Abstract
This study synthesized a layered porous MOFs Cu-BDC by a simple solvothermal method, and the adsorption effect of materials on U(VI) were investigated by static adsorption experiments. The results show that the adsorption capacity of U(VI) reaches the maximum at 298.15 K pH = 6, with a maximum value of 1128.35 mg·g−1. Langmuir and Freundlich isotherm equations were used to fit the thermodynamic data, which were more consistent with Langmuir Isotherm model. Adsorption kinetics experiments show that Cu-BDC reaches adsorption equilibrium at 200 min, and the adsorption process is closer to the Pseudo-first-order kinetic equation, and the adsorption process is dominated by chemical control, physical control, and chemical control work together. Thermodynamics results indicate the spontaneous nature of U(VI) adsorption process onto Cu-BDC. In addition, The unique porous Layered structure and abundant active sites are the reasons for the high adsorption capacity of the materials.
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References
Michaelides EE, Michaelides DN (2020) Impact of nuclear energy on fossil fuel substitution. Nucl Eng Des 366:110742. https://doi.org/10.1016/j.nucengdes.2020.110742
Wang Z, Meng Q, Ma R, Wang Z, Yang Y, Sha H, Ma X, Ruan X, Zou X, Yuan Y, Zhu G (2020) Constructing an ion pathway for uranium extraction from seawater. Chem 6:1683–1691. https://doi.org/10.1016/j.chempr.2020.04.012
Sun Z, Chen D, Chen B, Kong L, Su M (2018) Enhanced uranium(VI) adsorption by chitosan modified phosphate rock. Colloids Surf, A 547:141–147. https://doi.org/10.1016/j.colsurfa.2018.02.043
Li N, Gao P, Chen H, Li F, Wang Z (2022) Amidoxime modified Fe3O4@TiO2 particles for antibacterial and efficient uranium extraction from seawater. Chemosphere 287:137. https://doi.org/10.1016/j.chemosphere.2021.132137
Tsouris C (2017) Uranium extraction: fuel from seawater. Nat Energy 2:7546. https://doi.org/10.1038/nenergy.2017.22
Hu J, Lv Y, Cui W, Chen W, Li S (2019) Study on treatment of uranium-containing wastewater by biosorption. IOP Conference Series: Earth and Environmental Science 330:032029. https://doi.org/10.1088/1755-1315/330/3/032029
Faa A, Gerosa C, Fanni D, Floris G, Eyken PV, Lachowicz JI, Nurchi VM (2018) Depleted uranium and human health. Curr Med Chem 25:49–64. https://doi.org/10.2174/0929867324666170426102343
Rump A, Eder S, Lamkowski A, Hermann C, Abend M, Port M (2019) A quantitative comparison of the chemo—and radiotoxicity of uranium at different enrichment grades. Toxicol Lett 313:159–168. https://doi.org/10.1016/j.toxlet.2019.07.004
Kulkarni S, Ballal A, Apte SK (2013) Bioprecipitation of uranium from alkaline waste solutions using recombinant Deinococcus radiodurans. J Hazard Mater 262:853–861. https://doi.org/10.1016/j.jhazmat.2013.09.057
Zhu X, Alexandratos SD (2015) Development of a new ion-exchange/coordinating phosphate ligand for the sorption of U(VI) and trivalent ions from phosphoric acid solutions. Chem Eng Sci 127:126–132. https://doi.org/10.1016/j.ces.2015.01.027
Tang N, Liang J, Niu C, Wang H, Luo Y, Xing W, Ye S, Liang C, Guo H, Guo J, Zhang Y, Zeng G (2020) Amidoxime-based materials for uranium recovery and removal. Journal of Materials Chemistry A 8:7588–7625. https://doi.org/10.1039/c9ta14082d
