Skip to main content
SpringerLink
Log in

Organophosphine ligands in PtPX2Y and PtPXYZ complexes; structural aspects

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Abstract

This review covers over ninety platinum complexes with PtPX2Y and PtPXYZ inner coordination spheres, in which the P-donor ligands are organomonophosphines. These complexes crystallize in four crystal systems: tetragonal (×3), orthorhombic (×17), triclinic (×20) and monoclinic (×56). Complexes with the PtPX2Y chromophore exist in cis- as well as trans-configurations; however, the latter prevails. There are four types of ligands which create such chromophores: monodentate (H, OL, NL, CO, BL, Cl, SL, Br, SeL and I); homobidentate (O2L, N2L, S2L, Se2L and As2L); heterobidentate (O/N, O/S, N/S, N/Se and N/Te); and heterotridentate (O/O/N, N/N/S, N/N/Se, O/S/S, Se/N/Se and O/N/S). The chelating ligands create four-, five- and six-membered metallocycles, and the effects of both steric and electronic factors can be seen from the values of the L–Pt–L bite angles. The structural parameters are analyzed and discussed, with particular attention to trans-effects. Three types of isomerism are identified, namely cis–trans, distortion and ligands.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

Abbreviations

As7 :

Hepta-arsatricyclo(2.2.1.03,5)heptane

BC6H7NI:

Iodo-(4-methylpyridine)boryl

C4H10NSe:

2-(N,N-dimethylamino)ethaneselenolate

C4H3NO:

1-Aza-4-oxo-1,3-butadiene

C5H11NSe:

2-(N,N-dimethylamino)propane-1-selenolate

C5H12NS:

2-(Dimethylamino)propane-1-thiolate

C5H13N:

2-Methylbutan-1-amine

C5H7O2 :

Acetylacetonate

C6H11N:

1-Methyl-1,4,5,6-tetrahydropyrimidine

C6H5N2O:

Pyridine-2′-carboxamidate

C6H7NOS:

2-(Methylsulphinyl)pyridine

C8H11NOS:

2-(n-Propylsulphinyl)pyridine

C8H8N3O:

Salicylaldehyde thiosemicarbazone

C10H10N2 :

Diaziridine-adamantane

C10H10NO2 :

1,2,3,4-Tetrahydro-isoquinoline-3-carboxylate

C10H12NO:

Quinoline-8-carbaldehyde

C10H16N2 :

2,9-Dimethyl-1,10-phenanthroline

C10H7 :

Naphthyl

C11H9N3OS:

2-Oxyacetophenone-thiosemicarbazonate

C12H16N2O4Se2 :

Diethyl-3,3′-(diazene-1,2-diyl-N)-bis(2-(hydroseleno)butenoalate

C12H6N2O2 :

1,10-Phenanthroline-5,6-dione

C13H9NO2 :

N-(α,α′-dioxobenzylidene)anilinate

C14H10N2O3 :

2-(2′-Carboxylatophenylazo)-4-methylphenolate

C14H11N2O:

N-(α-aminobenzylidene)anthranilaldehydate

C14H15N3 :

1,3-Bis(p-tolyl)triazene

C15H14NS:

2-(1-(p-Tolylimino)ethyl)benzenethiolate

C16H13N3O3S2 :

4-Nitrobenzyl(1-(2-oxidophenyl)ethylidene)carbonodithiohydrazonate

C16H14N2OS2 :

Benzyl(1-(2-oxidophenyl)ethylidene)carbonodithiohydrazonate

C18H16N2OS2 :

Benzyl(4-oxido-4-phenylbut-3-en-2-ylidene)carbonodithiohydrazonate

C18H36N2O6 :

4,7,13,16,21,24-Hexaoxa-1,10-diazabicyclo(8.8.8)hexacosane[2.2.2-cryptand]

C19H13ClN2S2 :

6-Chloro-2-(diphenylphosphorothionyl)

C19H13ClN2S2 :

