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Branched aliphatic alkanes of shell bar section in Qarhan Lake, Qaidam Basin and their paleoclimate significance

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  • Geology
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Chinese Science Bulletin

Abstract

Biomarkers of paleolake deposits from Qarhan Salt Lake in Qaidam Basin, northwest China were systematically analyzed and the A–C series compounds of branched aliphatic alkanes with quaternary substituted carbon atom (BAQCs) were identified. The homologous distinguished three series, A–C, were identified as 5,5-diethylalkanes, 6,6-diethylalkanes and 5-butyl, 5-ethylalkanes series, and their relative abundance was A > B > C. Series A and C were characterized by odd carbon numbers, whereas series B was characterized by even carbon numbers. The high values of series A corresponded with the high values of series B and C. Therefore, it can be concluded that series A, B and C possess a similar biological origin. The abundance of series A was relatively low in the lower part of the section compared with that in the upper part, implying that these series originated from bacteria and/or algae more prevalent in fresh-mesohaline water, and such kinds of bacteria and/or algae are most likely to be thermophilous species. The A25/nC25 ratio differences in the section show that such branched aliphatic alkanes can be treated as one kind of environmental change proxy for paleolake evolution and may provide important information for the climate reconstruction of the Late Pleistocene.

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References

  1. Xie S C, Liang B, Guo J Q, et al. Biomarkers and the related global change. Quat Sci (in Chinese), 2003, 23(5): 521–528

    Google Scholar 

  2. Fu J M, Sheng G Y. Preliminary study on environmental organic geochemistry. Earth Sci Front (in Chinese), 1996, 3: 127–132

    Google Scholar 

  3. Yang X X, Sheng G Y, Lu J L, et al. Characteristics and paleoenvironmental significance of biomarkers in sediments from Hotong Qagan Nur (Soda Lake). Geochemica, 1996, 25(6): 536–544

    CAS  Google Scholar 

  4. Street-Perrott F A, Huang Y, Perrott A, et al. The impact of lower atmospheric CO2 on tropical mountain ecosystems. Science, 1997, 278: 1422–1426

    Article  ADS  Google Scholar 

  5. Sheng G Y, Cai K Q, Yang X X, et al. Branched aliphatic alkanes with quaternary substituted carbon atoms in sediments from Hotong Qagan Nur (Soda Lake) and their paleoenvironmental significance. Chin Sci Bull, 1998, 43(10): 1090–1093

    Google Scholar 

  6. Zhang G, Sheng G Y, Fu J M, et al. Molecular organic geochemical evidence for paleoenvironmental changes at 11.87–12.28 m in GS-1 core Gucheng Lake. Chin Sci Bull, 1999, 44(15): 1407–1411

    Article  CAS  Google Scholar 

  7. Evershed R P, Dudd S N, Charters S. et al. Lipids as carriers of anthropogenic signals from prehistory. Phil Trans R Soc Land, B, 1999, 354: 19–31

    Article  CAS  Google Scholar 

  8. Xie S C, Evershed R P. Peat molecular fossils recording paleoclimatic matter in replacement. Chin Sci Bull, 2001, 46(20): 1749–1752

    CAS  Google Scholar 

  9. Wang Z Y, Liu Z H, Yi Y, et al. Features of lipids and their significance in modern soils from various climato-vegetation regions. Acta Pedologica Sin (in Chinese), 2003, 40(6): 967–970

    Google Scholar 

  10. Kienast M, Steinke S, Stattegger K, et al. Synchronous tropical South China Sea SST change and Greenland warming during deglaciation. Science, 2001, 291: 2132–2134

    Article  PubMed  CAS  ADS  Google Scholar 

  11. Bard E, Rostek F, Sonzogni C, Interhemispheric synchrony of the last deglaciation inferred from alkenone palaeothermometry. Nature, 1997, 385: 707–710

    Article  CAS  ADS  Google Scholar 

  12. Song Q, Chu G Q, Li S Q et al. Long-chain unsaturated ketones in sulfide salt lakes and their paleoenvironemtal significance. Chin Sci Bull (in Chinese), 2004, 49(17): 1789–1792

    Google Scholar 

  13. Xie S C, Yao T D, Kang S C, et al. Geochemical analyses of a Himalayan snowpit profile: implications for atmospheric pollution and climate. Org Geochem, 2000, 31: 15–23

    Article  CAS  Google Scholar 

  14. Mycke B, Michaelis W, Degens E T. Biomarkers in sedimentary sulfides of Precambrian age. Org Geochem, 1988, 13: 619–625

    Article  CAS  Google Scholar 

  15. Dill H, Teschner M, Wehner H. Petrography, inorganic and organic geochemistry of lower Permian carbonaceous fan sequences (Brandschiefer Series)—Federal Republic of Germany—Constraints to their Paleogeography and assessment of their source rock potential. Chem Geol, 1988, 67: 307–325

    Article  CAS  Google Scholar 

  16. Kissin Y V, Feulmer G P, Payne W B. Gas chromatographic analysis of polymethyl-substituted alkanes. J Chromatog Sci, 1986, 24: 164–169

    CAS  Google Scholar 

  17. Kenig F, Sinninghe-Damste J S, Kock-van Dalen A C, et al. Occurrence and origin of mono-, di-, and trimethylalkanes in modern and Holocene cyanobacteri mats from Abu Dhabi, United Arab Emirates. Geochim Cosmochi Acta. 1995, 59: 2999–3015

