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Solid–Liquid Interfacial Energy of Solid Neopentylglycol Solution in Equilibrium with Neopentylglycol–Aminomethylpropanediol Eutectic Liquid

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Abstract

The grain boundary groove shapes for solid neopentylglycol solution (NPG-40 mol pct AMPD) in equilibrium with the neopentylglycol (NPG)–aminomethylpropanediol (AMPD) eutectic liquid (NPG-42.2 mol pct AMPD) have been directly observed using a horizontal linear temperature gradient apparatus. From the observed grain boundary groove shapes, the Gibbs–Thomson coefficient (Г) and solid–liquid interfacial energy (σ SL) of solid NPG solution have been determined to be (7.4 ± 0.7) × 10−8 K m and (6.4 ± 1.0) × 10−3 J m−2, respectively. The grain boundary energy of solid NPG solution has been determined to be (12.5 ± 1.0) × 10−3 J m−2 from the observed grain boundary groove shapes. The ratio of thermal conductivity of equilibrated eutectic liquid to thermal conductivity of solid NPG solution has also been determined to be 0.48.

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Acknowledgments

This project was supported by the Erciyes University Scientific Research Project Unit under Contract No: FBY-11-3775. The authors are grateful to the Erciyes University Scientific Research Project Unit for their financial support.

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Authors and Affiliations

  1. Department of Physics, Institute of Science and Technology, Erciyes University, 38039, Kayseri, Turkey

    Ümit Bayram (Research Assistant, PhD student) & Alaaddin Özer (M.Sc. Student)

  2. Department of Physics, Faculty of Arts and Sciences, Nevşehir University, 50300, Nevşehir, Turkey

    Sezen Aksöz (Associate Professor)

  3. Department of Metallurgical and Materials Engineering, Faculty of Chemical and Metallurgical Engineering, Yıldız Technical University, 34210, Davutpaşa, İstanbul, Turkey

    Necmettin Maraşlι (Professor)

Authors
  1. Ümit Bayram
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  2. Alaaddin Özer
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  4. Necmettin Maraşlι
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Correspondence to Necmettin Maraşlι.

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Manuscript submitted December 25, 2012.

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Bayram, Ü., Özer, A., Aksöz, S. et al. Solid–Liquid Interfacial Energy of Solid Neopentylglycol Solution in Equilibrium with Neopentylglycol–Aminomethylpropanediol Eutectic Liquid. Metall Mater Trans A 44, 4042–4050 (2013). https://doi.org/10.1007/s11661-013-1760-5

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