Abstract
Infrared brazing of Ti50Ni50 SMA and Inconel 600 alloy using Cusil-ABA and Ticusil filler metals has been investigated. The joints were dominated by Ag-Cu eutectic with proeutectic Cu in the Cusil-ABA brazed joint and with proeutectic Ag in the Ticusil one. A continuous curved belt composed of a Ni3Ti layer and a (Cu x Ni1−x )2Ti layer formed in the brazed Ti50Ni50/Ticusil/Inconel 600 joint. On the Ti50Ni50 SMA side, an intermetallic layer of (Cu x Ni1−x )2Ti formed in all joints, with x values around 0.81 and 0.47. Layers of (Cu x Ni1−x )2Ti, Ni3Ti, and mixed Ni3Ti and Ni2Cr intermetallics were observed next to the Inconel 600 substrate in the brazed Ti50Ni50/Cusil-ABA/Inconel 600 joint. The maximum shear strengths of the joints using the Cusil-ABA filler metal and the Ticusil filler metal were 324 and 300 MPa, respectively. In the Cusil-ABA brazed joint, cracks with cleavage-dominated fracture propagated along the (Cu x Ni1−x )2Ti interfacial layer next to the Ti50Ni50 SMA substrate. In the Ticusil brazed joint, ductile dimple fracture occurred in the Ag-rich matrix near the Inconel 600 alloy substrate. The absence of a detrimental Ti-Fe-(Cu) layer on the Inconel 600 substrate side can effectively improve the shear strength of the joint.
Similar content being viewed by others
References
K. Otsuka and C. M. Wayman: Shape Memory Materials, Cambridge University Press, London, 1998.
K. Otsuka and X. Ren: Prog. Mater. Sci., 2005, vol. 50, pp.511–678.
K. Krulevitch, A.P. Lee, P.B. Ramsey, J. C. Trevino, J. Hamilton and M. A. Northrup: J. Microelectron. Syst., 1996, vol. 5, p. 270.
L. McD. Schetky: Trans. Mater. Res. Soc. Jpn., 1994, vol. 18B, pp. 1131–42.
R.K. Shiue, C.P. Chen and S.K. Wu: Metall. Mater. Trans. A, 2015, vol. 46, pp. 2364–71.
W. F. Smith: Structure and Properties of Engineering Alloys, 2nd ed., McGraw-Hill Co. Ltd., New York, 1993, pp. 494–98.
J.H. Chen, G.Z. Wang, K. Nogi, M. Kamai, N. Sato and N. Iwamoto: J. Mater. Sci., 1993, vol. 28, pp. 2933–42.
W.C. Lee: J. Mater. Sci. Lett., 1996, vol. 15, pp. 29–31.
T. Zaharinie, F. Yusof, M. Fadzil, M. Hamdi, T. Ariga: Mater. Res. Innov., 2014, vol. 18(S6), pp. 68–72.
A. Laik, P. Mishra, K. Bhanumurthy, G.B. Kale, B.P. Kashyap: Acta Mater., 2013, vol. 61, pp. 126–38.
M.F. Montemor, M.G.S. Ferreira, N.E. Hakiki and M. Da Cunha Belo: Corr. Sci., 2000, vol. 42, pp. 1635–50
A.P. Xian and Z.Y. Si: J. Mater. Sci., 1993, vol. 25, pp. 4483–87.
X. Yue, P. He, J.C. Feng, J.H. Zhang and F. Q. Zhu: Mater. Charact., 2008, vol. 59, pp. 1721–27.
R.K. Shiue, S.K. Wu and S.Y. Chen: Acta Mater., 2003, vol. 51, pp. 1991–2004.
R.H. Shiue and S.K. Wu: Intermetallics, 2006, vol. 14, pp. 630–38.
R.K. Shiue, Y.H. Chen and S. K. Wu: Metall. Mater. Trans. A, 2013, vol. 44A, pp. 4454–60.
M. Schwartz: Brazing: for the Engineering Technologist, Chapman & Hall, New York, 1995, pp. 109–111.
P. Siegmund, C. Guhl, E. Schmidt, A. Rossberg, M. Rettenmayr: J. Mater. Sci., 2016, vol. 51, pp. 3693–3700.
A. Laik, A.A. Shirzadi, R. Tewari, A. Kumar, T. Jayakumar, G.K. Dey: Metall. Mater. Trans. A, 2013, vol. 44A, pp. 2212–25.
Y. Liu, Z.R. Huang, X.J. Liu: Ceram. Int., 2009, vol. 35, pp. 3479–84.
P. Villars, A. Prince and H. Okamoto: Handbook of Ternary Alloy Phase Diagrams, ASM International, Materials Park, 1995.
K.P. Gupta: Phase Diagrams of Ternary Nickel Alloys, Indian Institute of Metals, Calcutta, 1990.
T.Y. Yang, R.K. Shiue and S.K. Wu: Intermetallics, 2004, vol. 12, pp. 1285-1292.
ASM Materials Handbook: Binary Phase Diagrams, ASM International, Materials Park, 1992, vol. 3, 9.2.155.
T.B. Massalski: Binary Alloy Phase Diagrams, ASM International, Materials Park, 1992.
Acknowledgments
The authors gratefully acknowledge the financial support for this research provided by the Ministry of Science and Technology (MOST) and National Taiwan University (NTU), Taiwan, under Grant Nos. MOST 104-2221-E002-005 and NTU 105R891803.
Author information
Authors and Affiliations
Corresponding author
Additional information
Manuscript submitted February 26, 2016.
Rights and permissions
About this article
Cite this article
Shiue, RK., Wu, SK. & Yang, SH. Infrared Brazing of Ti50Ni50 Shape Memory Alloy and Inconel 600 Alloy with Two Ag-Cu-Ti Active Braze Alloys. Metall Mater Trans A 48, 735–744 (2017). https://doi.org/10.1007/s11661-016-3890-z
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11661-016-3890-z