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Sulfur isotopic composition and source identification of atmospheric environment in central Zhejiang, China

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Abstract

Sulfur dioxide and sulfate aerosols in the atmosphere are significant factors leading to acidification of the atmospheric environment and worsening the pollution of acid deposition. Because of the “fingerprint” characteristics of the stable sulfur isotopic composition, sulfur isotope has been widely adopted in environmental researches concerning sulfur cycle and source identification. In this study, the atmospheric environment of Jinhua City, central Zhejiang Province, was continuously monitored, and the sulfur isotopic composition of SO2 and sulfate aerosols in the atmosphere was analyzed. The results indicate that the variation of δ 34S values for SO2 ranges from 1.0‰ to 7.5‰, and annual average is 4.7‰±2.3‰, whereas that of sulfate aerosols ranges from 6.4‰ to 9.8‰, and annual average is 8.1‰±1.0‰. The δ 34S values for SO2 have significant seasonal variations, which are 7.0‰ in winter and 3.3‰ in summer. These variations cannot be attributed to a single factor, and we suggest a temperature-dependent isotope equilibrium fractionation and elevated biogenic sulfur emissions of isotopically light S in summer may be the main controlling mechanisms. Furthermore, we also discuss the δ 34S model of atmospheric SO2 oxidation to form sulfate, and suggest that heterogeneous oxidation dominates in the oxidation reactions of atmospheric SO2 in the central Zhejiang Province. We further suggest that the relative humidity in the atmosphere plays an important role in the oxidation mechanism of atmospheric SO2.

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References

  1. Jamieson R E, Wadleigh M A. Tracing sources of precipitation sulfate in eastern Canada using stable isotopes and trace metals. J Geophy Res, 2000, 105: 20549–20556

    Article  Google Scholar 

  2. Romero A B. Mass-independent sulfur isotopic compositions in atmospheric sulfates. Dissertation for Doctoral Degree. San Diego: University of California, 2003

    Google Scholar 

  3. Bao H M, Reheis M C. Multiple oxygen and sulfur isotopic analyses on water-soluble sulfate in bulk atmospheric deposition from the southwestern United States. J Geophy Res, 2003, 108: 4430–4438

    Article  Google Scholar 

  4. Norman A L, Belzer W, Barrie L A. Insights into the biogenic contribution to total sulphate in aerosol and precipitation in the Fraser Valley afforded by isotopes of sulphur and oxygen. J Geophy Res, 2004, 109: 5311–5320

    Article  Google Scholar 

  5. Tie X, Brasseur G P, Briegleb B, et al. Two-dimensional simulation of Pinatubo aerosol and its effect on stratospheric ozone. J Geophy Res, 1994, 99: 20545–20562

    Article  Google Scholar 

  6. Adams P J, Seinfeld J H, Koch D M. Global concentrations of tropospheric sulfate, nitrate, and ammonium aerosol simulated in a general circulation model. J Geophy Res, 1999, 104: 13791–13823

    Article  Google Scholar 

  7. Charlson R J, Schwartz S E, Hales J M, et al., Climate forcing by atmospheric aerosols. Science, 1992, 225: 423–430

    Article  Google Scholar 

  8. Seinfeld, J H, Pandis S N. Atmospheric Chemistry and Physics: From Air Pollution to Climate Change. New York: John Wiley & Sons Inc, 1998

    Google Scholar 

  9. Haywood J, Boucher O. Estimates of the direct and indirect radiative forcing due to tropospheric aerosols: A review. Rev Geophy, 2000, 38: 513–543

    Article  Google Scholar 

  10. IPCC. Climate Change 2001: The Scientific Basis: Contribution of Working Group I to the Third Assessment Report of the Intergovernment Panel on Climate Change. New York: Cambridge University Press, 2001

    Google Scholar 

  11. Zhang M Y. Environmental chemistry of acid deposition and sources attribution using sulfur isotopic compositions—A case study in the central region of Zhejiang Province. Dissertation for Doctoral Degree. Beijing: Graduate University of Chinese Academy of Sciences, 2006

    Google Scholar 

  12. Mukai H, Tanaka A, Fujii T, et al. Regional characteristics of sulfur and lead isotope ratios in the atmosphere at several Chinese urban sites. Environ Sci Technol, 2001, 35: 1064–1071

    Article  Google Scholar 

  13. Saltzman E, Brass G, Price D. The mechanism of sulphate aerosol formation: Chemical and sulphur isotopic evidence. Geophy Res Lett, 1983, 10: 513–516

    Article  Google Scholar 

  14. Kawamura H, Matsuoka N, Tawaki S, et al. Sulfur isotope variations in atmospheric sulfur oxides, particulate matter and deposits collected at Kyushu island, Japan. Water Air Soil Pollut, 2001, 130: 1775–1780

    Article  Google Scholar 

  15. Novak M, Jackova I, Prechova E. Temporal trends in the isotope signature of air-borne sulfur in Central Europe. Environ Sci Technol, 2001, 35: 255–260

    Article  Google Scholar 

  16. Zhang H B, Chen Y W, Liu D P. Study on sulfur source of acid rain using sulfur isotopic trace (in Chinese). Geochimica, 1995, 24(Suppl): 126–133

