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Synthesis and stimuli-responsive properties of the phenanthroline based metallo-supramolecular polymers

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Abstract

A series of functional metallo-supramolecular materials based on polyhedral oligomeric silsesquioxane (POSS) and phenanthroline ligand were prepared using a two-step approach. Firstly, using a phenanthroline ligand, an amino-functionalized transition metal complex was prepared by tin(II) chloride. In the second step, this metal complex was subsequently reacted with the octakis(3-chloropropyl)octasilsesquioxane, resulting for the metallosupramolecular polymers bearing POSS structure. All the synthesized compounds were fully characterized by spectroscopic analysis, thermal and electron microscopy techniques. Stimuli responsible properties of metallo-supramolecular materials were also investigated the reversibility upon external factors, such as electrochemical or the addition of competitive complexing ligands by electroanalytic techniques and UV–Vis spectroscopy. The electro- and chemo-responsive properties of the metallo-supramolecular materials were also improved. As a result, prepared phenanthroline-functionalized polyhedral silsesquioxane are good candidates for electronic, opto-electronic, and photovoltaic applications as a smart stimuli-responsive material.

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Acknowledgments

Authors would like to thank TÜBİTAK - The Scientific and Technological Research Council of Turkey for the financial support with the project number MAG110M751.

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Authors and Affiliations

  1. Faculty of Sciences, Department of Chemistry, Fırat University, 23100, Elazıg, Turkey

    Maruf Hurşit Demirel

  2. Faculty of Sciences and Literature, Department of Chemistry, Inonu University, 44280, Malatya, Turkey

    Süleyman Köytepe, Ahmet Gültek & Turgay Seçkin

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  1. Maruf Hurşit Demirel
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  2. Süleyman Köytepe
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  3. Ahmet Gültek
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  4. Turgay Seçkin
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Correspondence to Süleyman Köytepe.

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Demirel, M.H., Köytepe, S., Gültek, A. et al. Synthesis and stimuli-responsive properties of the phenanthroline based metallo-supramolecular polymers. J Polym Res 21, 345 (2014). https://doi.org/10.1007/s10965-013-0345-8

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  • DOI: https://doi.org/10.1007/s10965-013-0345-8

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