Abstract
Micro-structural changes in zinc oxide (ZnO) nanoparticles induced by the substitution of \(\hbox {Zn}^{2+}\) in ZnO by a rare earth (RE) metal ion, \(\hbox {Sm}^{3+}\), are investigated. Both pristine and Sm-doped ZnO with a nominal doping concentration of 1, 2 and 4% of Sm using a simple wet-chemical synthetic route followed by calcination at a high temperature of \(900{^{\circ }}\hbox {C}\), are synthesized. Structural investigations are primarily conducted using X-ray powder diffraction (XRPD) and scanning electron microscopy techniques. Evolution of structural parameters (unit cell parameters, average crystallite size, crystallinity percentage, lattice strain, stress, energy density and atomic packing factor) upon Sm doping is investigated together with Rietveld refinement and Le Bail analysis techniques. XRPD data confirmed that the synthesized nanostructures crystallize in a wurtzite hexagonal structure, the dopant Sm is incorporated into the Zn lattice and the annealing treatment plays a crucial role in determining the structural and optical properties of RE-metal-doped nanoparticles. Values of the optical band gap energy estimated from optical absorbance measurements reveal a widening of the band gap.
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References
Gleiter H 2000 Acta Mater. 48 1
Klingshirn C 2007 ChemPhysChem 8 6
Klingshirn C 2007 Phys. Status Solidi 244 9
Klingshirn C, Fallert J, Zhou H, Sartor J, Thiele C, Maier-Flaig F et al 2010 Phys. status solidi 247 1424
Kołodziejczak-Radzimska A and Jesionowski T 2014 Materials (Basel) 7 4
Bagnall D M, Chen Y F, Zhu Z, Yao T, Koyama S, Shen M Y et al 1998 Appl. Phys. Lett. 70 2230
Reynolds D C, Look D C and Jogai B 1996 Solid State Commun. 99 12
Wang Z L 2004 J. Phys. Condens. Matter 16 25
Lim J-H, Kang C-K, Kim K-K, Park I-K, Hwang D-K and Park S-J 2006 Adv. Mater. 18 2720
Xu S and Wang Z L 2011 Nano Res. 4 11
Shao S, Zheng K, Zidek K, Chabera P, Pullerits T and Zhang F 2013 Sol. Energy Mater. Sol. Cells 118 43
Ciciliati M A, Silva M F, Fernandes D M, de Melo M A C, Hechenleitner A A W and Pineda E A G 2015 Mater. Lett. 159 84
Saleh R and Djaja N F 2014 Spectrochim. Acta A: Mol. Biomol. Spectrosc. 130 581
Fabbiyola S, Sailaja V, Kennedy L J, Bououdina M and Judith Vijaya J 2017 J. Alloys Compd. 694 522
Singhal S, Kaur J, Namgyal T and Sharma R 2012 Phys. B Condens. Matter 407 8
Hosseini S M, Sarsari I A, Kameli P and Salamati H 2015 J. Alloys Compd. 640 408
Kundaliya D C, Ogale S B, Lofland S E, Dhar S, Metting C J, Shinde S R et al 2004 Nat. Mater. 3 709
Jung S W, An S-J, Yi G-C, Jung C U, Lee S-I and Cho S 2002 Appl. Phys. Lett. 80 4561
Korake P V, Kadam A N and Garadkar K M 2014 J. Rare Earths 32 4
Atkinson S C 2014 Crystal structures and phase transitions in the rare earth oxides, University of Salford
Daksh D and Agrawal Y K 2016 Rev. Nanosci. Nanotechnol. 5 1
Lin C C, Young S L, Kung C Y, Horng L, Chen H Z, Kao M C et al 2013 Vacuum 87 178
Ahmed M A, Mwankemwa B S, Carleschi E, Doyle B P, Meyer W E and Nel J M 2018 Mater. Sci. Semicond. Process. 79 53
Kumar D R, Ranjith K S, Nivedita L R and Kumar R T R 2017 J. Rare Earths 35 10
Abbad M M, Takriff M S, Benamor A, Nasser M S, Mahmoudi E and Mohammad A W 2018 J. Sol-Gel Sci. Technol. 85 178
Pandiyarajan T, Mangalaraja R V, Karthikeyan B, Sathishkumar P, Mansilla H D, Contreras D et al 2015 Appl. Phys. A 119 487
Toby B H 2001 J. Appl. Crystallogr. 34 2
Laugier J and Bochu B 1999 LMGP-Suite of programs for the interpretation of X-ray experiments (ENSP/Laboratoire des Matériaux et du Génie Physique)
Sawada H, Wang R and Sleight A W 1996 J. Solid State Chem. 122 1
Zav’yalova A A, Imamov R M, Ragimli N A and Semilatov S A 1976 Sov. Phys. Crystallogr. 21 411
Arora D, Asokan K, Mahajan A, Kaur H and Singh D P 2016 RSC Adv. 6 81
Kaygili O 2014 J. Therm. Anal. Calorim. 117 1
Kaygili O, Ercan I, Ates T, Keser S, Orek C, Gunduz B et al 2018 Chem. Phys. 513 273
Kumar S S, Venkateswarlu P, Rao V R and Rao G N 2013 Int. Nano Lett. 3 30
Zhang J-M, Zhang Y, Xu K-W and Ji V 2006 Solid State Commun. 139 3
Nye J F 1985 Physical properties of crystals: their representation by tensors and matrices (Oxford: Clarendon Press)
Kumar P, Singh B K, Pal B N and Pandey P C 2016 Appl. Phys. A 122 8
Mote V D, Dargad J S and Dole B N 2013 Nanosci. Nanoeng. 1 2
Zamiri R, Rebelo A, Zamiri G, Adnani A, Kuashal A, Belsley M S et al 2014 RSC Adv. 4 20902
Tauc J 1966 in S Nudelman and S Mitra (eds) Optical properties and electronic structure of amorphous semiconductors (Boston: Springer US)
Badreddine K, Kazah I, Rekaby M and Awad R 2018 J. Nanomater. 2018 1
He H Y, Fei J and Lu J 2015 J. Nanostruct. Chem. 5 2
Kamarulzaman N, Kasim M F and Rusdi R 2015 Nanoscale Res. Lett. 10 1
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We thank Y Kaya for his assistance and discussion on the determination of optical energy gaps.
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Okur, H.E., Bulut, N., Ates, T. et al. Structural and optical characterization of Sm-doped ZnO nanoparticles. Bull Mater Sci 42, 199 (2019). https://doi.org/10.1007/s12034-019-1877-2
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DOI: https://doi.org/10.1007/s12034-019-1877-2