Skip to main content
Log in

Efficient adsorption of U(VI) using in low-level radioactive wastewater containing organic matter by amino groups modified polyacrylonitrile fibers

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

A kind of amino groups modified polyacrylonitrile fibers (PAN-A) was prepared to extract uranium from organic-containing low-level radioactive wastewater (OC-LLRW). SEM/EDS and FTIR characterization conformed that amino group was triumphant grafed on polyacrylonitrile fibers (PAN) surface. Its adsorption capacity was 492.1 mg g−1 (pH 6.0) and can endure at least five adsorption/desorption cycles under condition of 0.1 mol L−1 HCl solution. This PAN-A can work efficiently in the organic containing waste water (urea, tetrahydrofurfuryl alcohol), while the polyvinylalcohol (PVA) exhibited an apparently suppressive effect. This phenomenon was mainly with respect to the sticky nature of PVA.

Graphical abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

References

  1. He S, Yang Z, Cui X, Zhang X, Niu X (2020) Fabrication of the novel Ag-doped SnS2@InVO4 composite with high adsorption-photocatalysis for the removal of uranium (VI). Chemosphere 260:127548

    Article  CAS  PubMed  Google Scholar 

  2. Tang C, Tang Y, Zhu J, Qiu X, Li J, Xu S (2012) Research and development of fuel element for Chinese 10 MW high temperature gas-cooled reactor. J Nucl Sci Technol 37:802–806

    Article  Google Scholar 

  3. Tang CH, Tang YP, Zhu JG, Zou YW, Li JH, Ni XJ (2002) Design and manufacture of the fuel element for the 10 MW high temperature gas-cooled reactor. Nucl Eng Des 218:91–102

    Article  CAS  Google Scholar 

  4. Fu X, Liang T, Tang Y, Xu Z, Tang C (2004) Preparation of UO2 kernel for HTR-10 fuel element. J Nucl Sci Technol 41:943–948

    Article  CAS  Google Scholar 

  5. Liu H, Wang J (2016) Separation of ammonia from radioactive wastewater by hydrophobic membrane contactor. Prog Nucl Energy 86:97–102

    Article  CAS  Google Scholar 

  6. Ilia R, Liatsou I, Savva I, Vasile E, Vekas L, Marinica O, Mpekris F, Pashalidis I, Krasia-Christoforou T (2017) Magnetoresponsive polymer networks as adsorbents for the removal of U(VI) ions from aqueous media. Eur Polym J 97:138–146

    Article  CAS  Google Scholar 

  7. Lin Y, Liu Y, Zhang S, Xie Z, Wang Y, Liu Y, Dai Y, Wang Y, Zhang Z, Liu Y, Deng S (2021) Electrochemical synthesis of EuVO4 for the adsorption of U(VI): performance and mechanism. Chemosphere 273:128569

    Article  CAS  PubMed  Google Scholar 

  8. Liu R, Zhang W, Chen Y, Wang Y (2020) Uranium (VI) adsorption by copper and copper/iron bimetallic central MOFs. Colloids Surf A Physicochem Eng Asp 587:124334

    Article  CAS  Google Scholar 

  9. Zhong X, Liang W, Lu Z, Qiu M, Hu B (2021) Ultra-high capacity of graphene oxide conjugated covalent organic framework nanohybrid for U(VI) and Eu(III) adsorption removal. J Mol Liq 323:114603

    Article  CAS  Google Scholar 

  10. Pang H, Wu Y, Wang X, Hu B, Wang X (2019) Recent advances in composites of graphene and layered double hydroxides for water remediation: a review. Chem Asian J 14:2542–2552

    Article  CAS  PubMed  Google Scholar 

  11. Ma F, Gui Y, Liu P, Xue Y, Song W (2020) Functional fibrous materials-based adsorbents for uranium adsorption and environmental remediation. Chem Eng J 390:124597

    Article  CAS  Google Scholar 

  12. Cheng Y, He P, Dong F, Nie X, Ding C, Wang S, Zhang Y, Liu H, Zhou S (2019) Polyamine and amidoxime groups modified bifunctional polyacrylonitrile-based ion exchange fibers for highly efficient extraction of U(VI) from real uranium mine water. Chem Eng J 367:198–207

    Article  CAS  Google Scholar 

  13. Huang G, Li W, Liu Q, Liu J, Zhang H, Li R, Li Z, Jing X, Wang J (2018) Efficient removal of uranium(VI) from simulated seawater with hyperbranched polyethylenimine (HPEI)-functionalized polyacrylonitrile fibers. New J Chem 42:168–176

    Article  CAS  Google Scholar 

  14. Ju P, Alali KT, Sun G, Zhang H, Liu Q, Liu J, Yu J, Chen R, Wang J (2021) Swollen-layer constructed with polyamine on the surface of nano-polyacrylonitrile cloth used for extract uranium from seawater. Chemosphere 271:129548

    Article  CAS  PubMed  Google Scholar 

  15. Xu X, Ding X-J, Ao J-X, Li R, Xing Z, Liu X-Y, Guo X-J, Wu G-Z, Ma H-J, Zhao X-Y (2019) Preparation of amidoxime-based PE/PP fibers for extraction of uranium from aqueous solution. Nucl Sci Tech 30:40–52

