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Nitronyl-nitroxide PCP-pincer complexes of palladium and nickel: synthesis and an EPR study

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Abstract

The possibility of the application of nitronyl-nitroxide ligand (NIT) as a spin label for the study of the composition of transition metals complexes with M-NIT bonds by EPR spectroscopy was explored using PCP-pincer complexes of Pd and Ni as examples.

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Funding

This work was performed within the framework of the state task (theme No. 44.1) using the equipment of the Center of Collective Usage “Analytic center of IOMC RAS” under financial support in the framework of the grant “Ensuring the development of the material and technical infrastructure of centers for the collective usage by scientific equipment” (unique identifier RF-2296.61321X0017, agreement No. 075-15-2021-670).

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Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 Tropinina ul., 603137, Nizhny Novgorod, Russia

    K. A. Kozhanov, V. K. Cherkasov & M. P. Bubnov

Authors
  1. K. A. Kozhanov
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  2. V. K. Cherkasov
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  3. M. P. Bubnov
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Corresponding author

Correspondence to K. A. Kozhanov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1527–1532, July, 2022.

No human or animal subjects were used in this research.

The authors declare no competing interests.

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Kozhanov, K.A., Cherkasov, V.K. & Bubnov, M.P. Nitronyl-nitroxide PCP-pincer complexes of palladium and nickel: synthesis and an EPR study. Russ Chem Bull 71, 1527–1532 (2022). https://doi.org/10.1007/s11172-022-3560-9

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  • DOI: https://doi.org/10.1007/s11172-022-3560-9

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