Abstract
We report a facile and effective approach for the fabrication of hierarchically porous-structured NiO film. In this approach, the NiO film was deposited by chemical bath deposition through a self-assembled monolayer of polystyrene spheres template. The obtained NiO film exhibits a special hierarchical structure consists of two parts: the lower part is nickel oxide monolayer hollow-sphere array and the upper part is randomly porous net-like nickel oxide. The as-prepared NiO also shows a high specific surface area of 537 m2 g−1 and a narrow pore distribution centered at 140 nm. This is a technique for preparing large area hierarchical porous oxide or hydroxide films, which have a great promise for applications in optical devices, electrochemical sensors and thin-film batteries.
Similar content being viewed by others
References
X.H. Xia, J.P. Tu, J. Zhang, X.L. Wang, W.K. Zhang, H. Huang, Electrochim. Acta 53, 5721 (2008). doi:10.1016/j.electacta.2008.03.047
X.H. Huang, J.P. Tu, X.H. Xia, X.L. Wang, J.Y. Xiang, L. Zhang, Y. Zhou, J. Power Sources 188, 588 (2009). doi:10.1016/j.jpowsour.2008.11.111
S. Banerjee, A. Santhanam, A. Dhathathreyan, P.M. Rao, Langmuir 19, 5522 (2003). doi:10.1021/la034420o
M.-S. Wu, C.-H. Yang, M.-J. Wang, Electrochim. Acta 54, 155 (2008). doi:10.1016/j.electacta.2008.08.027
L.D. Kadam, P.S. Patil, Sol. Energy Mater. Sol. Cells 69, 361 (2001). doi:10.1016/S0927-0248(00)00403-7
D. Wang, C. Song, Z. Hu, X. Fu, J. Phys. Chem. B 109, 1125 (2005). doi:10.1021/jp046797o
M. Wu, J. Gao, S. Zhang, A. Chen, J. Porous Mater. 13, 407 (2006). doi:10.1007/s10934-006-8038-x
X.H. Xia, J.P. Tu, J. Zhang, X.L. Wang, W.K. Zhang, H. Huang, Sol. Energy Mater. Sol. Cells 92, 628 (2008). doi:10.1016/j.solmat.2008.01.009
H. Nagayama, H. Honda, H. Kawahara, J. Electrochem. Soc. 135, 2013 (1988). doi:10.1149/1.2096198
P. Yang, T. Deng, D. Zhao, P. Feng, D. Pine, B.F. Chmelka, G.M. Whitesides, G.D. Stucky, Science 282, 2244 (1998). doi:10.1126/science.282.5397.2244
M.C. Orilall, N.M. Abrams, J. Lee, F.J. DiSalvo, U. Wiesner, J. Am. Chem. Soc. 130, 8882 (2008). doi:10.1021/ja802093u
J. Li, Y. Zhang, Chem. Mater. 19, 2581 (2007). doi:10.1021/cm070197v
P.N. Bartlett, J.J. Baumberg, P.R. Birkin, M.A. Ghanem, M.C. Netti, Chem. Mater. 14, 2199 (2002). doi:10.1021/cm011272j
M. Sadakane, T. Horiuchi, N. Kato, C. Takahashi, W. Ueda, Chem. Mater. 19, 5779 (2007). doi:10.1021/cm071823r
U. Jeong, Y. Wang, M. Ibisata, Y. Xia, Adv. Funct. Mater. 15, 1907 (2005). doi:10.1002/adfm.200500472
D. Lan, Y. Wang, X. Du, Z. Mei, Q. Xue, K. Wang, X. Han, Z. Zhang, Cryst. Growth Des. 8, 2912 (2008). doi:10.1021/cg7012683
G. Duan, W. Cai, Y. Luo, F. Sun, Adv. Funct. Mater. 17, 644 (2007). doi:10.1002/adfm.200600568
S.Y. Han, D.H. Lee, Y.J. Chang, S.O. Ryu, T.J. Lee, C.H. Chang, J. Electrochem. Soc. 153, 382 (2006). doi:10.1149/1.2186767
P. Oliva, J. Leonardi, J.F. Laurent, C. Delmas, J.J. Braconnier, M. Figlarz, F. Fievet, A. de Guibert, J. Power Sources 8, 229 (1982). doi:10.1016/0378-7753(82)80057-8
A. Surca, B. Orel, B. Pihlar, P. Bukovec, J. Electroanal. Chem. 408, 83 (1996). doi:10.1016/0022-0728(96)04509-3
R. Cerc Korošec, P. Bukovec, B. Pihlar, J. Padežnik Gomilšek, Thermochim. Acta 402, 57 (2003)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Xiao, A., Yang, J. & Zhang, W. Hierarchically porous-structured nickel oxide film prepared by chemical bath deposition through polystyrene spheres template. J Porous Mater 17, 283–287 (2010). https://doi.org/10.1007/s10934-009-9290-7
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10934-009-9290-7