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1D and 2D solid-state metallosupramolecular arrays of freebase 5,10,15,20-tetra(4-pyridyl)porphyrin, peripherally linked by zinc and manganese ions

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Abstract

Freebase 5,10,15,20-tetra(4-pyridyl)porphyrin (TPyP) is able to assemble into crystalline rigid 1D and 2D metallosupramolecular arrrays via exocyclic coordination with tetracoordinate and hexacoordinate metal ions, respectively. In this contribution we report on two coordination polymers of μ 4-bridging freebase TPyP with zinc and manganese halide moieties. The structure of [(ZnBr2)2TPyP] · 6 TCE (2) (TCE = 1,1,2,2-tetrachloroethane) consists of 1D polymeric chains. The topology of [(MnCl2)TPyP] · 6 TCE (3) is the (4,4) square grid type. The crystal structure of the known compound [(HgI2)2TPyP] · 4 TCE (1) was redetermined by X-ray crystallography.

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Acknowledgments

The authors thank Dr. Eckhard Bill and Andreas Göbels (Max-Planck-Institut für Bioanorganische Chemie) for performing the magnetic susceptibility measurement and Dr. Harish Parala (Lehrstuhl für Anorganische Chemie II, Ruhr-Universität Bochum) for the thermal analysis. Professor William S. Sheldrick is gratefully acknowledged for supporting our work. Financial support from the Deutsche Forschungsgemeinschaft (DFG) is gratefully acknowledged.

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  1. Lehrstuhl für Analytische Chemie, Ruhr-Universtät Bochum, 44780, Bochum, Germany

    Rüdiger W. Seidel & Iris M. Oppel

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  1. Rüdiger W. Seidel
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  2. Iris M. Oppel
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Correspondence to Iris M. Oppel.

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Seidel, R.W., Oppel, I.M. 1D and 2D solid-state metallosupramolecular arrays of freebase 5,10,15,20-tetra(4-pyridyl)porphyrin, peripherally linked by zinc and manganese ions. Struct Chem 20, 121–128 (2009). https://doi.org/10.1007/s11224-009-9418-z

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