    Article  Google Scholar 

  16. Şimşek S, Şenol ZM, Ulusoy Hİ (2017) Synthesis and characterization of a composite polymeric material including chelating agent for adsorption of uranyl ions. J Hazard Mater 338:437–446

    Article  PubMed  Google Scholar 

  17. Tang Y, Zhou J, Guo J, Liao X, Shi B (2021) Irradiation-stable hydrous titanium oxide-immobilized collagen fibers for uranium removal from radioactive wastewater. J Environ Manag 283:112001

    Article  CAS  Google Scholar 

  18. Li Z, Meng Q, Yang Y, Zou X, Yuan Y, Zhu G (2020) Constructing amidoxime-modified porous adsorbents with open architecture for cost-effective and efficient uranium extraction. Chem Sci 11:4747–4752

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  19. Deng SB, Bai RB, Chen JP (2003) Aminated polyacrylonitrile fibers for lead and copper removal. Langmuir 19:5058–5064

    Article  CAS  Google Scholar 

  20. Deng S, Zhang G, Wang X, Zheng T, Wang P (2015) Preparation and performance of polyacrylonitrile fiber functionalized with iminodiacetic acid under microwave irradiation for adsorption of Cu(II) and Hg(II). Chem Eng J 276:349–357

    Article  CAS  Google Scholar 

  21. Bhunia P, Chatterjee S, Rudra P, De S (2018) Chelating polyacrylonitrile beads for removal of lead and cadmium from wastewater. Sep Purif Technol 193:202–213

    Article  CAS  Google Scholar 

  22. He N, Li H, Cheng C, Dong H, Lu X, Wen J, Wang X (2020) Enhanced marine applicability of adsorbent for uranium via synergy of hyperbranched poly(amido amine) and amidoxime groups. Chem Eng J 395:125162

    Article  CAS  Google Scholar 

  23. Wang Y, Yu C, Zeng D, Zhang Z, Cao X, Liu Y (2021) High-efficiency removal of U(VI) by mesoporous carbon functionalized with amino group. J Radioanal Nucl Chem 328:951–961

    Article  CAS  Google Scholar 

  24. Zussman E, Chen X, Ding W, Calabri L, Dikin DA, Quintana JP, Ruoff RS (2005) Mechanical and structural characterization of electrospun PAN-derived carbon nanofibers. Carbon 43:2175–2185

    Article  CAS  Google Scholar 

  25. Xu G, Wang L, Xie Y, Tao M, Zhang W (2018) Highly selective and efficient adsorption of Hg(2+) by a recyclable aminophosphonic acid functionalized polyacrylonitrile fiber. J Hazard Mater 344:679–688

    Article  CAS  PubMed  Google Scholar 

  26. Zhuang S, Wang J (2020) Poly amidoxime functionalized carbon nanotube as an efficient adsorbent for removal of uranium from aqueous solution. J Mol Liq 319:114288

    Article  CAS  Google Scholar 

  27. Das S, Samanta A, Kole K, Gangopadhyay G, Jana S (2020) MnO2 flowery nanocomposites for efficient and fast removal of mercury(II) from aqueous solution: a facile strategy and mechanistic interpretation. Dalton Trans 49:6790–6800

    Article  CAS  PubMed  Google Scholar 

  28. Xiao J, Jing Y, Wang X, Yao Y, Jia Y (2018) Preconcentration of uranium(VI) from aqueous solution by amidoxime-functionalized microspheres silica material: kinetics, isotherm and mechanism study. ChemistrySelect 3:12346–12356

    Article  CAS  Google Scholar 

  29. Aslani CK, Amik O (2021) Active Carbon/PAN composite adsorbent for uranium removal: modeling adsorption isotherm data, thermodynamic and kinetic studies. Appl Radiat Isot 168:109474

    Article  CAS  PubMed  Google Scholar 

  30. Ju P, Liu Q, Zhang H, Chen R, Liu J, Yu J, Liu P, Zhang M, Wang J (2019) Hyperbranched topological swollen-layer constructs of multi-active sites polyacrylonitrile (PAN) adsorbent for uranium(VI) extraction from seawater. Chem Eng J 374:1204–1213

    Article  CAS  Google Scholar 

  31. Li J, Wu Z, Duan Q, Li X, Li Y, Alsulami H, Alhodaly MS, Hayat T, Sun Y (2020) Simultaneous removal of U(VI) and Re(VII) by highly efficient functionalized ZIF-8 nanosheets adsorbent. J Hazard Mater 393:122398

    Article  CAS  PubMed  Google Scholar 

  32. Zhang Q, Wang Y, Wang Z, Zhang Z, Wang X, Yang Z (2021) Active biochar support nano zero-valent iron for efficient removal of U(VI) from sewage water. J Alloys Compd 852:156993

    Article  CAS  Google Scholar 

  33. Wen J, Li Q, Li H, Chen M, Hu S, Cheng H (2018) Nano-TiO2 imparts amidoximated wool fibers with good antibacterial activity and adsorption capacity for uranium(VI) recovery. Ind Eng Chem Res 57:1826–1833