6-Chloro-2-((diphenylphosphorothioyl)imino)-1,3-benzothiazol-3(2H)-yl

C20H31N9S2 :

3,5-Diacetyl-1,2,4-triazolate bis(4-cyclohexylthiosemicarbazonate)

C21H15N2 :

3,5-Diphenyl-2-(pyridin-2-yl)-1H-pyrazol-1-yl

C28H24N4S2 :

PhSNC(MeC6H4)N–NC(MeC6H4)NSPh

C28H24N4Se2 :

PhSeNC(MeC6H4)N–NC(MeC6H4)NSePh

C29H30F6OS:

1,1,1,3,3,3-Hexafluoro-2(2-((1,2,2-triphenyl-2-(sulfanyl)ethyl)sulfanyl) phenyl)propan-2-thiolate

C40H38N2P2 :

1,1-(Bis(p-tolylimino)diphenylphospharanyl)ethane

NH = C(OMe)(Me):

1-Imino-1-methoxyethane

S2C5H8N:

Pyrrolidine-1-carbodithiolate

SC4H3N2 :

Pyrimidine-2-thiolate

SC6H4NO2 :

2-Mercaptonicotinic acid

SC6H8N3 :

Benzaldehyde thiosemicarbazonate

SeC6H5N2O:

2-(Selanyl)nicotinamidate

References

  1. Melník M, Mikuš P (2014) Phosphorus, sulfur, silicon. Relat Elem 189:1289

    Article  Google Scholar 

  2. Melník M, Mikuš P (2015) Phosphorus, sulfur, silicon. Relat Elem 190:1769

    Google Scholar 

  3. Melník M, Mikuš P (2015) Rev Inorg Chem 35:179

    Google Scholar 

  4. Melník M, Mikuš P (2016) Rev Inorg Chem 36:43

    Article  Google Scholar 

  5. Melník M, Mikuš P, Rev Inorg Chem (in press)

  6. Motsche H, Nussbaumer C, Pregosin PS, Bachechi F, Mura P, Zambonelli L (1980) Helv Chim Acta 63:2071

    Article  Google Scholar 

  7. Halder S, Drew MGB, Bhattacharya S (2008) J Chem Sci (Bangalone India) 120:441

    Article  CAS  Google Scholar 

  8. De Pascali SA, Papadia P, Capoocia S, Marchio L, Lanfranchi M, Ciccarese A, Fanizzi FP (2009) Dalton Trans 7786

  9. Giardina-Papa D, Intini FP, Natile G, Pacifico C (2012) Acta Crystallogr Sect C 68:m300

    Article  CAS  Google Scholar 

  10. Kozelka J, Bois C (1988) Inorg Chem 27:3860

    Article  Google Scholar 

  11. Albinati A, Lianza F, Muller B, Pregosin PS (1993) Inorg Chim Acta 208:119

    Article  CAS  Google Scholar 

  12. Mc Bee JL, Tilley TD (2010) Organometallics 29:184

    Article  CAS  Google Scholar 

  13. Okamura R, Fujihara T, Wada T, Tanaka K (2006) Bull Chem Soc Jpn 79:106

    Article  CAS  Google Scholar 

  14. Avis MW, Elsevier CJ, Veldman N, Kooijman H, Spek AL (1996) Inorg Chem 35:1518

    Article  CAS  Google Scholar 

  15. Jircitano AJ, Rohly JG, Bowman Mertes K (1981) J Am Chem Soc 103:4879

    Article  CAS  Google Scholar 

  16. Huh HS, Lee YK, Lee SW (2006) J Mol Struct 789:209

    Article  CAS  Google Scholar 

  17. Chivers T, McGregor K, Parvez M (1993) J Chem Soc Chem Commun 1021

  18. Matesanz AI, Perles J, Souza P (2012) Dalton Trans 12538

  19. Chivers T, Mc Gregor K, Parvez M (1994) Inorg Chem 33:2364

