Abstract
In this study, we investigated the structural properties of Urfa stone (US) doped with erbium oxide (Er2O3). Solid US was powdered by using an agate mortar, and its elemental composition was determined using inductive coupling plasma (ICP) methods. Varying amounts of Er2O3 (5, 10, 20, 30, and 40%) were added as a dopant to the US powder using mechanical alloying methods. The resultant samples were sintered at 1000 °C for 1 h. The structural properties of the Er2O3-doped US samples were subsequently investigated using X-ray diffraction (XRD), Fourier-transform infrared spectrometry (FTIR), and photoluminescence methods. Results from the XRD analysis of the Er2O3-doped US powder indicated two crystalline phases: (1) calcium oxide (CaO) or lime and (2) Er2O3. After the samples were sintered at 1000 °C, CaO, Er2O3, calcium carbonate (CaCO3), and mixed crystalline phases were observed. Results from the FTIR analysis of the Er2O3-doped US samples indicated absorption bands at 711.91, 872.08, and 1396.87 cm−1 in the spectra. Finally, photoluminescence analysis results indicated a shift in the emission and excitation bands to longer and shorter wavelengths, respectively, in the solid state (non-aqueous media) US-Er complex.
Similar content being viewed by others
References
Agan C (2011) Investigation into the usage of sanliurfa limestones in Turkey as underground storage cavern with regard to some engineering properties. Int J Phy Sci 6:7629–7637. https://doi.org/10.5897/IJPS11.250
Agan C (2016) A preliminary study on the conservation and polishing performance of sanliurfa limestones as a traditional building material. Bull Eng Geol Environ 75:13–25. https://doi.org/10.1007/s10064-015-0729-6
Aktas B, Albaskara M, Yalcin S, Dogru K (2017) Optical properties of soda–lime–silica glasses doped with eggshell powder. Acta Phys Pol A 132:442–444. https://doi.org/10.12693/APhysPolA.132.442
Anadolu Agency (2018) Unique Urfa stone promoted for wider use in architecture. Daily Sabah Life. https://www.dailysabah.com/life/2018/11/02/unique-urfa-stone-promoted-for-wider-use-in-architecture
Andreev BA, Krasil’nik ZF, Kryzhkov DI, Yablonskiĭ AN, Kuznetsov VP, Gregorkiewicz T, Klik MAJ (2004) Er3+ photoluminescence excitation spectra in erbium-doped epitaxial silicon structures. Phys Solid State 46:97–100. https://doi.org/10.1134/1.1641931
Ceyhan G, Köse M, Tümer M, McKee V (2012) Novel polymeric potassium complex: its synthesis, structural characterization, photoluminescence and electrochemical properties. J Lumin 132:850–857. https://doi.org/10.1016/j.jlumin.2011.09.056
Ceyhan G, Köse M, Tümer M, Demirtaş I, Yağlioğlu AŞ, McKee V (2013) Structural characterization of some Schiff base compounds: investigation of their electrochemical, photoluminescence, thermal and anticancer activity properties. J Lumin 143:623–634. https://doi.org/10.1016/j.jlumin.2013.06.002
Gao Y, Sun Y, Zou H, Sheng Y, Zhou X, Zhang B, Zhou B (2016) Effect of Eu3+ doping on the structural and photoluminescence properties of cubic CaCO3. Mater Sci Eng B 203:52–58. https://doi.org/10.1016/j.mseb.2015.09.004
Kaci S, Keffous A, Bozetine I, Trari M, Fellahi O (2016) Influence of growth conditions of hydrogenated amorphous silicon carbide on optical properties of the interfacial layer in SiC-based photodevice. Acta Phys Pol A 130:463–465. https://doi.org/10.12693/APhysPolA.130.463
Kang M, Liu J, Yin G, Sun R (2009) Preparation and characterization of Eu3+-doped CaCO3 phosphor by microwave synthesis. Rare Metals 28:439–444. https://doi.org/10.1007/s12598-009-0085-4
Ruiz MG, Hernández J, Baños L, Montes JN, García MER (2009) Characterization of calcium carbonate, calcium oxide, and calcium hydroxide as starting point to the improvement of lime for their use in construction. J Mater Civ Eng 21:694–698. https://doi.org/10.1061/(ASCE)0899-1561(2009)21:11(694)
Tiwari N, Dubey V (2016) Luminescence studies and infrared emission of erbium-doped calcium zirconate phosphor. Luminescence 31:837–842. https://doi.org/10.1002/bio.3039
Truffault L, Ta MT, Devers T, Konstantinov K, Harel V, Simmonard C, Andreazza C, Nevirkovets IP, Pineau A, Veron O, Blondeau JP (2010) Application of nanostructured Ca doped CeO2 for ultraviolet filtration. Mater Res Bull 45:527–535. https://doi.org/10.1016/j.materresbull.2010.02.008
Yalcin S, Aktas B, Albaskara M, Arslan A, Ceyhan G (2018) Investigation of the photoluminescence properties of Urfa stone powder doped with chromium oxide. Arab J Geosci 11:157. https://doi.org/10.1007/s12517-018-3513-7
Acknowledgements
The authors wish to thank the Harran University’s Central Laboratory (HUBTAM) and Chemistry Department for enabling the XRD and FTIR analyses, and Sutcu Imam University’s Research and Development Center for University-Industry-Public Relations for enabling the photoluminescence analysis in support of this study.
Funding
This study was funded by the Harran University Scientific Research Council (HUBAK 14085, 15026, and K17144).
Author information
Authors and Affiliations
Corresponding authors
Additional information
This article is part of the Topical Collection on Geo-Resources-Earth-Environmental Sciences
Rights and permissions
About this article
Cite this article
Aktas, B., Yalcin, S., Albaskara, M. et al. Structural properties of Urfa stone doped with erbium oxide. Arab J Geosci 11, 757 (2018). https://doi.org/10.1007/s12517-018-4112-3
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s12517-018-4112-3