Skip to main content
Log in

Electrical Properties of Thermally Sprayed Ni- and Ni20Cr-Based Resistors

  • Peer Reviewed
  • Published:
Journal of Thermal Spray Technology Aims and scope Submit manuscript

Abstract

Five laboratories were asked to deposit Ni and Ni20Cr powders to obtain resistors; we studied their electrical properties in the temperature range 20-500 °C and interpreted the results in the light of their microstructure. Resistors sprayed from Ni powders consist of NiO x “islands” embedded in a Ni matrix. The temperature dependence of resistance (TCR) is in perfect agreement with that of pure Ni, indicating that the matrix determines the electrical transport. Annealing at temperatures from 200 to 400 °C results in an irreversible decrease of resistance. A multiphase microstructure is observed in resistors prepared from 80Ni20Cr powders. The major phase in these resistors is a NiCr alloy but with a Ni:Cr ratio larger than 80:20. Minor amounts of metal oxides are also detected. The TCR in these samples spans from 180 ppm/°C to 2830 ppm/°C, and is attributed to different degree of oxidation and segregation of the metals in the alloy.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12

Similar content being viewed by others

References

  1. L. Pawłowski The Science and Engineering of Thermal Spray Coatings Wiley, Chichester (1995)

    Google Scholar 

  2. R. McPherson, Plasma-Sprayed Ceramic Coatings, Surface Engineering: Processes and Applications, K.N. Strafford et al., Eds., Technomic Publications, 1995, p 3-20

  3. A. Sharma, R.J. Gambino, S. Sampath Anisotropic Electrical Properties in Thermal Spray Metallic Coatings Acta Mater. 54 (2006) 59–65

    CAS  Google Scholar 

  4. R. Gadow, A. Killinger, C. Li Product Development with Thermally Sprayed Functional Coatings on Glass and Glass–Ceramics Substrates Int. J. Appl. Ceram. Technol. 2 (2005) 493–503

    Article  CAS  Google Scholar 

  5. T. Tong, J. Li, Q. Chen, J.P. Longtin, S. Tankiewicz, S. Sampath Ultrafast Laser Micromachining of Thermal Sprayed Coatings for Microheaters: Design, Fabrication and Characterization Sens. Actuators A 114 (2004) 102–111

    Article  CAS  Google Scholar 

  6. D. Michels, J. Hadeler, J.H.V. Lienhard (1998) High Heat Flux Resistance Heaters from VPS and HVOF Thermal Spraying. Exp. Heat Transfer 11:341–359

    Article  CAS  Google Scholar 

  7. H.F. Younis, R.S. Dahbura, and J.H.V. Lienhard, Thin Film Resistance Heaters for High Heat Flux Jet Array Cooling Experiments, Proc. ASME Heat Transfer Division 3, ASME HTD, 1997, 353, p 127-134

  8. M. Prudenziati, G. Cirri, P. Dal Bo Novel High-Temperature Reliable Heaters in Plasma Spray Technology J. Therm. Spray Technol., 15 (2006) 329–331

    Article  CAS  Google Scholar 

  9. J. Longtin, S. Sampath, R.J. Gambino, S. Tankiewicz, R. Greenlaw Sensors for Harsh Environments by Direct Write Thermal Spray IEEE Sens. J., 4 (2004) 118–121

    Article  Google Scholar 

  10. R.J. Gambino, M. Manivel Raja, S. Sampath, R. Greenlaw Plasma Sprayed Thick Film Anisotropic Magnetoresistive (AMR) Sensors IEEE Sens. J., 4 (2004) 764–767

    Article  CAS  Google Scholar 

  11. N. Margadant, S. Siegmann, J. Patscheider, T. Keller, W. Wagner, J. Ilavsky, J. Pisacka, G. Barbexat, and P. Fiala, Microstructure-Property Relationship And Cross-Property Correlations of Thermal Sprayed Ni-Alloy Coatings, Proc. Thermal Spray 2001: New Surfaces for a New Millennium, C.C. Berndt, K.A. Khor, and E.F. Lugscheider, Eds., ASM International, Materials Park, OH, 2001, p 643–652

  12. S. Sampath, H. Herman, A. Patel, R. Gambino, R. Greenlaw, and E. Tormey, Thermal SprayTechniques for Fabrication of Meso-Electronics and Sensors, Material Research Society Symposium Proceedings, 2000, 624, p 181-188

  13. M. Prudenziati, Development and the Implementation of High-Temperature Reliable Heaters in Plasma Spray Technology, J. Therm. Spray Technol., 2008, 17, p 234–243

    Article  CAS  Google Scholar 

  14. R. Pawlak, Laser-Remelted Plasma Coatings, Proc. SPIE—The International Society for Optical Engineering. Laser Technology VII: Applications of Lasers, 2003, 5229, p 251-254

