Skip to main content
Log in

Magnetic carbon aerogel pyrolysis from sodium carboxymethyl cellulose/sodium montmorillonite composite aerogel for removal of organic contamination

  • Published:
Journal of Porous Materials Aims and scope Submit manuscript

Abstract

In this paper, we present a facile approach for the synthesis of polysaccharide-based carbon aerogel by sol–gel processing, freeze-drying, and pyrolysis of a sodium carboxymethyl cellulose/sodium montmorillonite composite aerogel. The as-prepared carbon aerogel was characterized by scanning electron microscopy, Fourier transform infrared spectroscopy, X-ray diffractometry, nitrogen adsorption measurements, and vibrating sample magnetometry. The carbon aerogel obtained in this study possessed low density (0.064 ± 0.0029 g/cm3), a high surface area (185 m2/g), and flame retardance. Measurements of the magnetic properties indicated that the carbon aerogel exhibited typical ferromagnetic characteristic at room temperature. The absorption capacity of the carbon aerogel for oils and organic solvents is as much as 10–20 times its own weight. Moreover, a method of combustion could be employed to recycle the carbon aerogel. The results imply that the carbon aerogel is a potential cost-effective adsorbent for oil and organic pollutants from aqueous solutions in environmental pollution cleanup.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. R. Singh, R.K. Khardekar, D.K. Kohli, M.K. Singh, H. Srivastava, P.K. Gupta, Mater. Lett. 64, 843–845 (2010)

    Article  CAS  Google Scholar 

  2. H. Wang, Y. Gong, Y. Wang, RSC Adv. 4, 45753–45759 (2014)

    Article  CAS  Google Scholar 

  3. J. Wang, M. Chen, C. Wang, J. Wang, J. Zheng, Mater. Lett. 68, 446–449 (2012)

    Article  CAS  Google Scholar 

  4. M. Yu, J. Li, L. Wang, J. Porous. Mat. 23, 997–1003 (2016)

    Article  CAS  Google Scholar 

  5. S. Han, Q. Sun, H. Zheng, J. Li, C. Jin, Carbohydr. Polym. 136, 95–100 (2016)

    Article  CAS  Google Scholar 

  6. A.M. Elkhatat, S.A. Al-Muhtaseb, Adv. Mater. 23, 2887–2903 (2011)

    Article  CAS  Google Scholar 

  7. M.F. De Volder, S.H. Tawfick, R.H. Baughman, A.J. Hart, Science 339, 535–539 (2013)

    Article  Google Scholar 

  8. Z.S. Wu, A. Winter, L. Chen, Y. Sun, A. Turchanin, X. Feng, K. Mullen, Adv. Mater. 24, 5130–5135 (2012)

    Article  CAS  Google Scholar 

  9. H. Sun, Z. Xu, C. Gao, Adv. Mater. 25, 2554–2560 (2013)

    Article  CAS  Google Scholar 

  10. B. Kong, J. Tang, Z. Wu, J. Wei, H. Wu, Y. Wang, G. Zheng, D. Zhao, Angew. Chem. Int. Edit 53, 2888–2892 (2014)

    Article  CAS  Google Scholar 

  11. Z.Y. Wu, C. Li, H.W. Liang, J.F. Chen, S.H. Yu, Angew. Chem. Int. Ed. 52, 2925–2929 (2013)

    Article  CAS  Google Scholar 

  12. Y.Q. Li, Y.A. Samad, K. Polychronopoulou, S.M. Alhassan, K. Liao, A.C.S. Sustain, Chem. Eng. 2, 1492–1497 (2014)

    CAS  Google Scholar 

  13. X. Wu, W. Jia, Chem. Eng. J. 245, 210–216 (2014)

    Article  CAS  Google Scholar 

  14. X. Chang, D. Chen, X. Jiao, Polymer 51, 3801–3807 (2010)

    Article  CAS  Google Scholar 

  15. H.B. Chen, B.S. Chiou, Y.Z. Wang, D.A. Schiraldi, ACS Appl. Mater. Inter. 5, 1715–1721 (2013)

    Article  CAS  Google Scholar 

  16. T. Pojanavaraphan, R. Magaraphan, B.S. Chiou, Biomacromolecules 11, 2640–2646 (2010)

    Article  CAS  Google Scholar 

  17. L. Wang, D.A. Schiraldi, M. Sánchez-Soto, Ind. Eng. Chem. Res. 53, 7680–7687 (2014)

    Article  CAS  Google Scholar 

  18. N.H. Kim, S.V. Malhotra, M. Xanthos, Microporous Mesoporous Mater. 96, 29–35 (2006)

    Article  CAS  Google Scholar 

  19. O. Monticelli, Z. Musina, A. Frache, F. Bellucci, G. Camino, S. Russo, Polym. Degrad. Stab. 92, 370–378 (2007)

    Article  CAS  Google Scholar 

  20. X. Chen, H. Gao, H.J. Ploehn, Carbohydr. Polym. 101, 565–573 (2014)

    Article  CAS  Google Scholar 

  21. R. Lin, A. Li, L. Lu, Y. Cao, Carbohydr. Polym. 118, 126–132 (2015)

    Article  CAS  Google Scholar 

  22. Y. Xu, X. Ren, M.A. Hanna, J. Appl. Polym. Sci. 99, 1684–1691 (2006)

    Article  CAS  Google Scholar 

  23. J.F. Du, Y. Bai, W.Y. Chu, L.J. Qiao, J. Polym. Sci. Pol. Phys. 48, 260–266 (2010)

    Article  CAS  Google Scholar 

  24. W. Wang, Y. Sun, B. Liu, S. Wang, M. Cao, Carbon 91, 56–65 (2015)

    Article  CAS  Google Scholar 

  25. Q. Wu, W. Li, J. Tan, X. Nan, S. Liu, Appl. Surf. Sci. 332, 354–361 (2015)

    Article  CAS  Google Scholar 

  26. Song X, Yang S, He L, RSC Adv. 4, 49000–49005 (2014)

    Article  CAS  Google Scholar 

  27. Z. Liu, C. Lv, X. Tan, J. Phys. Chem. Solids 74, 1275–1280 (2013)

    Article  CAS  Google Scholar 

  28. J. Li, M. Luo, C.J. Zhao, C.Y. Li, W. Wang, Y.G. Zu, Y.J. Fu, Bioresource. Technol. 128, 673–678 (2013)

    Article  CAS  Google Scholar 

  29. D. Wang, T. Silbaugh, R. Pfeffer, Y.S. Lin, Powder. Technol. 203, 298–309 (2010)

    Article  CAS  Google Scholar 

  30. S.S. Banerjee, M.V. Joshi, R.V. Jayaram, Chemosphere 64, 1026–1031 (2006)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by the Fundamental Research Funds for Central Universities (E2572017EB05) and Heilongjiang Province outstanding youth science fund (JC201301).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Lijuan Wang.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Yu, M., Han, Y., Li, J. et al. Magnetic carbon aerogel pyrolysis from sodium carboxymethyl cellulose/sodium montmorillonite composite aerogel for removal of organic contamination. J Porous Mater 25, 657–664 (2018). https://doi.org/10.1007/s10934-017-0478-y

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10934-017-0478-y

Keywords

Navigation