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Rational construction of Na0.44MnO2 nanorods and PAN nanofibers composite as high areal capacity sodium-ion batteries

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Abstract

The electrode materials are traditionally loaded on the surface of the metal current collector by using of roll coating methods in sodium-ion batteries (SIBs). However, with the increase of the mass loading, the sodium storage performance of the cathodes deteriorates dramatically in the traditional casting process. In this work, we propose a novel strategy by applying electrospinning and airbrush-spraying technique to fabricate Na0.44MnO2-based paper (NMO-BP) electrodes. The results indicate that the NMO-BP electrodes show good electrochemical performance in terms of high areal capacities and good cycling stability with the loaded Na0.44MnO2 active material increasing from 2.6 to 10.4 mg cm−2. A high areal capacities of 1.10 mAh cm−2 is obtained in the NMO-BP electrodes with high areal loading (> 10 mg cm−2) for SIBs. This research provides a new method to explore cathode materials for sodium-ion battery with higher areal capacities.

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Funding

This work is financially supported by the National Natural Science Foundation of China (Grant. No. 51901031), the student research training plan in the year of 2020 (A2020-130), the Scientific and Technological Research Program of Chongqing Municipal Education Commission (Grant No. KJQN201900623), and the Doctoral Start-Up Fund (Grant No. A2019-05) of Chongqing University of Posts and Telecommunications.

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Authors and Affiliations

  1. College of Automation, Chongqing University of Posts and Telecommunications, Chongqing, 400065, People’s Republic of China

    Tian-E. Fan, Song-Ming Liu, Xin Tang, Zhen-Hua Zou, Jiang-Qi Xie & Ming-Yu Wang

  2. Key Laboratory of Industrial Internet of Things and Networked Control, Ministry of Education, Chongqing University of Posts and Telecommunications, Chongqing, 400065, People’s Republic of China

    Tian-E. Fan

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  1. Tian-E. Fan
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  2. Song-Ming Liu
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  3. Xin Tang
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  4. Zhen-Hua Zou
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  5. Jiang-Qi Xie
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  6. Ming-Yu Wang
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Correspondence to Tian-E. Fan.

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Fan, TE., Liu, SM., Tang, X. et al. Rational construction of Na0.44MnO2 nanorods and PAN nanofibers composite as high areal capacity sodium-ion batteries. Ionics 27, 1137–1142 (2021). https://doi.org/10.1007/s11581-021-03910-8

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  • DOI: https://doi.org/10.1007/s11581-021-03910-8

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