  15. E.P. Wolfarth, Ferrmagnetic Materials, North Holland, 1980

  16. H. Herman, S. Sampath, R. McCune Thermal Spray: Current Status and Future Trends MRS Bull. 25 (2000) 17–25

    CAS  Google Scholar 

  17. R. McPherson The Relationship Between the Mechanism of Formation, Microstructure and Properties of Plasma-Sprayed Coatings Thin Solid Films 83 (1981) 297–310

    Article  CAS  Google Scholar 

  18. S. Sampath, H. Herman Rapid Solidification and Microstructure Development During Plasma Spray Deposition J. Therm. Spray Technol., 5(4) (1996) 445–456

    Article  CAS  Google Scholar 

  19. R.A. Serway, Principles of Physics, 2nd ed, Fort Worth, TX, Saunders College Pub. London (1998).

    Google Scholar 

  20. P. Chráska, B. Kolman, M. Suchánek, and K. Voleník, Composition Changes of Selected Alloys During Their Plasma Spraying, Thermal Spray 2004: Advances in Technology and Application, Proceedings of the International Thermal Spray Conference, May 10-12, 2004 (Osaka, Japan), 2004, p 7-11

  21. K. Voleník, P. Chráska, and J. Dubský, Oxidation of Ni-Based Alloys Sprayed by a Water-Stabilized Plasma Gun (WSP®), Proc. of the ITSC 2003: Advancing the Science & Applying the Technology (Orlando, OH), C. Moreau and B. Marple, Eds., ASM International, Materials Park, OH, 2003, p 1033–1040

  22. K. Volenik, B. Kolman, J. Dubsky, and P. Chraska, In-Flight Behaviour of Ni-Al Powder During Its Plasma Spraying, Proceedings of the ITSC 2005—Thermal Spray Connects: Explore its Surfacing Potential! May 2-4, 2005 (Basel, Switzerland), 2005, p 1175-178

  23. C.-J. Li, W.-Y. Li Effect of Sprayed Powder Particle Size on the Oxidation Behavior of MCrAlY Materials During High Velocity Oxygen-Fuel Deposition Surf. Coat. Technol. 162 (2002) 31–41

    Article  Google Scholar 

  24. V.V. Sobolev, J.M. Guilemany Oxidation of Coatings in Thermal Spraying Mater. Lett. 37 (1998) 231–235

    Article  CAS  Google Scholar 

  25. J.L. Vosson, W. Kern, Thin Films Processes, Academic Press, New York, 1987

    Google Scholar 

  26. I.H. Kazi, P.M. Wild, T.N. Moore, M. Sayer The Electromechanical Behavior of Nichrome (80/20 wt.%) Film Thin Solid Films 433 (2003) 337–343

    Article  CAS  Google Scholar 

  27. M.M. Nayak, R. Rajanna, S. Mohan Performance Study of a Pressure Transducer with Meandering-Path Thin Film Strain Gauges Thin Solid Films 193/194 (1990) 1023–1029

    Article  Google Scholar 

  28. R.W. Cahn and P. Haasen, Physical Metallurgy, 3rd ed., part II, Elsevier Sci. Publ., Amsterdam, 1983

  29. S. Kuroda, T.W. Clyne The Quenching Stress in Thermally Sprayed Coatings Thin Solid Films 200 (1991) 49–66

    Article  CAS  Google Scholar 

  30. T. Keller, N. Margadant, T. Pirling, M.J. Riegert-Escribano, W. Wagner Residual Stress Determination in Thermally Sprayed Metallic Deposits by Neutron Diffraction Mater. Sci. Eng. A 373 (2004) 33–44

    Article  CAS  Google Scholar 

  31. S. Sampath, X.Y. Jiang, J. Matejicek, L. Prchlik, A. Kulkarni, A. Vaidya Role of Thermal Spray Processing Method on the Microstructure, Residual Stress and Properties of Coatings: An Integrated Study for Ni–5 wt.%Al Bond Coats Mater. Sci. Eng. A 364 (2004) 216–231

    Article  CAS  Google Scholar 

  32. K. Schröder Handbook of Electrical Resistivities of Binary Metallic Alloys CRC Press, Florida (1983) 194–197

    Google Scholar 

  33. E.J. Verwey, P.W. Haayman, F.C. Romeijn Physical Properties and Cation Arrangement of Oxides with Spinel Structures J. Chem. Phys., 15 (1947) 181–187

    Article  CAS  Google Scholar 

  34. W.D. Kingery, D.R. Uhlman, H.K. Bowen Introduction to Ceramics Wiley Interscience, New York 1975

    Google Scholar 

Download references

Acknowledgments

The authors are grateful to Centro Sviluppo Materiali (CSM), Rome, Italy for financially supporting this project. We are also indebted to INGLASS S.r.l, San Polo di Piave, Treviso, Italy, for having promoted this research.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Maria Prudenziati.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Prudenziati, M., Gualtieri, M.L. Electrical Properties of Thermally Sprayed Ni- and Ni20Cr-Based Resistors. J Therm Spray Tech 17, 385–394 (2008). https://doi.org/10.1007/s11666-008-9187-z

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11666-008-9187-z

Keywords

Navigation