    Article  CAS  Google Scholar 

  20. Rath NP, Fallis KA, Andeson GK (1993) Acta Crystallogr Sect C 49:2079

    Article  Google Scholar 

  21. Pryadun RS, Gerlits OO, Atwood JD (2006) J Coord Chem 59:85

    Article  CAS  Google Scholar 

  22. Dell’Amico DB, Labella L, Marchetti F, Samaritani S (2012) Dalton Trans 1389

  23. Dell’Amico DB, Broglia C, Labella L, Marchetti F, Mendola D, Samaritani S (2013) Inorg Chim Acta 395:181

    Article  Google Scholar 

  24. Fanizzi FP, Lanfranchi M, Natile G, Tiripicchio A (1994) Inorg Chem 33:3331

    Article  CAS  Google Scholar 

  25. Cetinkaya B, Özdemir I, Tahir MN, Ülkii D (1998) J Organomet Chem 561:7

    Article  CAS  Google Scholar 

  26. Colquhoun HM, Stoddart JF, Williams DJ (1981) J Chem Soc Chem Commun 847

  27. Alston DR, Slawin AMZ, Stoddart JF, Williams DJ, Zarzycki R (1988) Angew Chem Int Ed Engl 27:1184

    Article  Google Scholar 

  28. Cameron BR, Corrent SS, Loeb SJ (1995) Angew Chem Int Ed Engl 34:2689

    Article  CAS  Google Scholar 

  29. Bachechi F, Mura P, Zambonelli L (1980) Acta Crystallogr Sect B 36:3604

    Article  Google Scholar 

  30. Albinati A, Pregosin PS, Wombacher F (1990) Inorg Chem 29:1812

    Article  CAS  Google Scholar 

  31. Adedapo A, Chaloner PA, Hitchcock PB, Al-Juad SS (1993) J Chem Res (M) 205:1312

    Google Scholar 

  32. Cetinkaya B, Cetinkaya E, Hitchcock PB, Lappert MF, Özdemir I (1997) J Chem Soc Dalton Trans 1359

  33. Chivers T, Hilts RW, Krouse IH, Cordes AW, Hallford R, Scott SR (1992) Can J Chem 70:2602

    Article  CAS  Google Scholar 

  34. van Vliet MRP, van Koten G, van Beek JAM, Vrieze K, Muller F, Stam CH (1986) Inorg Chim Acta 112:77

    Article  Google Scholar 

  35. Adedapo A, Avent AG, Carmichael D, Chaloner PA, Hitchcock PB, Wagenaar A (1993) J Chem Soc Chem Commun 186

  36. Albinati A, Anklin CG, Ganazolli F, Rüegg H, Pregosin PS (1987) Inorg Chem 26:503

    Article  CAS  Google Scholar 

  37. Ambuehl J, Pregosin PS, Venanzi LM, Consiglio G, Bachechi F, Zambonelli L (1979) J Organomet Chem 181:255

    Article  CAS  Google Scholar 

  38. Bachechi F, Zambonelli L (1985) Acta Crystallogr Sect C 41:835

    Article  Google Scholar 

  39. Bachechi F, Zambonelli L (1989) J Cryst Spectr Res 19:299

    Article  CAS  Google Scholar 

  40. Bachechi F, Cellai L, Sparapani B, Paradisi MP (1989) J Chem Res (M) 8:158

    Google Scholar 

  41. Quiroga AG, Ramos-Lima FJ, Alvarez-Valdes A, Font-Bardia M, Bergamo A, Sava G, Navaro-Ranninger C (2011) Polyhedron 30:1646

