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Mercury derivatives of polyhedral boranes, carboranes, and metallacarboranes

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Russian Chemical Bulletin Aims and scope

Abstract

The review concerns the synthesis, structure, and chemical transformations of mercury derivatives of various polyhedral boron hydrides (carboranes, metallacarboranes, and boranes) and covers a period of time since the pioneering studies of Prof. V. I. Bregadze on chemistry of C- and B-substituted derivatives of icosahedral carboranes C2B10H12 up to date. The emphasis is placed on recent results obtained in this field, in particular, Hg-promoted substitution in nido-carboranes as well as the synthesis and properties of mercury derivatives of monocarbon carborane anion [CB11H12]–.

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  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    I. B. Sivaev & M. Yu. Stogniy

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  1. I. B. Sivaev
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Dedicated to Professor V. I. Bregadze on the occasion of his 80th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 0217–0253, February, 2019.

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Sivaev, I.B., Stogniy, M.Y. Mercury derivatives of polyhedral boranes, carboranes, and metallacarboranes. Russ Chem Bull 68, 217–253 (2019). https://doi.org/10.1007/s11172-019-2379-5

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