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Characterization and catalytic behaviors of methylamine modified FAU zeolites

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Abstract

The methylamine (MA) modified FAU zeolites with 5.8 and 80 of silica alumina molar ratio were successfully prepared by the treatment of original FAU zeolites with MA. The obtained materials were investigated with diffuse reflectance infrared Fourier transform spectroscopy, X-ray diffraction, magic-angle spinning nuclear magnetic resonance, thermogravimetry, temperature-programmed desorption of CO2 and NH3 (CO2-TPD and NH3-TPD), nitrogen content analysis, and specific surface area analysis. The formations and thermal stabilities of different Si–N–C groups in the MA modified FAU zeolites were confirmed. The changing of aluminium species due to the interaction of MA and framework/extraframework aluminium (FAL/EFAL) in the modified samples was discovered. The acidity and basicity of the MA modified FAU zeolites were correlated to the hybrid aluminium species and variation of Si–N–C groups, respectively. The catalytic behaviors of the MA modified FAU zeolites were explored by Knoevenagel condensation reaction of benzaldehyde and malonic acid.

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References

  1. S.L. Suib, Science 302, 1335 (2003)

    Article  CAS  Google Scholar 

  2. J. Weitkamp, Solid State Ionics 131, 175 (2000)

    Article  CAS  Google Scholar 

  3. J.F. Haw, Phys. Chem. Chem. Phys. 4, 5431 (2002). doi:10.1039/B206483a

    Article  CAS  Google Scholar 

  4. A. Corma, Chem. Rev. 95, 559 (1995)

    Article  CAS  Google Scholar 

  5. R. Astala, S.M. Auerbach, J. Am. Chem. Soc. 126, 1843 (2004). doi:10.1021/Ja037890d

    Article  CAS  Google Scholar 

  6. H. Hattori, Chem. Rev. 95, 537 (1995)

    Article  CAS  Google Scholar 

  7. D. Barthomeuf, Micropor. Mesopor. Mat. 66, 1 (2003). doi:10.1016/j.micromeso.2003.08.006

    Article  CAS  Google Scholar 

  8. G.J. Suppes, M.A. Dasari, E.J. Doskocil, P.J. Mankidy, M.J. Goff, Appl. Catal. a-Gen 257, 213 (2004). doi:10.1016/j.apcata.2003.07.010

    Article  CAS  Google Scholar 

  9. R.J. Davis, E.J. Doskocil, S. Bordawekar, Catal. Today 62, 241 (2000)

    Article  CAS  Google Scholar 

  10. K. Yamamoto, Y. Sakata, Y. Nohara, Y. Takahashi, T. Tatsumi, Science 300, 470 (2003)

    Article  CAS  Google Scholar 

  11. S. Ernst, M. Hartmann, S. Sauerbeck, T. Bongers, Appl Catal. a-Gen 200, 117 (2000)

    Article  CAS  Google Scholar 

  12. P.W. Lednor, R. Deruiter, J. Chem. Soc. Chem. Commun. 22, 1625 (1991)

    Google Scholar 

  13. P.W. Lednor, Catal. Today 15, 177 (1992)

    Article  Google Scholar 

  14. Y.D. Xia, R. Mokaya, Angew. Chem. Int. Edit. 42, 2639 (2003). doi:10.1002/anie.200350978

    Article  CAS  Google Scholar 

  15. M.P. Kapoor, S. Inagaki, Chem. Lett. 32, 94 (2003)

    Article  CAS  Google Scholar 

  16. N. Chino, T. Okubo, Micropor. Mesopor. Mat. 87, 15 (2005). doi:10.1016/j.micromeso.2005.07.034

    Article  CAS  Google Scholar 

  17. K.D. Hammond, M. Gharibeh, G.A. Tompsett, F. Dogan, A.V. Brown, C.P. Grey, S.M. Auerbach, W.C. Conner, Chem. Mater. 22, 130 (2010). doi:10.1021/Cm902511a

    Article  CAS  Google Scholar 

  18. F. Dogan, K.D. Hammond, G.A. Tompsett, H. Huo, W.C. Conner, S.M. Auerbach, C.P. Grey, J. Am. Chem. Soc. 131, 11062 (2009). doi:10.1021/Ja9031133

