Skip to main content
Log in

Impact of Fertilizer Application and Agricultural Crops on the Quality of Groundwater in the Alluvial Aquifer, Northern France

  • Published:
Water, Air, & Soil Pollution Aims and scope Submit manuscript

Abstract

In France, the quality of water resources with respect to nitrates deteriorated between the beginning of 1970s and 2000s. A stabilization of the situation and of the improvements has been observed punctually since the 2000s. Despite the application of the Nitrates Directive in France (91/676/CEE), the overall situation remains degraded, with numerous increases in nitrate concentrations in the underground waters. In the North of France, an alluvial groundwater’s nitrate concentration exceeds the drinking water limit fixed at 50 mg/l, in the sectors of Catillon-sur-Sambre and Rejet-de-Beaulieu. In order to quantify and model the impact of agricultural nitrogen on groundwater, an approach based on an integrated model has been established using three specific codes for each lithological horizon: Agriflux (for the root zone), VS2DT (for the unsaturated zone), and ModFlow-MT3D (for the saturated zone). The results illustrate the sensitivity of quality to agricultural crops used. Based on scenarios over 20 years, the predictions show a link between nitrate concentrations in the groundwater and agricultural crops as well as fertilization. Improving quality with a concentration of nitrate less than 50 mg/l requires a reasoned management accompanied by rotations of crops and transformations into grasslands and for sensitive areas the use of the culture producing the least nitrogen flow such as beets. The integrated model constitutes an efficient tool for predicting the evolution of the groundwater quality, especially in sensitive areas like the valleys with a rapid nitrate transfer to the aquifer. The model makes it possible to correctly evaluate the concentrations of nitrates reaching the groundwater with a monitoring of the concentration evolution in each lithological horizon, thus constituting a good tool for the management of agricultural pollution.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

References

  • Almasri, M. N., & Kaluarachchi, J. J. (2007). Modeling nitrate contamination of groundwater in agricultural watersheds. Journal of Hydrology. https://doi.org/10.1016/j.jhydrol.2007.06.016.

  • Banton, O., Larocque, M., Surateau, F., & Villeneuve, J. P. (1993). AgriFlux Logiciel d’évaluation des pertes en composés azotés vers les eaux souterraines et superficielles. INRS-eau (research report n° : R-380). Canada: Quebec.

    Google Scholar 

  • Barroin, G., Dorioz, J.M., Durand, P., & Mérot, P. (1996). Entraînement de l’azote dans les eaux de surface et conséquences sur les écosystèmes aquatiques. COLLOQUES-INRA, 39–54.

  • Bear, J. (1988). Dynamics of fluids in porous media. New York: Dover publications, Inc..

    Google Scholar 

  • Beckelynck, J., L’hopitault, J.C., & Philippo, A. (1982). Étude de l’influence de la pollution atmosphérique sur les eaux de pluie. Rapport pour la DIR. Rég. Ind. Rech. du Nord-Pas-de-Calais par le Serv. Géol. Rég. du BRGM, Lezennes, 82 SGN 1001 NPC, p. 23.

  • Bernard, P. Y., Benoît, M., Roger-Estrade, J., & Plantureux, S. (2016). Using biophysical models to manage nitrogen pollution from agricultural sources: utopic or realistic approach for non-scientist users? Case study of a drinking water catchment area in Lorraine, France. Journal of Environmental Management. https://doi.org/10.1016/j.jenvman.2016.08.050.

  • Bernard, D., El Khattabi, J., Lefevre, E., Serhal, H., Bastin-Lacherez, S., & Shahrour, I. (2008). Origin of nickel in water solution of the chalk aquifer (northern of France) and geochemical factors of variation. Environmental Geology. https://doi.org/10.1007/s00254-007-0704-z.

  • Bonton, A., Rouleau, A., Bouchard, C., & Rodriguez, J. (2011). Nitrate transport modeling to evaluate source water protection scenarios for a municipal well in an agricultural area. Agricultural Systems. https://doi.org/10.1016/j.agsy.2011.02.001.

  • Bonton, A., Bouchard, C., Rouleau, A., Rodriguez, M. J., & Therrien, R. (2012). Calibration and validation of an integrated nitrate transport model within a well capture zone. Journal Contaminant Hydrology. https://doi.org/10.1016/j.jconhyd.2011.10.007.

  • Carlier, E., & El Khattabi, J. (2005). Proposal for a probabilistic model of dispersion: a first validation. Mathematical and Computer Modelling. https://doi.org/10.1016/j.mcm.2004.05.014.

  • Carlier, E., El Khattabi, J., & Potdevin, J.L. (2006). Solute transport in sand and chalk: a probabilistic approach. Hydrological Processes. http://onlinelibrary.wiley.com/doi/10.1002/hyp.5931/full.

  • Cho, J., Mostaghimi, S., & Kang, M. S. (2010). Development and application of a modeling approach for surface water and groundwater interaction. Agricultural Water Management. https://doi.org/10.1016/j.agwat.2009.08.018.

  • Czekaj, J., Jakobczyk-Karpierz, S., Rubin, H., Sitek, S., & Witkowski, J. (2016). Identification of nitrate sources in groundwater and potential impact on drinking water reservoir (Coczalkowice reservoir, Poland). Physics and Chemistry of the Earth. https://doi.org/10.1016/j.pce.2015.11.005.