    Article  CAS  Google Scholar 

  42. Ramos-Lima FJ, Quiroga AG, Garcia-Serrelde B, Blanco F, Carnero A, Navarro-Raninger C (2007) J Med Chem 50:2194

    Article  CAS  Google Scholar 

  43. Ramos-Lima FJ, Quiroga AG, Perez JM, Font-Bardia M, Solans X, Navarro-Raninger C (2003) Eur J Inorg Chem 2003:1591

    Article  Google Scholar 

  44. Adams CJ, Anderson KM, Baber RA, Connelly NG, Kandiah M, Orpen AG (2004) Dalton Trans 3353

  45. de Sousa GF, Filgueiras CAL, Marcarenhas YP, de Azevedo WF Jr (2002) Transit Met Chem 27:433

    Article  Google Scholar 

  46. Hubel R, Polborn K, Knizek J, Noth H, Beck W (2000) Z Anorg Allg Chem 626:1701

    Article  CAS  Google Scholar 

  47. Khan MNJ, King C, Fackler JP Jr, Winpenny REP (1993) Inorg Chem 32:2502

    Article  CAS  Google Scholar 

  48. Abicht HP, Jurkschat K, Peters K, Peters EM, von Schnering HG (1989) J Organomet Chem 364:415

    Article  CAS  Google Scholar 

  49. Michaud-Soret I, Kozelka J, Bois C (1993) Acta Crystallogr Sect C 49:589

    Article  Google Scholar 

  50. Kano N, Kusaka S, Kawashima T (2010) Dalton Trans 456

  51. Scherer OJ, Forstinger K, Kaub J, Sheldrick WS (1986) Chem Ber 119:2731

    Article  CAS  Google Scholar 

  52. Lobana TS, Kaur P, Hundal G, Butcher RJ, Castineiras A (2008) Z Anorg Chem 634:747

    Article  CAS  Google Scholar 

  53. Quital SMO, Nogueira HIS, Felix V, Drew MGB (2002) J Chem Soc Dalton Trans 4479

  54. Lobana TS, Bawa G, Hundal G, Zeller M (2008) Z Anorg Allg Chem 634:931

    Article  CAS  Google Scholar 

  55. Hursthouse MB, Short RL, Kelly PF, Woollins JD (1988) Acta Crystallogr Sect C 44:1731

    Article  Google Scholar 

  56. Chan LT, Chen HW, Fackler JP Jr, Masters AF, Pan WH (1982) Inorg Chem 21:4291

    Article  CAS  Google Scholar 

  57. Montagner D, Miguel PJS (2011) Dalton Trans 40:10809

    Article  CAS  Google Scholar 

  58. Grant GJ, Galas DF, van Derveer DG (2002) Polyhedron 21:879

    Article  CAS  Google Scholar 

  59. Browning J, Beveridge KA, Bushnell GW, Dixon KR (1986) Inorg Chem 25:1987

    Article  CAS  Google Scholar 

  60. Williams DJ, Slawin AMZ, Phillips JR, Woollins JD (1996) Polyhedron 15:3175

    Article  CAS  Google Scholar 

  61. Beni Z, Ros R, Scopelliti R, Roulet R (2005) Dalton Trans 315

  62. De Renzi A, Di Blasio B, Panunzi A, Pedone C, Vitagliano A (1976) Gazz Chim Ital 106:709

    Google Scholar 

  63. Chuahan RS, Prabhu CP, Phandis PP, Kedamath G, Golen JA, Rheingold AL, Jain VK (2013) J Organomet Chem 723:163

    Article  Google Scholar 

  64. Chaudheery S, Jain VK, Patch RP (1996) J Chem Res (M) 486:2801

    Google Scholar 

  65. Arsenyan P, Oberte K, Rubina K, Belyakov S (2005) Tetrahedron Lett 46:1001

    Article  CAS  Google Scholar 

  66. Kelly PF, Slawin AMZ, Williams DJ, Woollins JD (1989) J Chem Soc Chem Commun 408

  67. Kesanli B, Charles S, Lam YF, Bott SG, Fettinger J, Eichhorn B (2000) J Am Chem Soc 122:11101

    Article  CAS  Google Scholar 

  68. Fanizzi FP, Maresca L, Natile G, Lanfranchi M, Tiripicchio A, Pacchioni G (1992) J Chem Soc Chem Commun 4:333

    Article  Google Scholar 

  69. Braunschweig H, Brenner PB, Dewhurst RD, Radacki K (2013) Z Naturforsch B Chem Sci 68:747

    Article  CAS  Google Scholar 

  70. Lombardi A, Maglio O, Pavone V, Di Blasio B, Saviano M, Nastri F, Pedone C, Benedetti E (1993) Inorg Chim Acta 204:87

