Skip to main content
SpringerLink
Log in

The adsorbing effect of calcined layered double hydroxide for chloride ions in simulated concrete pore solutions

  • Cementitious Materials
  • Published:
Journal of Wuhan University of Technology-Mater. Sci. Ed. Aims and scope Submit manuscript

Abstract

The adsorbing effect of calcined layered double hydroxide (CLDH) for chloride ions in simulated concrete pore (SCP) solutions was investigated with the potentiodynamic polarization method, impedance measurement, ion selective electrode analysis and XRD. CLDH could effectively adsorb Cl− and increase pH value in SCP solutions containing NaCl. The chloride to hydroxyl ions ratio ([Cl−]/[OH−]) of the solution greatly decreased by CLDH treatment. In CLDH treated SCP solution with Cl−, the pitting potential of carbon steel notably increased, and the surface impedance was much higher, indicating strengthened passivation. The process of CLDH adsorbing chloride ions from SCP solutions was accompanied with the reconstruction of the layered structure.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Wang Y, Li L, Page CL. Modelling of Chloride Ingress into Concrete from a Saline Environment[J]. Build. Environ., 2005, 40(12): 1 573–1 582

    Article  Google Scholar 

  2. Moreno M, Morris W, Alvarez MG, et al. Corrosion of Reinforcing Steel in Simulated Concrete Pore Solutions: Effect of Carbonation and Chloride Content[J]. Corros. Sci., 2004, 46(11): 2 681–2 699

    Article  Google Scholar 

  3. Saremi M, Mahallati E. A study on Chloride-induced Depassivation of Mild Steel in Simulated Concrete Pore Solution[J]. Cement Concrete Res., 2002, 32(12): 1 915–1 921

    Article  Google Scholar 

  4. Liu Y, Du R, Lin C. Effect of Chloride Ions on the Corrosion Behavior of Reinforcing Steel in Simulated Concrete Pore Solutions[J]. Electrochem., 2005, 11(3): 333–336 (In Chinese)

    Google Scholar 

  5. Angelo V. Preparation and Catalytic Properties of Cationic and Anionic Clays[J]. Catal. Today, 1998, 41(1–3): 53–71

    Google Scholar 

  6. Tong Z, Shichi T, Kakagi M. Oxidation Catalysis of a Manganese(III) Porphyrin Intercalated in Layered Double Hydroxide Clays[J]. Mater. Lett., 2003, 57(15): 2 258–2 261

    Article  Google Scholar 

  7. Yang W, Kim Y, Liu PT, et al. A Study by in situ Techniques of the Thermal Evolution of the Structure of a Mg-Al-CO3 Layered Double Hydroxide[J]. Chem. Eng. Sci., 2002, 57(15): 2 945–2 953

    Article  Google Scholar 

  8. Wang J, Li Z, Guo Y. Adsorption of Chloride Anion by Mg/Al Hydrotalcite and Its Calcined Product[J]. J. Xi’an Polytechnic University, 2008, 22(2): 171–174 (In Chinese)

    Google Scholar 

  9. Liang L, He J, Wei M, et al. Uptake of Chloride Ion from Aqueous Solution by Calcined Layered Double Hydroxides: Equilibrium and Kinetic Studies[J]. Water Res., 2006, 40(4): 735–743

    Article  Google Scholar 

  10. Kameda T, Uchiyama N, Park K, et al. Removal of Hydrogen Chloride from Gaseous Streams using Magnesium-aluminum Oxide[J]. Chemosphere, 2008, 73(5): 844–847

    Article  Google Scholar 

  11. Zhang FZ, Zhang BW, Xu SL, et al. A Preparation Method of Calcium Aluminium Hydrotalcite Use as Concrete Admixture[P]. Chinese Patent, 200810101344, 2008

    Google Scholar 

  12. Li L, Sagüés A. Chloride Corrosion Threshold of Reinforcing Steel in Alkaline SolutionsCyclic Polarization Behavior[J]. Corros., 2002, 58(4): 305–316

    Article  Google Scholar 

  13. Ghods P, Isgor OB, McRae GA, et al. Electrochemical Investigation of Chloride-induced Depassivation of Black Steel Rebar under Simulated Service Conditions[J]. Corros. Sci., 2010, 52(5):1 649–1 659

    Article  Google Scholar 

  14. Xu J, Jiang L, Wang J. Influence of Detection Methods on Chloride Threshold Value for the Corrosion of Steel Reinforcement[J]. Constr. Build. Mater., 2009, 23(5): 1 902–1 908

    Article  Google Scholar 

  15. Kameda T, Yabuuchi F, Yoshioka T, et al. New Method of Treating Dilute Mineral Acids using Magnesium-Aluminum Oxide[J]. Water Res., 2003, 37(7): 1 545–1 550

    Article  Google Scholar 

  16. You Y, Zhao H, Vance GF. Adsorption of Dicamba (3,6-dichloro-2-methoxy benzoic acid) in Aqueous Solution by Calcined-layered Double Hydroxide[J]. Appl. Clay Sci., 2002, 21(5–6): 217–226

    Article  Google Scholar 

  17. Ren Z, He J, Zhang C, et al. Removal of Chloride Anion by Calcined Layered Double Hydroxides[J]. Fine Chem., 2002, 19(6): 339–342 (in Chinese)

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. School of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing Key Laboratory of Electrochemical Process and Technology for Materials, Beijing, 100029, China

    Yuming Tang  (唐聿明), Xuhui Zhao, Le Niu & Yu Zuo  (左禹)

Authors
  1. Yuming Tang  (唐聿明)
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Xuhui Zhao
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Le Niu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yu Zuo  (左禹)
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yu Zuo  (左禹).

Additional information

Funded by the National Natural Science Foundation of China (51171014 and 51210001) and the Fundamental Research Funds for the Central Universities (No.ZZ1116)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Tang, Y., Zhao, X., Niu, L. et al. The adsorbing effect of calcined layered double hydroxide for chloride ions in simulated concrete pore solutions. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 29, 278–283 (2014). https://doi.org/10.1007/s11595-014-0908-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11595-014-0908-5

Key words

Search

Navigation