    Article  CAS  Google Scholar 

  34. He Y-R, Li S-C, Li X-L, Yang Y, Tang A-M, Du L, Tan Z-Y, Zhang D, Chen H-B (2018) Graphene (rGO) hydrogel: a promising material for facile removal of uranium from aqueous solution. Chem Eng J 338:333–340

    Article  CAS  Google Scholar 

  35. Zhou L, Ouyang J, Shehzad H, Le Z, Li Z, Adesina AA (2018) Adsorption of U(VI) onto the carboxymethylated chitosan/Na-bentonite membranes: kinetic, isothermic and thermodynamic studies. J Radioanal Nucl Chem 317:1377–1385

    Article  CAS  Google Scholar 

  36. Dolatyari L, Yaftian MR, Rostamnia S (2016) Removal of uranium(VI) ions from aqueous solutions using Schiff base functionalized SBA-15 mesoporous silica materials. J Environ Manage 169:8–17

    Article  CAS  PubMed  Google Scholar 

  37. Zhang L, Wang LL, le Gong L, Feng XF, Luo MB, Luo F (2016) Coumarin-modified microporous-mesoporous Zn-MOF-74 showing ultra-high uptake capacity and photo-switched storage/release of U(VI) ions. J Hazard Mater 311:30–36

    Article  CAS  PubMed  Google Scholar 

  38. Alahabadi A, Singh P, Raizada P, Anastopoulos I, Sivamani S, Dotto GL, Landarani M, Ivanets A, Kyzas GZ, Hosseini-Bandegharaei A (2020) Activated carbon from wood wastes for the removal of uranium and thorium ions through modification with mineral acid. Colloids Surf A Physicochem Eng Asp 607:125516

    Article  CAS  Google Scholar 

  39. Hallaji H, Keshtkar AR, Moosavian MA (2015) A novel electrospun PVA/ZnO nanofiber adsorbent for U(VI), Cu(II) and Ni(II) removal from aqueous solution. J Taiwan Inst Chem Eng 46:109–118

    Article  CAS  Google Scholar 

  40. Duan J, Ji H, Xu T, Pan F, Liu X, Liu W, Zhao D (2021) Simultaneous adsorption of uranium(VI) and 2-chlorophenol by activated carbon fiber supported/modified titanate nanotubes (TNTs/ACF): Effectiveness and synergistic effects. Chem Eng J 406:126752

    Article  CAS  Google Scholar 

  41. Lei H, Zhou D, Tang J, Hu X, Pan N, Zou H, Chi F, Wang X (2020) Epoxy graphene oxide from a simple photo-Fenton reaction and its hybrid with phytic acid for enhancing U(VI) capture. Sci Total Environ 738:140316

    Article  CAS  PubMed  Google Scholar 

  42. Dong Z, Zhang Z, Zhou R, Dong Y, Dai Y, Cao X, Wang Y, Liu Y (2020) Construction of oxidized millimeter-sized hierarchically porous carbon spheres for U(VI) adsorption. Chem Eng J 386:123944

    Article  CAS  Google Scholar 

  43. Li FF, Cui WR, Jiang W, Zhang CR, Liang RP, Qiu JD (2020) Stable sp(2) carbon-conjugated covalent organic framework for detection and efficient adsorption of uranium from radioactive wastewater. J Hazard Mater 392:122333

    Article  CAS  PubMed  Google Scholar 

  44. Bai Z, Liu Q, Zhang H, Liu J, Yu J, Wang J (2020) High efficiency biosorption of Uranium (VI) ions from solution by using hemp fibers functionalized with imidazole-4,5-dicarboxylic. J Mol Liq 297:111739

    Article  CAS  Google Scholar 

  45. Zhang M, Yuan M, Zhang M, Wang M, Chen J, Li R, Qiu L, Feng X, Hu J, Wu G (2020) Efficient removal of uranium from diluted aqueous solution with hydroxypyridone functionalized polyethylene nonwoven fabrics. Radiat Phys Chem 171:108742

    Article  CAS  Google Scholar 

  46. Ma S, Huang L, Ma L, Shim Y, Islam SM, Wang P, Zhao LD, Wang S, Sun G, Yang X, Kanatzidis MG (2015) Efficient uranium capture by polysulfide/layered double hydroxide composites. J Am Chem Soc 137:3670–3677

    Article  CAS  PubMed  Google Scholar 

Download references

Acknowledgements

This work was supported by the National Natural Science Foundation of China (41877323, 21806133, 41702037 and 42061134018).

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Faqin Dong or Xiaoqin Nie.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Supplementary Information

Below is the link to the electronic supplementary material.

Supplementary file1 (DOCX 178 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Xia, X., Dong, F., Nie, X. et al. Efficient adsorption of U(VI) using in low-level radioactive wastewater containing organic matter by amino groups modified polyacrylonitrile fibers. J Radioanal Nucl Chem 331, 921–936 (2022). https://doi.org/10.1007/s10967-021-08146-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10967-021-08146-4

Keywords

Navigation