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Crystal structure of [Co(N2C2H8)3] [AuBr4]2Br bis(tetrabromoaurate(III))tris(ethylenediamine) cobalt(III) bromide

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A double complex salt [Co(N2C2H8)3][AuBr4]2Br is obtained and characterized using single crystal X-ray diffraction analysis. The crystallographic data of C6H24Au2Br9CoN6 are as follows: a = 21.6479(17) Å, b = 14.9085(12) Å, c = 8.2676(7) Å, β = 110.820(2)°, V = 1538.92(12) Å3, C2/c space group, Z = 4, d x = 3.602 g/cm3. Square planar coordination of the gold atom in the complex anion is completed to a tetragonal pyramid by an additional bromine atom of the adjacent complex anion at the Au... Br distance of 3.677 Å.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    I. A. Baidina & E. V. Makotchenko

  2. Novosibirsk State University, Novosibirsk, Russia

    E. V. Makotchenko

Authors
  1. I. A. Baidina
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  2. E. V. Makotchenko
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Correspondence to I. A. Baidina.

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Original Russian Text Copyright © 2010 by I. A. Baidina and E. V. Makotchenko

Translated from Zhurnal Strukturnoi Khimii, Vol. 51, No. 1, pp. 192–194, January–February, 2010.

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Baidina, I.A., Makotchenko, E.V. Crystal structure of [Co(N2C2H8)3] [AuBr4]2Br bis(tetrabromoaurate(III))tris(ethylenediamine) cobalt(III) bromide. J Struct Chem 51, 187–189 (2010). https://doi.org/10.1007/s10947-010-0028-9

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  • DOI: https://doi.org/10.1007/s10947-010-0028-9

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