Li N, Yang L, Ji X, Ren J, Gao B, Deng W, Wang Z (2020) Bioinspired succinyl-β-cyclodextrin membranes for enhanced uranium extraction and reclamation. Environ Sci Nano 7:3124–3135. https://doi.org/10.1039/d0en00709a
Liu T, Zhang X, Wang H, Chen M, Yuan Y, Zhang R, Xie Z, Liu Y, Zhang H, Wang N (2021) Photothermal enhancement of uranium capture from seawater by monolithic MOF-bonded carbon sponge. Chem Eng J 412:1221. https://doi.org/10.1016/j.cej.2021.128700
Yuan Y, Zhao S, Wen J, Wang D, Guo X, Xu L, Wang X, Wang N (2019) Rational design of porous nanofiber adsorbent by blow-spinning with ultrahigh uranium recovery capacity from seawater. Adv Func Mater 29:1258. https://doi.org/10.1002/adfm.201805380
Ma F, Gui Y, Liu P, Xue Y, Song W (2020) Functional fibrous materials-based adsorbents for uranium adsorption and environmental remediation. Chem Eng J 390:124597. https://doi.org/10.1016/j.cej.2020.124597
Acharya R, Lenka A, Parida K (2021) Magnetite modified amino group based polymer nanocomposites towards efficient adsorptive detoxification of aqueous Cr (VI): A review. J Mol Liq. https://doi.org/10.1016/j.molliq.2021.116487
Jun B-M, Lee H-K, Park S, Kim T-J (2021) Purification of uranium-contaminated radioactive water by adsorption: a review on adsorbent materials. Sep Purif Technol 278:119675. https://doi.org/10.1016/j.seppur.2021.119675
Mohamud H, Ivanov P, Russell BC, Regan PH, Ward NI (2018) Selective sorption of uranium from aqueous solution by graphene oxide-modified materials. J Radioanal Nucl Chem 316:839–848. https://doi.org/10.1007/s10967-018-5741-4
Banala UK, Das NPI, Toleti SR (2021) Microbial interactions with uranium: towards an effective bioremediation approach. Environ Technol Innov 21:101254. https://doi.org/10.1016/j.eti.2020.101254
Zhao Z, Cheng G, Zhang Y, Han B, Wang X (2021) Metal-organic-framework based functional materials for uranium recovery: performance optimization and structure/functionality-activity relationships. ChemPlusChem 86:1177–1192. https://doi.org/10.1002/cplu.202100315
Kayan A (2018) Inorganic-organic hybrid materials and their adsorbent properties. Advanced Composites and Hybrid Materials 2:34–45. https://doi.org/10.1007/s42114-018-0073-y
Islamoglu T, Goswami S, Li Z, Howarth AJ, Farha OK, Hupp JT (2017) Postsynthetic tuning of metal-organic frameworks for targeted applications. Acc Chem Res 50:805–813. https://doi.org/10.1021/acs.accounts.6b00577
Yang W, Pan Q, Song S, Zhang H (2019) Metal–organic framework-based materials for the recovery of uranium from aqueous solutions. Inorganic Chemistry Frontiers 6:1924–1937. https://doi.org/10.1039/c9qi00386j
Kang Y-S, Lu Y, Chen K, Zhao Y, Wang P, Sun W-Y (2019) Metal–organic frameworks with catalytic centers: from synthesis to catalytic application. Coord Chem Rev 378:262–280. https://doi.org/10.1016/j.ccr.2018.02.009
Mondol MMH, Jhung SH (2021) Adsorptive removal of pesticides from water with metal–organic framework-based materials. Chem Eng J 421:688. https://doi.org/10.1016/j.cej.2021.129688
Gao M, Liu G, Gao Y, Chen G, Huang X, Xu X, Wang J, Yang X, Xu D (2021) Recent advances in metal-organic frameworks/membranes for adsorption and removal of metal ions. TrAC, Trends Anal Chem 137:226. https://doi.org/10.1016/j.trac.2021.116226
