapillarity and chemistry in carbon nanotubes. Science 274, 1897–1899 (1996)
P. Poncharal, Z.L. Wang, D. Ugarte, W.A. de Heer, Electrostatic deflections and electromechanical resonances of carbon nanotubes. Science 283, 1513–1516 (1999)
M.A. Pimenta, A. Marucci, S.D.M. Brown, M.J. Matthews, A.M. Rao, P.C. Eklund, R.E. Smalley, G. Dresselhaus, M.S. Dresselhaus, Resonant Raman effect in single-wall carbon nanotubes, J. Mater. Res. 13, 2396 (1998)
M.A. Pimenta, A. Marucci, S. Empedocles, M. Bawendi, E.B. Hanlon, A.M. Rao, P.C. Eklund, R.E. Smalley, G. Dresselhaus, M.S. Dresselhaus, Raman modes of metallic carbon nanotubes. Phys. Rev. B Condens. Matter 58, R16016–R16019 (1998)
M.J. Matthews, M.A. Pimenta, G. Dresselhaus, M.S. Dresselhaus, M. Endo, Origin of dispersive effect of the Raman D-band in carbon materials, Phys. Rev. B Condens. Matter 59, R6585 (1999)
P. Corio, S.D.M. Brown, A. Marucci, M.A. Pimenta, K. Kneipp, G. Dresselhaus, M.S. Dresselhaus, Surface-enhanced resonant Raman spectroscopy of single-wall carbon nanotubes adsorbed on silver and gold surfaces. Phys. Rev. B Condens. Matter 61, 13202–13211 (2000)
A. Jorio, R. Saito, J.H. Hafner, C.M. Lieber, M. Hunter, T. McClure, G. Dresselhaus, M.S. Dresselhaus, Structural (n,m) determination of isolated single-wall carbon nanotubes by resonant raman scattering. Phys. Rev. Lett. 86, 1118–1121 (2001)
A.G. Souza Filho, A. Jorio, A.K. Swan, M.S. Ünlü, B.B. Goldberg, R. Saito, J.H. Hafner, C.M. Lieber, M.A. Pimenta, G. Dresselhaus, M.S. Dresselhaus, Electronic transition energyEiifor an isolated(n,m)single-wall carbon nanotube obtained by anti-Stokes/Stokes resonant Raman intensity ratio. Phys. Rev. B: Condens. Matter 63, 241404 (2001)
M. Zheng, A. Jagota, M.S. Strano, A.P. Santos, P. Barone, S.G. Chou, B.A. Diner, M.S. Dresselhaus, R.S. McLean, G.B. Onoa, G.G. Samsonidze, E.D. Semke, M. Usrey, D.J. Walls, Structure-based carbon nanotube sorting by sequence-dependent DNA assembly. Science 302, 1545–1548 (2003)
A.M. Rao, M.A. Pimenta, A. Jorio, M.S.S. Dantas, R. Saito, G. Dresselhaus, M.S. Dresselhaus, Polarized Raman study of aligned multiwalled carbon nanotubes. Phys. Rev. Lett. 84(1820), 1820–1823 (2000)
C. Fantini, M.A. Pimenta, M.S.S. Dantas, D. Ugarte, A.M. Rao, A. Jorio, G. Dresselhaus, M.S. Dresselhaus, Micro-Raman investigation of aligned single-wall carbon nanotubes. Phys. Rev. B Rapid Comm. 63, 161405 (2001)
C. Fantini, A. Jorio, M. Souza, M.S. Strano, M.S. Dresselhaus, M.A. Pimenta, Optical transition energies for carbon nanotubes from resonant raman spectroscopy: environment and temperature effects. Phys. Rev. Lett. 93, 147406 (2004)
C. Fantini, A. Jorio, M. Souza, L.O. Ladeira, A.G. Souza Filho, R. Saito, G.G. Samsonidze, G. Dresselhaus, M.S. Dresselhaus, M.A. Pimenta, Phys. Rev. Lett. 93, 087401 (2004)
J.G. Huber, J.G.V. Romero, J.D. Spivey, C.A. Luengo, A bench arc-furnace facility for fullerene and single-wall nanotubes synthesis. Quím. Nova 24, 898–900 (2001)
D. Ugarte, M.C. Schnitzler, A.J. Zarbin, M.M. Oliveira, Chem. Phys. Lett. 381, 541 (2003)
A.G. Souza Filho, S.G. Chou, G.G. Samsonidze, G. Dresselhaus, M.S. Dresselhaus, L. An, J. Liu, A.K. Swan, M.S. Ünlü, B.B. Goldberg, A. Jorio, A. Grüneis, R. Saito, Stokes and anti-Stokes Raman spectra of small-diameter isolated carbon nanotubes. Phys. Rev. B 69(11), 115428 (2004)
M.S.C. Mazzoni, H. Chacham, P. Ordejon, D. Sanchez-Portal, J.M. Soler, E. Artacho, Phys. Rev. B Condens. Matter 60, 2208 (1999)
