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Synthesis and properties of crosslinked waterborne polyurethane

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Abstract

Waterborne polyurethane prepolymer was prepared by the reaction of isophorone isocyanate(IPDI), polyether polyol(PTMG), dimethylol propionic acid(DMPA) and trimethylol propane(TMP), which was modified by silicane coupling agent(APTES) to form highly crosslinked polyurethane emulsion. The films of the waterborne polyurethane were prepared. The structure of the polyurethane was characterized by Fourier transform infared spectrometer (FTIR), X-ray diffraction (XRD) and differential scanning calorimeter (DSC). The mechanical properties and water absorption of the films were measured. FT-IR indicates that APTES reacted with -NCO of polyurethane. XRD and DSC shows that crystallinity of polyurethane decreased with the increase of w(APTES). Tensile strength increases as the NCO/OH ratio increases. Tensile strength of films increases with increase of w(DMPA) and elongation at break decreases. The water absorption decreases with the increase of w(TMP) when w(TMP) is lower than 1.8%. As the mass fraction of APTES increases from 0% to 10%, the tensile strength of PU films increased from 18 MPa to 28 MPa, water absorption and ethanol absorption decreased.

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References

  1. Bai C, Zhang X, Dai J (2008) Effect of the hard segment on the properties of UV curable waterborne blocked polyurethanes. J Polymer Res 15:67–73

    Article  CAS  Google Scholar 

  2. Jeon HT, Jang MK, Kima BK (2007) Synthesis and characterizations of waterborne polyurethane-silica hybrids using sol-gel process. Colloid Surface Physicochem Eng Aspect 302:559–567

    Article  CAS  Google Scholar 

  3. Cheng X, Chen Z, Shi T et al (2007) Synthesis and characterization of core-shell LIPN-fluorine containing polyacrylate latex. Colloid Surface 292:119–124

    Article  CAS  Google Scholar 

  4. Jang JY, Jhon YK, Cheong IW (2002) Effect of process variables on molecular weight and mechanical properties of water-based polyurethane dispersion. Colloid Surface 196:135–143

    Article  CAS  Google Scholar 

  5. Zequn Y, Qishan H, Jianming Y (2008) Technology development of high performance waterborne polyurethanes. Chinese Polymer Bulletin 9:20–29

    Google Scholar 

  6. Qingsi Z, Xiaoli Z, Tianduo L (2007) Prepara tion and properties of reactive aqueous polyurethane dispersion modified by polysiloxane. Petrochemical technology 36:839–845

    Google Scholar 

  7. Pierre C, Eric C, Henri C et al (2005) Synthesis of core-shell polyurethane-polydimethylsiloxane particles in cyclohexane and in supercritical carbon dioxide used as dispersant media: A comparative investigation. Polymer 46:1057–1066

    Article  Google Scholar 

  8. Chen H, Fan Q, Chen D (2001) Synthesis and properties of polyurethane modified with an aminoethylaminopropyl-substituted polydimethysiloxane. J Appl Polymer Sci 79:295–301

    Article  CAS  Google Scholar 

  9. Queiroz DP, de Pinho MN (2005) Structural characteristics and gas permeation properties of polydimethylsiloxane/ poly (propylene oxide) urethane/urea bi-soft segment membranes. Polymer 46:2346

    Article  CAS  Google Scholar 

  10. Wang LF, Ji Q, Glass TE et al (2000) Synthesis and characterization of organosiloxane modified segmented polyether polyurethanes. Polymer 41:5083–5093

    Article  CAS  Google Scholar 

  11. Jena KK, Raju KVSN (2007) Synthesis and characterization of hyperbranched polyurethane-urea/silica based hybrid coatings[J]. Ind Eng Chem Res 46:6408–6416

    Article  CAS  Google Scholar 

  12. Wang LF, Ji Q, Glass TE et al (2000) Synthesis and characterization of organosiloxane modified segmented polyether polyurethanes. Polymer 41:5083–5093

    Article  CAS  Google Scholar 

  13. Zhang T, Xi K, Yu X, Gu M, Guo S (2003) Synthesis, properties of fullerene-containing polyurethane–urea and its optical limiting absorption. Polymer 44:2647–2654

    Article  CAS  Google Scholar 

  14. Blank WJ, Tramontano VJ (1996) Properties of crosslinked polyurethane dispersions. Progr Org Coating 27:1–15

    Article  CAS  Google Scholar 

  15. Lucas HR, Mealmaker WE, Giannopouos N (1996) Novel polyurethanes with interpenetrating networks for the coating industry. Progr Org Coating 27:133–144

    Article  CAS  Google Scholar 

Download references

Acknowledgements

We would like to express our great thanks to the National Natural Science Foundation of China (grant number: 20876093) and the Graduate Innovation Fund of Shaanxi University of Science and Technology for financial support.

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Authors and Affiliations

  1. College of chemistry and chemical engineering, Shaanxi University of Science & Technology, Xi’an, 710021, China

    Lei Wang, Yiding Shen, Xiaojuan Lai, Zhongjin Li & Min Liu

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  1. Lei Wang
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  2. Yiding Shen
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  3. Xiaojuan Lai
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  4. Zhongjin Li
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  5. Min Liu
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Correspondence to Xiaojuan Lai.

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Wang, L., Shen, Y., Lai, X. et al. Synthesis and properties of crosslinked waterborne polyurethane. J Polym Res 18, 469–476 (2011). https://doi.org/10.1007/s10965-010-9438-9

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  • DOI: https://doi.org/10.1007/s10965-010-9438-9

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