Tchinsa A, Hossain MF, Wang T, Zhou Y (2021) Removal of organic pollutants from aqueous solution using metal organic frameworks (MOFs)-based adsorbents: a review. Chemosphere 284:131393. https://doi.org/10.1016/j.chemosphere.2021.131393
Carson CG, Hardcastle K, Schwartz J, Liu X, Hoffmann C, Gerhardt RA, Tannenbaum R (2009) Synthesis and structure characterization of copper terephthalate metal-organic frameworks. Eur J Inorg Chem 2009:2338–2343. https://doi.org/10.1002/ejic.200801224
Zheng G, Xing Z, Gao X, Nie C, Xu Z, Ju Z (2021) Fabrication of 2D Cu-BDC MOF and its derived porous carbon as anode material for high-performance Li/K-ion batteries. Appl Surf Sci 559:701. https://doi.org/10.1016/j.apsusc.2021.149701
Duan C, Li J, Yang P, Ke G, Zhu C, Zhang S (2019) A facile synthesis of hierarchically porous Cu-BTC for efficient removal of uranium(VI). J Radioanal Nucl Chem 323:317–327. https://doi.org/10.1007/s10967-019-06888-w
Albolkany MK, Liu C, Wang Y, Chen CH, Zhu C, Chen X, Liu B (2021) Molecular surgery at microporous MOF for mesopore generation and renovation. Angew Chem Int Ed Engl 60:14601–14608. https://doi.org/10.1002/anie.202103104
Ahmed I, Hasan Z, Lee G, Lee HJ, Jhung SH (2022) Contribution of hydrogen bonding to liquid-phase adsorptive removal of hazardous organics with metal-organic framework-based materials. Chem Eng J 430:132–596. https://doi.org/10.1016/j.cej.2021.132596
Zhan G, Fan L, Zhao F, Huang Z, Chen B, Yang X, Zhou S-f (2019) Fabrication of ultrathin 2D Cu-BDC nanosheets and the derived integrated MOF nanocomposites. Adv Func Mater 29:62. https://doi.org/10.1002/adfm.201806720
Liu R, Wang ZQ, Liu QY, Luo F, Wang YL (2019) A zinc MOF with carboxylate oxygen-functionalized pore channels for uranium(VI) sorption. Eur J Inorg Chem 2019:735–739. https://doi.org/10.1002/ejic.201801295
Rostamnia S, Alamgholiloo H, Liu X (2016) Pd-grafted open metal site copper-benzene-1,4-dicarboxylate metal organic frameworks (Cu-BDC MOF’s) as promising interfacial catalysts for sustainable Suzuki coupling. J Colloid Interface Sci 469:310–317. https://doi.org/10.1016/j.jcis.2016.02.021
Abdi S, Nasiri M, Mesbahi A, Khani MH (2017) Investigation of uranium (VI) adsorption by polypyrrole. J Hazard Mater 332:132–139. https://doi.org/10.1016/j.jhazmat.2017.01.013
Gupta NK, Kim S, Bae J, Sookim K (2021) Fabrication of Cu(BDC)0.5(BDC-NH2)0.5 metal-organic framework for superior H2S removal at room temperature. Chem Eng J. https://doi.org/10.1016/j.cej.2021.128536
Xu C, Zhang W, Chen Y, Hu G, Liu R, Han Z (2019) Synthesis of NH2-MIL-125/NH2-MIL-125-P@TiO2 and its adsorption to uranyl ions. ChemistrySelect 4:12801–12806. https://doi.org/10.1002/slct.201902745
Li JH, Yang LX, Li JQ, Yin WH, Tao Y, Wu HQ, Luo F (2019) Anchoring nZVI on metal-organic framework for removal of uranium(VI) from aqueous solution. J Solid State Chem 269:16–23. https://doi.org/10.1016/j.jssc.2018.09.013
Lv Z, Wang H, Chen C, Yang S, Chen L, Alsaedi A, Hayat T (2019) Enhanced removal of uranium(VI) from aqueous solution by a novel Mg-MOF-74-derived porous MgO/carbon adsorbent. J Colloid Interface Sci 537:1–10. https://doi.org/10.1016/j.jcis.2018.11.062
Yin Y, Yang H, Xin Z, Zhang C, Xu G, Wang Y, Dong G, Zhang X (2020) β-mCoPc/Cu-BDC composites for oxidation of benzyl alcohol to benzaldehyde. J Coord Chem 73:1503–1515. https://doi.org/10.1080/00958972.2020.1784406