M.S.C. Mazzoni, H. Chacham, Atomic restructuring and localized electron states in a bent carbon nanotube: A first-principles study. Phys. Rev. B Condens. Matter 61, 7312–7315 (2000)
M.S.C. Mazzoni, H. Chacham, Bandgap closure of a flattened semiconductor carbon nanotube: a first-principles study. Appl. Phys. Lett. 76, 1561–1563 (2000)
S.B. Fagan, R. Mota, A.J.R. Da Silva, A. Fazzio, Substitutional Si doping in deformed carbon nanotubes. Nano Lett. 4, 975–977 (2004)
L.B. da Silva, S.B. Fagan, R. Mota, Ab initio study of deformed carbon nanotube sensors for carbon monoxide molecules. Nano Lett. 4, 65–67 (2004)
S.B. Fagan, R. Mota, A.J.R. da Silva, A. Fazzio, Phys. Rev. B Condens. Matter 2054141, 67 (2003)
S.B. Fagan, L.B. da Silva, R. Mota, Ab initio study of radial deformation plus vacancy on carbon nanotubes: energetics and electronic properties. Nano Lett. 3, 289–291 (2003)
R.J. Baierle, S.B. Fagan, R. Mota, A.J.R. da Silva, A. Fazzio, Phys. Rev. B Condens. Matter 64, 854131 (2001)
S.B. Fagan, R. Mota, R. Baierle, A.J.R. da Silva, A. Fazzio, Energetics and structural properties of adsorbed atoms and molecules on silicon-doped carbon nanotubes. Mater. Charact. 50, 183–187 (2003)
S.B. Fagan, R.J. Baierle, R. Mota, A.J.R. da Silva, A. Fazzio, Ab initiocalculations for a hypothetical material: silicon nanotubes. Phys. Rev. B Condens. Matter 61, 9994–9996 (2000)
R.J. Baierle, S.B. Fagan, R. Mota, A.J.R. da Silva, A. Fazzio, Phys. Rev. B Condens. Matter 8, 854131 (2001)
E.B. Barros, A.G.S. Filho, V. Lemos, S.B. Fagan, C.A. Luengo, J.G. Huber, Charge transfer effects in acid treated single-wall carbon nanotubes. Carbon 43, 2495–2500 (2005)
S.B. Fagan, A.G.S. Filho, J.M. Filho, P. Corio, M.S. Dresselhaus, Electronic properties of Ag- and CrO3-filled single-wall carbon nanotubes. Chem. Phys. Lett. 406, 54–59 (2005)
S.B. Fagan, A.G. Souza, J.O.G. Lima, J. Mendes, O.P. Ferreira, I.O. Mazali, O.L. Alves, M.S. Dresselhaus, 1,2-Dichlorobenzene interacting with carbon nanotubes. Nano Lett. 4, 1285–1288 (2004)
A.G. Souza Filho et al., Raman spectroscopy for probing chemically/physically induced phenomena in carbon nanotubes. Nanotechnology 14, 1130–1139 (2003)
D. Grimm, P. Venezuela, A. Latgé, Thermal and mechanical stability of Y-shaped carbon nanotubes. Phys. Rev. B Condens. Matter 71, 155425 (2005)
A. Latgé, D. Grimm, P. Venezuela, Y-shaped carbon nanotubes: structural stability and transport properties. J. Mol. Catal. A Chem. 228, 125–130 (2005)
P. Orellana, M.L. de Guevara, M. Pacheco, A. Latge, Phys. Rev. B 68, 53211 (2003)
C. Rocha, T. Dargam, A. Latgé, Phys. Rev. B 65, 5431 (2002)
P. Tangney, R.B. Capaz, C.D. Spataru, M.L. Cohen, S.G. Louie, Structural transformations of carbon nanotubes under hydrostatic pressure. Nano Lett. 5, 2268–2273 (2005)
R.B. Capaz, C.D. Spataru, P. Tangney, M.L. Cohen, S.G. Louie, Temperature dependence of the band gap of semiconducting carbon nanotubes. Phys. Rev. Lett. 94, 036801 (2005)
R.B. Capaz, C.D. Spataru, P. Tangney, M.L. Cohen, S.G. Louie, Hydrostatic pressure effects on the structural and electronic properties of carbon nanotubes. Phys. Status Solidi (B) 241, 3352–3359 (2004)
M. Verissimo-Alves, B. Koiller, H. Chacham, R.B. Capaz, Electromechanical effects in carbon nanotubes: ab initio and analytical tight-binding calculations. Phys. Rev. B Condens. Matter 67, 161401 (2003)
