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A multi-functional 3D polymolybdate-based copper(II) complex based on an asymmetric pyridyl-amide ligand: synthesis, structure and properties

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Abstract

A polymolybdate-based metal–organic compound {H2[Cu2(L)2(Mo8O27)(H2O)4]} (1) [L = N-(pyridin-3-yl)isonicotinamide] has been synthesized under solvothermal (methanol–water mixed solvent) conditions and structurally characterized by single-crystal X-ray diffraction. Compound 1 exhibits a 3D metal–organic network containing unusual 1D [Mo8O27] 6n− n inorganic chains, with adjacent 1D chains connected by Cu(II) atoms and L ligands to form a 3D framework with a trinodal 4,4,6-connected {42.63.8}2{44.68.83} topology. The electrocatalytic activities of compound 1 and its photocatalytic properties for the degradation of organic dyes have also been investigated.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 21501013, 21401010) and the Program for Distinguished Professor of Liaoning Province (No. 2015399).

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Authors and Affiliations

  1. Faculty of Chemistry and Chemical Engineering, Bohai University, Jinzhou, 121000, People’s Republic of China

    Hong-yan Lin, Ge Song, Yuan Tian, Jia-feng Lin, Xiang Wang & Guo-cheng Liu

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  1. Hong-yan Lin
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  2. Ge Song
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  3. Yuan Tian
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  4. Jia-feng Lin
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  5. Xiang Wang
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  6. Guo-cheng Liu
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Correspondence to Hong-yan Lin or Guo-cheng Liu.

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Lin, Hy., Song, G., Tian, Y. et al. A multi-functional 3D polymolybdate-based copper(II) complex based on an asymmetric pyridyl-amide ligand: synthesis, structure and properties. Transit Met Chem 43, 185–192 (2018). https://doi.org/10.1007/s11243-018-0206-8

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  • DOI: https://doi.org/10.1007/s11243-018-0206-8

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