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Pyridine-2,5-dicarboxylic acid complexes of nickel(II) with 2,2′-bipyridine and 1,10-phenanthroline coligands; syntheses, crystal structures, spectroscopic and thermal studies

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Abstract

Two pyridine-2,5-dicarboxylic acid (pydcH2) complexes of nickel(II) with 2,2′-bipyridine and 1,10-phenanthroline were synthesized and characterized by elemental, spectroscopic, thermal analysis, magnetic measurements and single crystal X-ray diffraction techniques. Both [Ni(pydc)(bipy)2]·7H2O and [Ni(pydc)(phen)2]·6.5H2O crystallize in the monoclinic system and P21/c space group. The Ni(II) ions are coordinated by two bidentate bipy or phen ligands and one pydc dianion in a distorted octahedral geometry. The pydc ligand is coordinated through the pyridine nitrogen atom and oxygen atom of carboxyl group as a bidentate ligand. Both carboxylate groups of pydc are deprotonated but only the 2-carboxylate is coordinated to the metal. Thermal decompositions of the complexes have been studied over the range 30–600 °C on heating in a static air atmosphere.

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Acknowledgments

This work was supported by the Dumlupinar University by project No 2007/14.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Arts and Sciences, Dumlupınar University, 43820, Kütahya, Turkey

    Alper Tolga Çolak & Demet Akduman

  2. Department of Chemistry, Faculty of Arts and Sciences, Eskişehir Osmangazi University, 26480, Eskişehir, Turkey

    Okan Zafer Yeşilel

  3. Department of Physics, Faculty of Arts and Sciences, Ondokuz Mayıs University, 55139, Kurupelit, Samsun, Turkey

    Orhan Büyükgüngör

Authors
  1. Alper Tolga Çolak
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  2. Demet Akduman
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  3. Okan Zafer Yeşilel
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  4. Orhan Büyükgüngör
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Correspondence to Alper Tolga Çolak.

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Çolak, A.T., Akduman, D., Yeşilel, O.Z. et al. Pyridine-2,5-dicarboxylic acid complexes of nickel(II) with 2,2′-bipyridine and 1,10-phenanthroline coligands; syntheses, crystal structures, spectroscopic and thermal studies. Transition Met Chem 34, 861–868 (2009). https://doi.org/10.1007/s11243-009-9275-z

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  • DOI: https://doi.org/10.1007/s11243-009-9275-z

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