    Google Scholar 

  17. Zhang H B, Hu A Q, Lu C Z, et al. Sulfur isotopic composition of acid deposition in South China regions and its environmental significance (in Chinese). China Environ Sci, 2002, 22: 165–169

    Google Scholar 

  18. Hong Y T, Zhang H B, Zhu Y X, et al. Sulfur isotopic characteristic of coal in China and sulfur isotopic fractionation during coal-burning process. Sci China Ser B, 1992, 22: 868–873

    Google Scholar 

  19. Hong Y T, Zhu Y X, Zhang H B, et al. Fractionation of sulfur isotopes during coal burning process and its environmental significance (in Chinese). Acta Sci Circums, 1993, 13: 240–243

    Google Scholar 

  20. Liu G S, Hong Y T, Piao H C, et al. Study on sources of sulfur in atmospheric particulate matter with stable isotope method (in Chinese). China Environ Sci, 1996, 16: 426–429

    Google Scholar 

  21. Norman A L, Barrie L A, Toom-Sauntry D, et al. Sources of aerosol sulphate at Alert: Apportionment using stable isotopes. J Geophy Res, 1999, 104: 11619–11631

    Article  Google Scholar 

  22. Nriagu J O, Coker R D. Isotopic composition of sulphur in precipitation within the Great Lakes basin. Tellus, 1978, 30: 365–375

    Article  Google Scholar 

  23. Nriagu J O, Holdway D A, Coker R D. Biogenic sulphur and the acidity of rainfall in remote areas of Canada. Science, 1987, 237: 1189–1192

    Article  Google Scholar 

  24. van Stempvoort D R, Wills J J, Fritz P. Aboveground vegetation effects on the deposition and cycling of atmospheric sulfur: Chemical and stable isotope evidence. Water Air Soil Pollut, 1991, 60: 55–82

    Article  Google Scholar 

  25. Hong Y T, Zhang H B, Zhu Y X, et al. Characterics of sulphur isotopic composition of meteoric water in China. Prog Nat Sci, 1995, 5: 344–349

    Google Scholar 

  26. Caron F, Tessier A, Kramer J R, et al. Sulphur and oxygen isotopes of sulphate in precipitation and lake water, Quebec. Appl Geochem, 1986, 1: 601–606

    Article  Google Scholar 

  27. Alewell C, Mitchell M J, Likens G E, et al. Assessing the origin of sulfate deposition at the Hubbard Brook Experimental Forest. J Environ Qual, 2000, 29: 759–767

    Article  Google Scholar 

  28. Egiazarov A C, Kaviladze M N, Kerner E L, et al. Separation of sulfur isotopes by chemical exchange. Isotopenpraxis, 1971, 7: 379–383

    Article  Google Scholar 

  29. Eriksen T E. Sulphur isotope effects I: The isotopic exchange coefficient for the sulphur isotopes 34S-32S in the system SO2-HSO3 at 25, 35 and 45°C. Acta Chimica Scand, 1972, 26: 573–580

    Article  Google Scholar 

  30. Eriksen T E. Sulfur isotope effects II: The isotopic exchange coefficients for the sulfur isotopes 34S-32S in the system SO2 g-aqueous solutions of SO2. Acta Chim Scand, 1972, 26: 581–584

    Article  Google Scholar 

  31. Tanaka N, Rye D M, Xiao Y T, et al. Use of stable sulfur isotope systematics for evaluating oxidation reaction pathways and in-cloudscavenging of sulfur dioxide in the atmosphere. Geophy Res Lett, 1994, 21: 1519–1522

    Article  Google Scholar 

  32. Tang X Y. Atomospheric Environmental Chemistry. Beijing: Higher Education Press, 1992

    Google Scholar 

  33. Martin L R. Kinetics studies of sulfite oxidation in aqueous solution, in SO2, NO and NO2 oxidation mechanisms: Atmospheric consideration. In: Teasley J I, ed. Acid Precipitation Series. Boston: Butterworth Publishers, 1984. 66–100

    Google Scholar 

  34. Langner J, Rodhe H. A global three-dimensional model of the tropospheric sulfur cycle. J Atmos Chem, 1991, 13: 255–263

    Article  Google Scholar 

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Authors and Affiliations

  1. State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, 550002, China

    MiaoYun Zhang & ShiJie Wang

  2. Jinhua Environmental Monitoring Center, Jinhua, 321013, China

    MiaoYun Zhang, GuoQiang Ma & HuaiZhong Zhou

  3. Environmental Monitoring Center of Zhejiang Province, Hangzhou, 310012, China

    Jun Fu

Authors
  1. MiaoYun Zhang
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  2. ShiJie Wang
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  3. GuoQiang Ma
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  5. Jun Fu
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Correspondence to ShiJie Wang.

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Zhang, M., Wang, S., Ma, G. et al. Sulfur isotopic composition and source identification of atmospheric environment in central Zhejiang, China. Sci. China Earth Sci. 53, 1717–1725 (2010). https://doi.org/10.1007/s11430-010-4017-9

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  • DOI: https://doi.org/10.1007/s11430-010-4017-9

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