Abstract
The adsorption of hexavalent uranium on two different types of sea sand [e.g. a local, Cypriot (N_SS) and a commercially available marine sediment (C_SS)] has been investigated as a function of pH, initial metal concentration, ionic strength and contact time under normal atmospheric conditions. Before carrying out the adsorption experiments, the sea sand samples have been characterized by XRD, XRF, N2-adsorption, acid/base titrations and FTIR spectroscopy. Sample characterization showed clearly that the two sea sand types differ significantly in their composition, particularly in their calcite and FeOOH content. According to experimental data obtained from acid/base titrations and adsorption batch experiments sea sand composition affects the acid/base and the adsorption properties of the adsorbents. The extraordinary high affinity of N_SS for hexavalent uranium in the alkaline pH region can be attributed to the formation of mixed U(VI)–carbonato surface species on the FeOOH crystall phases present in N_SS, which effectively compete the formation of U(VI)–carbonato complexes in solution. On the other hand, data obtained by adsorption experiments carried out in solution of different ionic strengths don’t differ significantly from one another indicating the formation of inner-sphere complexes. Finally, the adsorption on sea sands is a relatively fast two-step process.
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References
Choppin GR (2007) Actinide speciation in the environment. J Radioanal Nucl Chem 273:695–703
Pashalidis I, Tsertos H (2004) Radiometric determination of uranium in natural waters after enrichment and separation by cation-exchange and liquid–liquid extraction. J Radioanal Nucl Chem 260:439–442
Antoniou S, Costa C, Pashalidis I (2013) Alpha-radiometry of seawater by liquid scintillation counting. J Radioanal Nucl Chem 295:649–656
Konstantinou M, Pashalidis I (2004) Speciation and spectrophotometric determination of uranium in seawater. Mediterr Mar Sci 5:55–60
Peev TM, Mitov IG (1999) Some investigations of sea sands from the Black Sea coastline. J Radioanal Nucl Chem 241:169–172
Sugandhi S, Prabhu SP, Mishra DG, Ravi PM, Hegde AG (2012) Distribution of uranium at Mumbai Harbour Bay (MHB). J Radioanal Nucl Chem 294:295–298
Takata H, Aono T, Tagami K, Uchida S (2011) Determination of naturally occurring uranium concentrations in seawater, sediment, and marine organisms in Japanese estuarine areas. J Radioanal Nucl Chem 287:795–799
Kumar A, Singhal RK, Rout S, Narayanan U, Karpe R, Ravi PM (2013) Adsorption and kinetic behavior of uranium and thorium in seawater-sediment system. J Radioanal Nucl Chem 295:649–656
Dong W, Tokunaga TK, Davis JA, Wan J (2012) Uranium(VI) adsorption and surface complexation modeling onto background sediments from the F-Area Savannah River Site. Environ Sci Technol 46:1565–1571
Tang J, Johannesson KH (2010) Rare earth elements adsorption onto Carrizo sand: influence of strong solution complexation. Chem Geol 279:120–133
Zuyi T, Taiwei C, Jinzhou D, XiongXin D, Yingjie G (2000) Effect of fulvic acids on sorption of U(VI), Zn, Yb, I and Se(IV) onto oxides of aluminium, iron and silicon. Appl Geochem 15:133–139
Khan MH, Warwick P, Evans N (2006) Spectrophotometric determination of uranium with arsenazo-III in perchloric acid. Chemosphere 63:1165–1169
Lin R, Spicer RL, Tungate FL, Davis BH (1996) A study of the oxidation of ferrous hydroxide in slightly basic solution to produce gamma-FeOOH. Colloids Surf A Physicochem Eng Aspects 113:79–96
Bargar JR, Reitmeyer R, Lenhart JJ, Davis JA (2000) Characterization of U(VI)–carbonato ternary complexes on hematite: EXAFS and electrophoretic mobility measurements. Geoch et Cosmoch Acta 64:2737–2749
Ulrich K-U, Rossberg A, Foerstendorf H, Zänker H, Scheinost AC (2006) Molecular characterization of uranium(VI) sorption complexes on iron(III)–rich acid mine water colloids. Geoch et Cosmoch Acta 70:5469–5487
Elzinga EJ, Tait CD, Reeder RJ, Rector KD, Donohoe RJ, Morris DE (2004) Spectroscopic investigation of U(VI) sorption at the calcite–water interface. Geoch Cosmoch Acta 68:2437–2448
Wang Z, Lee S-W, Catalano JG, Lezama-Pacheco JS, Bargar JR, Tebo BM, Giammar DE (2013) Adsorption of uranium(VI) to manganese oxides: X-ray absorption spectroscopy and surface complexation modeling. Environ Sci Technol 47:850–858
Ho Y-S (2004) Citation review of Lagergren kinetic rate equation on adsorption reactions. Scientometrics 59(171):177
Demetriou A, Pashalidis I (2011) Adsorption of hexavalent chromium on dunite. Water Sci Technol 63:818–824
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Efstathiou, M., Pashalidis, I. A comparative study of the adsorption of uranium on commercial and natural (Cypriot) sea sand samples. J Radioanal Nucl Chem 298, 1111–1116 (2013). https://doi.org/10.1007/s10967-013-2539-2
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DOI: https://doi.org/10.1007/s10967-013-2539-2