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Sorption of cobalt by extraction chromatographic resin on the base of di-(tert-butylbenzo)-18-crown-6

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Abstract

A number of sorbents based on di-(tert-butylbenzo)-18-crown-6, 1-octanol, and various supports (LPS-500, hydrophobized silica) was obtained. The effect of temperature, support impregnation time, and thiocyanate ion concentration on cobalt sorption was evaluated. A comparison of the sorbent efficiency of cobalt recovery from thiocyanate solutions was performed for sorbents obtained by impregnation with different solvents (methanol, chloroform). Sorption and kinetic characteristics (isotherm, sorption and desorption kinetics, selectivity) of the sorbents in relation to cobalt in thiocyanate solutions were obtained. The sorbent was shown to possess a high selectivity towards Co in the presence of foreign ions. Sorption and desorption of cobalt were investigated under dynamic conditions. The technique developed for determination of cobalt ions and the specific activity of 60Co radionuclide in aqueous environmental objects enabled quantitative recovery of 60Co against the prevailing background of 137Cs and 152Eu radionuclides accompanied by not less than 20-fold sample concentrating.

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Acknowledgements

This work was performed under the state assignment of FASO of the Russian Federation (“Oceanological Processes” Topic No. 0827-2018-0003) and under the Foundation for Assistance to Small Innovative Enterprises in Science and Technology (Start-1 program, Project No. S1-21807). One of the authors (S. Kapranov) wishes to acknowledge the financial support within the state assignment No. AAAA-A18-118021350003-6 from A. O. Kovalevsky Institute of Marine Biological Research of Russian Academy of Sciences.

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Authors and Affiliations

  1. Sevastopol State University, University Street, 33, Sevastopol, Russian Federation, 299053

    V. S. Yankovskaya & N. A. Bezhin

  2. Marine Hydrophysical Institute, Russian Academy of Sciences, Kapitanskaya Street, 2, Sevastopol, Russian Federation, 299011

    I. I. Dovhyi

  3. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninsky Prospect, 31, Bldg. 4, Moscow, Russian Federation, 119071

    V. V. Milyutin & N. A. Nekrasova

  4. Kovalevsky Institute of Marine Biological Research, Russian Academy of Sciences, Nakhimovsky Prospect, 2, Sevastopol, Russian Federation, 299011

    S. V. Kapranov

  5. Vernadsky Crimean Federal University, Akademik Vernadsky Prospect, 4, Simferopol, Republic of Crimea, Russian Federation, 95007

    V. F. Shulgin

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  1. V. S. Yankovskaya
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  2. I. I. Dovhyi
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  4. V. V. Milyutin
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  6. S. V. Kapranov
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Correspondence to V. S. Yankovskaya, I. I. Dovhyi or N. A. Bezhin.

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Yankovskaya, V.S., Dovhyi, I.I., Bezhin, N.A. et al. Sorption of cobalt by extraction chromatographic resin on the base of di-(tert-butylbenzo)-18-crown-6. J Radioanal Nucl Chem 318, 1085–1097 (2018). https://doi.org/10.1007/s10967-018-6090-z

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