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Metallo-Phthalocyanines Based Photocapacitors

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Abstract

The novel metallo-phthalocyanines (4–6) were obtained from the reactions of gereniol substituted phthalonitrile compound (3) with corresponding metal salts (Co (II), Cu (II) and Zn (II) acetates). The electrical and photoconductive properties of Al/p-Si/organic complex/Al devices with cobalt (4), copper (5) and zinc (6) phthalocyanines complexes containing geraniol as side groups were studied by using optoelectrical measurements at various sunlight intensites. The transient photocurrent and photocapacitance were measured as a function of time. Experimental results indicate that the prepared diodes exhibit both photodiode and photocapacitive behavior. Consequently, it is evaluated that the studied devices can be used as a photocapacitor in optical applications.

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Acknowledgements

Authors would like to acknowledge the support of the King Khalid University for this research through a grant RCAMS/KKU/007-18 under the (Research Center for Advanced Materials Science) at King Khalid University, Kingdom of Saudi Arabia. This study was also supported by Firat University Scientific Research Projects Unit under project No: FF.14.25.

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Authors and Affiliations

  1. Department of Physics, Faculty of Science, Gazi University, Ankara, Turkey

    A. Tataroglu

  2. Department of Chemistry, Faculty of Science, Firat University, Elazig, Turkey

    Kenan Koran & Ahmet Orhan Görgülü

  3. Department of Chemistry, Faculty of Science, Bingöl University, Bingöl, Turkey

    Eray Çaliskan

  4. Department of Chemistry, Faculty of Science, King Khalid University, P.O. Box 9004, Abha, 61413, Saudi Arabia

    Abdullah G. Al-Sehemi

  5. Research Center for Advanced Materials Science, King Khalid University, P.O. Box 9004, Abha, 61413, Saudi Arabia

    Abdullah G. Al-Sehemi

  6. Unit of Science and Technology, Faculty of Science, King Khalid University, P.O. Box 9004, Abha, 61413, Saudi Arabia

    Abdullah G. Al-Sehemi

  7. Department of Physics, Faculty of Sciences, King Abdulaziz University, Jeddah, Saudi Arabia

    Ahmed Al-Ghamdi

  8. Department of Physics, Faculty of Science, Firat University, Elazig, Turkey

    F. Yakuphanoglu

Authors
  1. A. Tataroglu
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  2. Kenan Koran
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  3. Eray Çaliskan
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  4. Abdullah G. Al-Sehemi
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  5. Ahmet Orhan Görgülü
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  6. Ahmed Al-Ghamdi
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  7. F. Yakuphanoglu
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Corresponding author

Correspondence to F. Yakuphanoglu.

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Tataroglu, A., Koran, K., Çaliskan, E. et al. Metallo-Phthalocyanines Based Photocapacitors. Silicon 11, 1275–1286 (2019). https://doi.org/10.1007/s12633-018-9917-x

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  • DOI: https://doi.org/10.1007/s12633-018-9917-x

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