    Article  CAS  Google Scholar 

  19. K.D. Hammond, F. Dogan, G.A. Tompsett, V. Agarwal, W.C. Conner, C.P. Grey, S.M. Auerbach, J. Am. Chem. Soc. 130, 14912 (2008). doi:10.1021/Ja8044844

    Article  CAS  Google Scholar 

  20. A. Stein, B. Wehrle, M. Jansen, Zeolites 13, 291 (1993)

    Article  CAS  Google Scholar 

  21. P. Grange, P. Bastians, R. Conanec, R. Marchand, Y. Laurent, Appl Catal. a-Gen 114, L191 (1994)

    Article  CAS  Google Scholar 

  22. M.J. Climent, A. Corma, V. Fornes, A. Frau, R. GuilLopez, S. Iborra, J. Primo, J. Catal. 163, 392 (1996)

    Article  CAS  Google Scholar 

  23. A. Massinon, J.A. Odriozola, P. Bastians, R. Conanec, R. Marchand, Y. Laurent, P. Grange, Appl Catal. a-Gen 137, 9 (1996)

    Article  CAS  Google Scholar 

  24. K.S. Wan, Q. Liu, C.M. Zhang, Chem. Lett. 32, 362 (2003)

    Article  CAS  Google Scholar 

  25. K. Narasimharao, M. Hartmann, H.H. Thiel, S. Ernst, Micropor. Mesopor. Mat. 90, 377 (2006). doi:10.1016/j.micromeso.2005.11.029

    Article  CAS  Google Scholar 

  26. J. El Haskouri, S. Cabrera, F. Sapina, J. Latorre, C. Guillem, A. Beltran-Porter, D. Beltran-Porter, M.D. Marcos, P. Amoros, Adv. Mater. 13, 192 (2001)

    Article  CAS  Google Scholar 

  27. A.J. Han, H.Y. He, J. Guo, H. Yu, Y.F. Huang, Y.C. Long, Micropor. Mesopor. Mat. 79, 177 (2005). doi:10.1016/j.micromeso.2004.11.001

    Article  CAS  Google Scholar 

  28. A.J. Han, J.G. Guo, H. Yu, Y. Zeng, Y.F. Huang, H.Y. He, Y.C. Long, ChemPhysChem 7, 607 (2006). doi:10.1002/cphc.200500389

    Article  CAS  Google Scholar 

  29. J. Guo, A.J. Han, H. Yu, J.P. Dong, H.Y. He, Y.C. Long, Micropor. Mesopor. Mat. 94, 166 (2006). doi:10.1016/j.micromeso.2006.03.046

    Article  CAS  Google Scholar 

  30. M.M.J. Treacy, J.B. Higgins, Collection of Simulated XRD Powder Patterns for Zeolites (Elsevier, Oxford, 2007)

    Google Scholar 

  31. T. Hasegawa, C.K. Krishnan, M. Ogura, Micropor. Mesopor. Mat. 132, 290 (2010). doi:10.1016/j.micromeso.2010.02.014

    Article  CAS  Google Scholar 

  32. D.M.G. Engelhardt, High-Resolution Solid State NMR of Silicates and Zeolites (Wiley, New York, 1987)

    Google Scholar 

  33. Y.C. Long, M.Y. Jin, Y.J. Sun, T.L. Wu, L.P. Wang, L. Fei, J. Chem. Soc. Faraday T 92, 1647 (1996)

    Article  Google Scholar 

  34. S. Ernst, M. Hartmann, S. Sauerbeck, Stud. Surf. Sci. Catal. 135, S620 (2001)

    Google Scholar 

Download references

Acknowledgments

This work is supported by National Basic Research Program of China (2009CB623506) and National Natural Science Foundation of China (Projects 20073010 and 20421303).

Conflict of interest

The authors declare that they have no conflict of interest.

Ethical standards

All the experiments comply with the current laws of China.

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Authors and Affiliations

  1. Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai, 200433, People’s Republic of China

    Xiaocheng Chen, Juan Guo, Zhengwen Fu, Heyong He & Yingcai Long

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  1. Xiaocheng Chen
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  2. Juan Guo
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  3. Zhengwen Fu
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  4. Heyong He
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  5. Yingcai Long
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Correspondence to Heyong He or Yingcai Long.

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Chen, X., Guo, J., Fu, Z. et al. Characterization and catalytic behaviors of methylamine modified FAU zeolites. J Porous Mater 20, 1271–1281 (2013). https://doi.org/10.1007/s10934-013-9711-5

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