    Article  CAS  ADS  Google Scholar 

  18. Derenne S, Largeau C, Berkaloff C. First example of an algeanan yielding aromatic-rich pyrolysate: possible geochemical implications on marine kerogen formation. Org Geochem, 1996, 24: 617–627

    Article  CAS  Google Scholar 

  19. Simons D J H, Kenig F, Crich D, et al. Significance of novel branched alkanes with quaternary carbon centers in black shales. Geochim Cosmochi Acta, 2002, 66: A718

    Google Scholar 

  20. Mitra S, Bianchi T S, Guo L, et al. Terrestrially derived dissolved organic matter in the Chesapeake Bay and the Middle Atlantic Bight. Geochim Cosmochi Acta, 2000, 64: 3547–3557

    Article  CAS  ADS  Google Scholar 

  21. Greenwood P F, Arouri K R. Abundance and geochemical significance of C2n dialkylalkanes and highly branched C3n alkanes in diverse Meso-and Neoproterozoic sediments. Org Geochem, 2004, 35: 331–346

    Article  CAS  Google Scholar 

  22. Kenig F, Simons D J H, Crich D, et al. Branched aliphatic alkanes with quaternary substituted carbon atoms in modern and ancient geologic samples. Proc Natl Acad Sci USA, 2003, 100: 12554–12558

    Article  PubMed  CAS  ADS  Google Scholar 

  23. Zhang H C, Pachur H J, Wünnemann B, et al. Late Quaternary development and levels of palaeolakes in Tengger desert, NW China. Palaeog Palaeoclim Palaeoecol, 2004, 211: 41–58

    Google Scholar 

  24. Zhang H C, Wünnemann B, Ma Y Z, et al. Lake level and climate change between 42000 and 18000 14C years BP in Tengger desert, NW China. Quat Res, 2002, 58: 62–72

    Article  CAS  Google Scholar 

  25. Zhang H C, Ma Y Z, Wünnemann B, et al. Abrupt climate changes during last glacial period in NW China. Geophys Res Lett, 2001, 28(16): 3203–3206

    Article  ADS  Google Scholar 

  26. Huang Q, Cai P Q. Geochronological study on the sediments in Qarhan Lake. In: Coll Pap Quat Sci Conf (in Chinese). Beijing: Science Press, 1987. 106–114

    Google Scholar 

  27. Chen K Z, Bowler J M, Kelts K. Palaeoclimatic evolution within the Qinghai-Xizang (Tibet) plateau in the last 40000 years. Quat Sci (in Chinese), 1990, 1: 21–31

    Google Scholar 

  28. Kenig F, Simons D J H, Crich D, et al. Alkanes with a quaternary carbon centre: a 2200 Myr record of sulfide oxidizing bacteria. Geochim Cosmochi Acta, 2002, 66: A393

    Google Scholar 

  29. Maxwell J R, Douglas A G, Eglinton G, et al. The Botryococcenes-Hydrocarbons of novel structure from the alga Botryococcus braunii, Kutzing. Phytochemistry, 1968, 7: 2157–2171

    Article  CAS  Google Scholar 

  30. Adam P. Nouvelles structures organo-soufrees d’interet geochimique: Aspects moleculaires et macromoleculaires. Dissertation for Doctoral Degree. Universite Louis Pasteur, Strasbourg, 1991

    Google Scholar 

  31. Arouri K, Conaghan P J, Walter M R, et al. Reconnaissance, sedimentology and hydrocarbon biomarkers of Ediacarian microbial mats and acritarchs, lower Ungoolya Group, Officer Basin. Precambrian Res, 2000, 100: 235–280

    Article  CAS  Google Scholar 

  32. Flaviano C, Leberre F, Derenne S, et al. First indications of the formation of kerogen amorphous fractions by selective preservation-Role of nonhydrolyzable macromolecular constituents of eubacterial cell-walls. Org Geochem, 1994, 22: 759–771

    Article  CAS  Google Scholar 

  33. Logan G A, Hinman M C, Walter M R, et al. Biogeochemistry of the 1640 Ma McArthur River (HYC) lead-zinc ore and host sediments, Morthern Territory, Australia. Geochim Cosmochi Acta, 2001, 65: 2317–2336

    Article  CAS  ADS  Google Scholar 

  34. Yamamoto S, Ishiwatari R, Machihara T, et al. Characterization of hydrocarbons from sediments of the Panama Basin (ODP Hole 677A and 678B). Res Org Geochem, 1990, 7: 41–42

    Google Scholar 

  35. Kenig F, Simons D H, Crich D, et al. Structure and distribution of branched aliphatic alkanes with quaternary carbon atoms in Cenomanian and Turonian black shales of Pasquia Hills (Saskatchewan, Canada). Org Geochem, 2005, 36: 117–138

    Article  CAS  Google Scholar 

  36. Schidlowski M. A 3800-million-year isotopic record of life from carbon in sedimentary rocks. Nature, 1988, 333: 313–318

    Article  CAS  ADS  Google Scholar 

Download references

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Correspondence to Chang FengQin.

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Supported by the Hundred Talent Project of Chinese Academy of Sciences, the National Natural Sciences Foundation of China (Grant No.40371117) and the Innovation Team Project of National Natural Sciences Foundation of China (Grant No.40421001)

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Zhang, H., Chang, F., Li, B. et al. Branched aliphatic alkanes of shell bar section in Qarhan Lake, Qaidam Basin and their paleoclimate significance. CHINESE SCI BULL 52, 1248–1256 (2007). https://doi.org/10.1007/s11434-007-0167-3

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  • DOI: https://doi.org/10.1007/s11434-007-0167-3

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