  • Darwishe, H., El Khattabi, J., Chaaban, F., Louche, B., Masson, E., & Carlier, E. (2017). Prediction and control of nitrate concentrations in groundwater by implementing a model based on GIS and artificial neural networks (ANN). Environmental Earth Sciences, 76(19), 649. https://doi.org/10.1007/s12665-017-6990-1.

    Article  Google Scholar 

  • Ford, M., & Tellam, J. H. (1994). Source, type and extent of inorganic contamination within the Birmingham urban aquifer system, UK. Journal Hydrology. https://doi.org/10.1016/0022-1694(94)90074-4.

  • Foster, S. S. D., Cripps, A. C., & Smith-Carington, A. (1982). Nitrate leaching to groundwater. Philosophical Transactions of the Royal Society of London. Series B, Biological Sciences, 296(1082), 477–489.

    Article  CAS  Google Scholar 

  • Healy, R.W. (1990). Simulation of solute transport in variably saturated porous media with supplemental information on modifications to the US Geological Survey’s computer program VS2D. Department of the Interior, US Geological Survey.

  • Johnsson, H., Bergström, L., Jansson, P. E., & Paustian, K. (1987). Simulated nitrogen dynamics and losses in a layered agricultural soil. Agriculture, Ecosystems & Environment. https://doi.org/10.1016/0167-8809(87)90099-5.

  • Lafrance, P., & Banton, O. (1995). Implication of spatial variability of organic carbon on predicting pesticide mobility in soil. Geoderma, 65(3–4), 331–338. https://doi.org/10.1016/0016-7061(94)00051-B.

    Article  CAS  Google Scholar 

  • Lappala, E. G. (1981). Modeling of water and solute transport under variably saturated conditions. In an interagency workshop, modeling and low-level waste management (pp. 81–116). 1980 Proceedings, Denver.

  • Laura, K. L., & Siegel, D. I. (2006). Modeling surface and ground water mixing in the hyporheic zone using MODFLOW and MT3D. Advances in Water Resources. https://doi.org/10.1016/j.advwatres.2005.12.003.

  • Lerner, D. N., Yang, Y., Barrett, M. H., & Tellam, J. H. (1999). Loadings of non-agricultural nitrogen in urban groundwater (pp. 117–124). IAHS Publications. http://hydrologie.org/redbooks/a259/iahs_259_0117.pdf. Accessed 21 Mar 2018.

  • McDonald, M. G., & Harbaugh, A. W. (1988). MODFLOW: a modular three dimensional finite difference ground water model, Open File Report 83–875. Washington: US Geological Survey.

    Google Scholar 

  • Reza Alizadeh, M., Reza Nikoo Gholam, M., & Reza Rakhshandehroo, G. (2017). Hydro-environmental management of groundwater resources: a fuzzy-based multi-objective compromise approach. Journal of Hydrology. https://doi.org/10.1016/j.jhydrol.2017.06.011.

  • Ritchie, J. T. (1991). Wheat phasic development. In J. Hanks & J. T. Ritchie (Eds.), Modeling plant and soil systems (pp. 31–54). Madison: Agronomy Monograph, 31, American Society of Agronomy, Crop Science Society of America, Sol Society Soil of America. https://doi.org/10.2134/agronmonogr31.c1.

  • Schroder, H., Harremoës, P., & Simonsen, J.F. (1985). Water pollution caused by nitogen from urban wastewater and from agriculture. Conference Nitrates in water. Paris.

  • Serhal, H., Bernard, D., El Khattabi, J., Lacherez-Bastin, S., & Shahrour, I. (2009). Impact of fertilizer application and urban wastes on the quality of groundwater in the Cambrai chalk aquifer, Northern France. Environmental Geology. https://doi.org/10.1007/s00254-008-1433-7.

  • Van Genuchten, M. (1980). A closed-form equation for predicting the hydraulic conductivity of unsaturated soils. Journal of Soil Sciences, 44, 892–898.

  • Zheng, C. C. (1990). MT3D, a modular three-dimensional transport model. S_S. Report to the U.S. Environmental Protection Agency. Rockville: Papadopulos and Associates.

    Google Scholar 

  • Zheng, C. C., & Wang, K. (1999). MT3DMS—a modular three dimensional multispecies transport model for simulation of advection, dispersion and chemical reactions of contaminants in groundwater systems, Contract report SERD99–1. United States: U.S. Army Corps of Engineers.

    Google Scholar 

  • Zhu, Y., Yang, J., Ye, M., Sun, H., & Shi, L. (2017). Development and application of a fully integrated model for unsaturated-saturated nitrogen reactive transport. Agricultural Water Management. https://doi.org/10.1016/j.agwat.2016.10.017.

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Jamal El Khattabi.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

El Khattabi, J., Louche, B., Darwishe, H. et al. Impact of Fertilizer Application and Agricultural Crops on the Quality of Groundwater in the Alluvial Aquifer, Northern France. Water Air Soil Pollut 229, 128 (2018). https://doi.org/10.1007/s11270-018-3767-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s11270-018-3767-4

Keywords

Navigation