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An azide-bridged copper(II) 1D-chain with ferromagnetic interactions: synthesis, structure and magnetic studies

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Abstract

A coordination polymer of formula [Cu(μ 1,3-N3)2(imH)2] n (1) has been synthesized by reaction of Cu(NO3)2 with imidazole and sodium azide in CH3OH/CH3CN. The complex was characterized by FTIR, elemental analysis, powder diffraction, thermogravimetric analysis, magnetic measurements, and single-crystal X-ray diffraction. The X-ray crystal structure shows that the Cu(II) centers have a distorted octahedral coordination geometry, being coordinated by two imidazole ligands at the trans positions. Each azide links two [Cu(imH)2]2+ units to form 1D zigzag chains. Variable-temperature magnetic susceptibility studies at low field reveal dominant intrachain ferromagnetic/antiferromagnetic interactions. Using a model with n = 10, the coupling parameters J AF = −2.95 and J F = 17.99 with g = 2.12 have been determined.

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Authors and Affiliations

  1. Department of Chemistry, University of Agriculture, Faisalabad, 38040, Pakistan

    Muhammad Nadeem Akhtar & Sadia Tahir

  2. Department of Chemistry, School of Science, The University of Jordan, Amman, 11942, Jordan

    Murad A. AlDamen

  3. International Institute for Carbon–Neutral Energy Research (I2CNER), Kyushu University, 744 Moto-oka, Nishi-Ku, Fukuoka, 819-0395, Japan

    Masaaki Sadakiyo

  4. Department of Chemistry, The Islamia University of Bahawalpur, Bahawalpur, Pakistan

    Muhammad Farooq Warsi

  5. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, People’s Republic of China

    You Song

Authors
  1. Muhammad Nadeem Akhtar
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  2. Sadia Tahir
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  3. Masaaki Sadakiyo
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  4. Muhammad Farooq Warsi
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  5. Murad A. AlDamen
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  6. You Song
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Correspondence to Muhammad Nadeem Akhtar or Murad A. AlDamen.

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Akhtar, M.N., Tahir, S., Sadakiyo, M. et al. An azide-bridged copper(II) 1D-chain with ferromagnetic interactions: synthesis, structure and magnetic studies. Transit Met Chem 42, 635–641 (2017). https://doi.org/10.1007/s11243-017-0169-1

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  • DOI: https://doi.org/10.1007/s11243-017-0169-1

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