Hu G, Zhang W, Chen Y, Xu C, Liu R, Han Z (2020) Removal of boron from water by GO/ZIF-67 hybrid material adsorption. Environ Sci Pollut Res Int 27:28396–28407. https://doi.org/10.1007/s11356-020-08018-6
Li F, Li X, Cui P, Sun Y (2018) Retracted Article: plasma-grafted amidoxime/metal–organic framework composites for the selective sequestration of U(vi). Environ Sci Nano 5:2000–2008. https://doi.org/10.1039/c8en00583d
Bi C, Zhang C, Ma F, Zhang X, Yang M, Nian J, Liu L, Dong H, Zhu L, Wang Q, Guo S, Lv Q (2021) Growth of a mesoporous Zr-MOF on functionalized graphene oxide as an efficient adsorbent for recovering uranium (VI) from wastewater. Microporous Mesoporous Mater 323:111–223. https://doi.org/10.1016/j.micromeso.2021.111223
Liu L, Fang Y, Meng Y, Wang X, Ma F, Zhang C, Dong H (2020) Efficient adsorbent for recovering uranium from seawater prepared by grafting amidoxime groups on chloromethylated MIL-101(Cr) via diaminomaleonitrile intermediate. Desalination 478:114–300. https://doi.org/10.1016/j.desal.2019.114300
Liu F, Xiong W, Liu J, Cheng Q, Cheng G, Shi L, Zhang Y (2018) Novel amino-functionalized carbon material derived from metal organic framework: a characteristic adsorbent for U(VI) removal from aqueous environment. Colloids Surf, A 556:72–80. https://doi.org/10.1016/j.colsurfa.2018.08.009
Bhaumik M, Maity A, Srinivasu VV, Onyango MS (2012) Removal of hexavalent chromium from aqueous solution using polypyrrole-polyaniline nanofibers. Chem Eng J 181–182:323–333. https://doi.org/10.1016/j.cej.2011.11.088
Prakash Tripathy S, Acharya R, Das M, Acharya R, Parida K (2020) Adsorptive remediation of Cr (VI) from aqueous solution using cobalt ferrite: kinetics and isotherm studies. Mater Today Proc 30:289–293. https://doi.org/10.1016/j.matpr.2020.01.534
Wang Z, Liu Z, Ye T, Wang Y, Zhou L (2020) Removal of uranyl ions from aqueous media by tannic acid-chitosan hydrothermal carbon: equilibria, kinetics and thermodynamics. J Radioanal Nucl Chem 326:1843–1852. https://doi.org/10.1007/s10967-020-07452-7
Xu C, Chen Y, Zhang W, Hu G, Liu R (2021) Layered nanoporous α-Gd2O3 prepared by a Gd–Organic framework template for U(VI) adsorption. ACS Appl Nano Mater 4:1104–1111. https://doi.org/10.1021/acsanm.0c02717
Pukdeejorhor L, Adpakpang K, Ponchai P, Wannapaiboon S, Ittisanronnachai S, Ogawa M, Horike S, Bureekaew S (2019) Polymorphism of mixed metal Cr/Fe terephthalate metal-organic frameworks utilizing a microwave synthetic method. Cryst Growth Des 19:5581–5591. https://doi.org/10.1021/acs.cgd.9b00508
Li W, Liu YY, Bai Y, Wang J, Pang H (2020) Anchoring ZIF-67 particles on amidoximerized polyacrylonitrile fibers for radionuclide sequestration in wastewater and seawater. J Hazard Mater 395:122692. https://doi.org/10.1016/j.jhazmat.2020.122692
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This work is supported by National Natural Science Foundation of China (22266027).
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Wei, Y., Zhang, L. & Chen, Y. Porous layered MOFs (Cu-BDC) for highly efficient uranyl-ion adsorption from aqueous solutions. J Radioanal Nucl Chem 333, 2339–2350 (2024). https://doi.org/10.1007/s10967-024-09469-8
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DOI: https://doi.org/10.1007/s10967-024-09469-8