    Article  CAS  Google Scholar 

  71. Ambach E, Nagel U, Beck W (1983) Chem Ber 116:659

    Article  CAS  Google Scholar 

  72. Kühlwein F, Polborn K, Beck W (1997) Z Anorg Allg Chem 623:1931

    Article  Google Scholar 

  73. Koch D, Polborn K, Sunkel K, Beck W (2002) Inorg Chim Acta 334:365

    Article  CAS  Google Scholar 

  74. Henderson W, McCaffrey LJ, Nicholson BK (2000) J Chem Soc Dalton Trans 16:2753

    Article  Google Scholar 

  75. da Maia SPI, de Femandez AAG, Silva JJN, Andricopulo AD, Lemos SS, Lang ES, Abram U, Deflon VM (2010) J Inorg Biochem 104:1276

    Article  CAS  Google Scholar 

  76. Halder S, Butcher RJ, Bhattacharya S (2007) Polyhedron 26:2741

    Article  CAS  Google Scholar 

  77. Ghavale N, Wadawale A, Dey S, Jain VK (2010) J Organomet Chem 695:2296

    Article  CAS  Google Scholar 

  78. Dey S, Kumbhare LB, Jain VK, Schurr T, Kaim W, Klein A, Belaj F (2004) Eur J Inorg Chem 2004:4510

    Article  Google Scholar 

  79. Krinsky JL, Arnold J, Bergman RG (2007) Organometallics 26:897

    Article  CAS  Google Scholar 

  80. Coles SJ, Dale SH, Elsegood MRJ, Gaw KG, Gelbuch T, Hursthouse MB, Light MF, Noble TA, Smith MB (2012) Eur J Inorg Chem 859

  81. Jones R, Kelly PF, Williams DJ, Woollins JD (1988) J Chem Soc Dalton Trans 1569

  82. Dey S, Jain VK, Knodler A, Kaim W, Zalis S (2001) Eur J Inorg Chem 2001:2965

    Article  Google Scholar 

  83. Dey S, Jain VK, Knodler A, Klein A, Kaim W, Zalis S (2002) Inorg Chem 41:2864

    Article  CAS  Google Scholar 

  84. Beni Z, Ros R, Tassan A, Scopelliti R, Roulet R (2005) Dalton Trans 315

  85. Melník M (1982) Coord Chem Rev 47:239

    Article  Google Scholar 

  86. Melník M, Holloway CE (2006) Coord Chem Rev 250:2261

    Article  Google Scholar 

Download references

Acknowledgements

This work was supported by the Projects VEGA 1/0873/15 and KEGA 022UK-4/2015.

Author information

Authors and Affiliations

  1. Department of Pharmaceutical Analysis and Nuclear Pharmacy, Faculty of Pharmacy, Comenius University in Bratislava, Odbojárov 10, 832 32, Bratislava, Slovak Republic

    Milan Melník & Peter Mikuš

  2. Faculty of Pharmacy, Toxicological and Antidoping Center, Comenius University in Bratislava, Odbojárov 10, 832 32, Bratislava, Slovak Republic

    Milan Melník & Peter Mikuš

Authors
  1. Milan Melník
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Peter Mikuš
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Milan Melník.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Melník, M., Mikuš, P. Organophosphine ligands in PtPX2Y and PtPXYZ complexes; structural aspects. Transit Met Chem 42, 491–501 (2017). https://doi.org/10.1007/s11243-017-0153-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11243-017-0153-9

Search

Navigation