V.R. Coluci, S.B. Legoas, M.A.M. de Aguiar, D.S. Galvão, Chaotic signature in the motion of coupled carbon nanotube oscillators. Nanotechnology 16, 583–589 (2005)
K.S. Troche, V.R. Coluci, S.F. Braga, D.D. Chinellato, F. Sato, S.B. Legoas, R. Rurali, D.S. Galvao, Prediction of ordered phases of encapsulated C60, C70, and C78 inside carbon nanotubes. Nano Lett. 5, 349–355 (2005)
S.F. Braga, V.R. Coluci, S.B. Legoas, R. Giro, D.S. Galvao, R.H. Baughman, Structure and dynamics of carbon nanoscrolls. Nano Lett. 4, 881–884 (2004)
S.B. Legoas, V.R. Coluci, S.F. Braga, P.Z. Coura, S. Dantas, D.S. Galvao, Gigahertz nanomechanical oscillators based on carbon nanotubes. Nanotechnology 15, S184–S189 (2004)
V.R. Coluci, S.F. Braga, S.B. Legoas, D.S. Galvão, R.H. Baughman, New families of carbon nanotubes based on graphyne motifs. Nanotechnology 15, S142–S149 (2004)
S.B. Legoas, V.R. Coluci, S.F. Braga, P.Z. Coura, S.O. Dantas, D.S. Galvao, Molecular-dynamics simulations of carbon nanotubes as gigahertz oscillators. Phys. Rev. Lett. 90, 055504/1 (2003)
Y. Kopelevich, R.R. da Silva, J.H.S. Torres, S. Moehlecke, M.B. Maple, Phys. C: Supercond. 408, 77 (2004)
Y. Kopelevich, J.C.M. Pantoja, J.C. Medina, R.R. da Silva, F. Mrowka, P. Esquinazi, Anomalous Hall effect in graphite. Phys. Lett. A 355, 233–236 (2006)
L.G. Cançado, M.A. Pimenta, R. Saito, A. Jorio, L.O. Ladeira, A. Grueneis, A.G. Souza Filho, G. Dresselhaus, M.S. Dresselhaus, Stokes and anti-Stokes double resonance Raman scattering in two-dimensional graphite. Phys. Rev. B Condens. Matter 66, 035415 (2002)
L.G. Cançado, M.A. Pimenta, B.R.A. Neves, M.S.S. Dantas, A. Jorio, Influence of the atomic structure on the Raman spectra of graphite edges. Phys. Rev. Lett. 93, 247401 (2004)
L.G. Cançado, M.A. Pimenta, A. Jorio, B.R.A. Neves, G. Medeiros-Ribeiro, T. Enoki, Y. Kobayashi, K. Takai, K. Fukui, M.S. Dresselhaus, R. Saito, Phys. Rev. Lett. 93, 047403 (2004)
L.G. Cancado, K. Takai, T. Enoki, M. Endo, Y.A. Kim, H. Mizusaki, A. Jorio, L.N. Coelho, R. Magalhaes-Paniago, M.A. Pimenta, App. Phys. Lett. 88, 163106 (2006)
L.M. Malard, J. Nilsson, D.C. Elias, J.C. Brant, F. Plentz, E.S. Alves, A.H. Castro Neto, M.A. Pimenta, Probing the electronic structure of bilayer graphene by Raman scattering. Phys. Rev. B Condens. Matter 76, 201401 (2007)
L.M. Malard, M.A. Pimenta, G. Dresselhaus, M.S. Dresselhaus, Raman spectroscopy in graphene. Phys. Rep. 473(5–6), 51–87 (2009)
C. Chen, Information Visualization: Beyond the Horizon, 2d edn. (Springer, Berlin, 2004), p. 316
C. Chen, Searching for intellectual turning points: Progressive knowledge domain visualization. Proc. Natl. Acad. Sci. 101, 5303–5310 (2004)
C. Chen, CiteSpace II: detecting and visualizing emerging trends and transient patterns in scientific literature. J. Am. Soc. Inf. Sci. Technol. 57, 359–377 (2006)
Acknowledgments
Laura A. Geracitano is Postdoctoral Fellowship CAPES/BRASIL (88887.169785/2018-00).
Funding
This study is financially supported by the CNPq and FAPEMIG for the INCT in Carbon Nanomaterials.
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Pimenta, M.A., Geracitano, L.A. & Fagan, S.B. History and National Initiatives of Carbon Nanotube and Graphene Research in Brazil. Braz J Phys 49, 288–300 (2019). https://doi.org/10.1007/s13538-018-0618-0
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DOI: https://doi.org/10.1007/s13538-018-0618-0