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Where to go for the Development of High-Performance H2 Storage Materials at Ambient Conditions?

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A Correction to this article was published on 29 November 2022

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Abstract

Hydrogen is expected to overcome energy resource depletion because it is the most abundant element in the universe and because an ideal hydrogen energy cycle has the potential to exploit energy infinitely. Conventionally, hydrogen storage utilizes compression under high pressure (350–700 bar) into a tank and liquefaction in the cryotemperature regime (20 K). To mitigate the impractical operating conditions researchers have conducted adsorption-dependent research to increase the specific surface area (SSA) in physisorption and to decrease the H2 binding energy in chemisorption. Nevertheless, these strategies are still unlikely to reach the required the U.S. Department of Energy (DOE) targets. To this end, researchers have tried to find hydrogen storage material to fit the H2 binding energy between the physisorption region and chemisorption region. Previous governing parameters, the SSA, and the H2 binding energy show no correlation to gravimetric H2 storage capacity (GHSC). In addition, no correlation between the H2 densification index (HDI) and the H2 binding energy is found as well, which means the latter cannot describe the H2-adsorbent interaction thoroughly. The several notable findings presented here suggest that the development of high-performance H2 storage materials can be realized through the optimal modulation of an underlying parameter that dominates the H2-adsorbent interaction. This paper highlights the necessity of research on what the underlying parameter that dominates the H2-adsorbent interaction is and on how it affects GHSC to develop H2 storage materials that meet the DOE targets.

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Copyright 2012 ACS Publications), B Nanoscopic ligands btei (PCN-61), ntei (PCN-66), and ttei (PCN-610) (Reproduced with permission. Copyright 2010, Wiley–VCH [20])

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Copyright 2007 ACS publications

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Copyright 2011, ACS publications [78]. B Effect of the pore size on the GHSC per unit SSA. The general trend indicates that small pores are more efficient than large pores for a given SSA (Reprinted with permission from [83], Copyright 2005, American Chemical Society). C GHSC outcomes at 300 K and 100 bar for various types of porous carbon and MOFs plotted as a function of the SSA. The figure is reproduced with permission. Copyright 2012, ACS publications [19]

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Acknowledgements

This research was supported by the Creative Materials Discovery Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ICT (NRF-2017M3D1A1039377), and by the Hydrogen Energy Innovation Technology Development Business through NRF funded by the Ministry of Science and ICT (NRF-2019M3E6A1104147). The authors are thankful to The Research Institute of Energy and Resources, Seoul National University  and SNU Materials Education/Research Division for Creative Global Leaders. One of the authors (CRP) would like to thank full-heartedly and dedicate this paper to the Great Seon(Zen) Master Daehang Kunsunim who enlightened him the Hanmaum Science of the Principle of Tri-Angular Circle and the Law of Five Get-Togethers.

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  1. Carbon Nanomaterials Design Laboratory, Department of Materials Science and Engineering, Research Institute of Advanced Materials, Seoul National University, Seoul, 08826, Republic of Korea

    Soon Hyeong So & Chong Rae Park

  2. Division of Advanced Materials, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Yuseong-gu, Daejeon, 34114, Republic of Korea

    Sae Jin Sung

  3. Advanced Nanohybrids Laboratory, Department of Chemistry and Chemical Engineering, Education and Research Center for Smart Energy and Materials, Inha University, Incheon, 22212, Republic of Korea

    Seung Jae Yang

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So, S.H., Sung, S.J., Yang, S.J. et al. Where to go for the Development of High-Performance H2 Storage Materials at Ambient Conditions?. Electron. Mater. Lett. 19, 1–18 (2023). https://doi.org/10.1007/s13391-022-00368-2

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