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Properties of magnetic microbeads in removing bisphenol-A from aqueous phase

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Abstract

In this study, magnetic poly(ethylene glycol dimethacrylate-N-methacryloyl-l-tryptophan methyl ester) [m-poly(EGDMA-MATrp)] beads (average diameter = 53–103 μm) were synthesized by copolymerizing of N-methacryloyl-l-tryptophan methyl ester with ethylene glycol dimethacrylate in the presence of magnetite (Fe3O4) and used for removal of bisphenol-A (BPA). The m-poly(EGDMA-MATrp) beads were characterized by N2 adsorption/desorption isotherms (BET), X-ray photoelectron spectroscopy, scanning electron microscopy, infrared spectroscopy, thermal gravimetric analysis, electron spin resonance analysis and swelling studies. To evaluate the efficiency of m-poly(EGDMA-MATrp) beads for adsorption of BPA from aqueous medium, the effects of pH, initial concentration, contact time and temperature were analyzed. The maximum BPA adsorption capacity of the m-poly(EGDMA-MATrp) beads was determined as 139.6 mg/g at pH 5.0, 25 °C. All the isotherm data can be fitted with the Langmuir, Freundlich and Dubinin–Radushkevich isotherm models. The adsorption process obeyed pseudo-second-order kinetic model.

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Acknowledgments

This work was partly supported by the Research Foundation of The University of Uludag Project Number: OUAP(F)-2013/29 and Project Number: KUAP(F)-2013/86.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Arts and Science, Uludag University, 16059, Bursa, Turkey

    Bilgen Osman, Elif Tümay Özer, Ali Kara, Emel Yeşilova & Necati Beşirli

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  1. Bilgen Osman
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  2. Elif Tümay Özer
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  3. Ali Kara
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Correspondence to Elif Tümay Özer.

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Osman, B., Özer, E.T., Kara, A. et al. Properties of magnetic microbeads in removing bisphenol-A from aqueous phase. J Porous Mater 22, 37–46 (2015). https://doi.org/10.1007/s10934-014-9870-z

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