Abstract
Hyperbranched poly(aryl ether ketone)s were prepared by polymerization of hydroquinone (A2) and 1,3,5-tris[4-(4-fluorobenzoyl)phenoxy]benzene (B3). The gelation of hyperbranched poly(aryl ether ketone)s was effectively avoided. Hydroxyl-term inated (HPAEK-OH) and fluoro-terminated (HPAEK-F) hyperbranched poly(aryl ether ketone)s were prepared by using different A2/B3 mass ratio. The structure of the B3 monomer was confirmed by MS, 1H NMR/IR. The glass transition temperatures of the HPAEK-F and HPAEK-OH are 114°C and 162°C respectively. Thermal stability of HPAEK-F is higher than HPAEK-OH.
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Translated from Acta Scientianum Naturalium Universitatis Jilinensis, 2005, 5 (in Chinese)
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Mu, J., Zhang, C., Wang, Z. et al. Synthesis and characterization of the B3-monomer and hyperbranched poly(aryl ether ketone)s. Front. Chem. China 1, 203–206 (2006). https://doi.org/10.1007/s11458-006-0015-z
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DOI: https://doi.org/10.1007/s11458-006-0015-z