Skip to main content
Log in

Lego-like spheres and tori

  • Original Paper
  • Published:
Journal of Mathematical Chemistry Aims and scope Submit manuscript

Abstract

Given a connected surface \({\mathbb {F}}^2\) with Euler characteristic \(\chi \) and three integers \(b>a\ge 1<k\), an \((\{a,b\};k)\)-\({\mathbb {F}}^2\) is a \({\mathbb {F}}^2\)-embedded graph, having vertices of degree only k and only a- and b-gonal faces. The main case are (geometric) fullerenes (5, 6; 3)-\({\mathbb {S}}^2\). By \(p_a\), \(p_b\) we denote the number of a-gonal, b-gonal faces. Call an \((\{a,b\};k)\)-map lego-admissible if either \(\frac{p_b}{p_a}\), or \(\frac{p_a}{p_b}\) is integer. Call it lego-like if it is either \(ab^f\)-lego map, or \(a^fb\)-lego map, i.e., the face-set is partitioned into \(\min (p_a,p_b)\) isomorphic clusters, legos, consisting either one a-gon and \(f=\frac{p_b}{p_a}\,b\)-gons, or, respectively, \(f=\frac{p_a}{p_b}\,a\)-gons and one b-gon; the case \(f=1\) we denote also by ab. Call a \((\{a,b\};k)\)-map elliptic, parabolic or hyperbolic if the curvature \(\kappa _b=1+\frac{b}{k}-\frac{b}{2}\) of b-gons is positive, zero or negative, respectively. There are 14 lego-like elliptic \((\{a,b\};k)\)-\({\mathbb {S}}^2\) with \((a,b)\ne (1,2)\). No \((\{1,3\};6)\)-\({\mathbb {S}}^2\) is lego-admissible. For other 7 families of parabolic \((\{a,b\};k)\)-\({\mathbb {S}}^2\), each lego-admissible sphere with \(p_a\le p_b\) is \(a^fb\) and an infinity (by Goldberg–Coxeter operation) of \(ab^f\)-spheres exist. The number of hyperbolic \(ab^f\,(\{a,b\};k)\)-\({\mathbb {S}}^2\) with \((a,b)\ne (1,3)\) is finite. Such \(a^f b\)-spheres with \(a\ge 3\) have \((a,k)=(3,4),(3,5),(4,3),(5,3)\) or (3, 3); their number is finite for each b, but infinite for each of 5 cases (ak). Any lego-admissible \((\{a,b\};k)\)-\({\mathbb {S}}^2\) with \(p_b=2\le a\) is \(a^f b\). We list, explicitly or by parameters, lego-admissible \((\{a,b\};k)\)-maps among: hyperbolic spheres, spheres with \(a\in \{1,2\}\), spheres with \(p_b\in \{2,\frac{p_a}{2}\}\), Goldberg–Coxeter’s spheres and \((\{a,b\};k)\)-tori. We present extensive computer search of lego-like spheres: 7 parabolic (\(p_b\)-dependent) families, basic examples of all 5 hyperbolic \(a^fb\) (b-dependent) families with \(a\ge 3\), and lego-like \((\{a,b\};3)\)-tori.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14
Fig. 15
Fig. 16
Fig. 17
Fig. 18
Fig. 19
Fig. 20
Fig. 21
Fig. 22
Fig. 23
Fig. 24
Fig. 25
Fig. 26
Fig. 27
Fig. 28
Fig. 29
Fig. 30
Fig. 31
Fig. 32
Fig. 33
Fig. 34
Fig. 35
Fig. 36
Fig. 37
Fig. 38

Similar content being viewed by others

References

  1. Z. Badri, C. Foroutan-Nejad, P. Rashidi-Ranjbar, A theoretical survey on the D-7d [84] fullerene, a fullerene with two heptagon rings. Comput. Theor. Chem. 1009, 103–107 (2013). doi:10.1016/j.comptc.2013.01.005

    Article  CAS  Google Scholar 

  2. G. Brinkmann, T. Harmuth, O. Heidemeier, The construction of cubic and quartic planar maps with prescribed face degrees. Discrete Appl. Math. 128(2–3), 541–554 (2003). doi:10.1016/S0166-218X(02)00549-8

    Article  Google Scholar 

  3. H.S.M. Coxeter, Virus macromolecules and geodesic domes. in A Spectrum of Mathematics (Essays Presented to H.G. Forder) (Auckland Univ. Press, Auckland, 1971), pp. 98–107

  4. M. Deza, M. Dutour, M. Shtogrin, 4-valent plane graphs with 2-, 3- and 4-gonal faces. in Advances in Algebra (World Sci. Publ., River Edge, 2003), pp. 73–97

  5. M. Deza, M. Dutour, Sikirić, Zigzag and central circuit structure of \((\{1,2,3\},6)\)-spheres. Taiwan. J. Math. 16(3), 913–940 (2012)

    Google Scholar 

  6. M. Deza, M. Dutour Sikirić, M. Shtogrin, Fullerene-like spheres with faces of negative curvature, in Diamond and Related Nanostructures, Carbon Materials: Chemistry and Physics, vol. 6 (Springer, Berlin, 2013), pp. 251–274

  7. M.M. Deza, M. Dutour Sikirić, M.I. Shtogrin, Geometric structure of chemistry-relevant graphs, in Forum for Interdisciplinary Mathematics, vol. 1 (Springer, New Delhi, 2015). doi:10.1007/978-81-322-2449-5

  8. M.V. Diudea, A.E. Vizitiu, Aromaticity of corazulenic fullerenes. J. Math. Chem. in Conference on 20 years of Molecular Topology in Cluj, Cluj Napoca, Romania, Sep. 25–30, 2006, vol. 45 no. 2, pp. 330–353 (2009) doi:10.1007/s10910-008-9409-0

  9. M. Dutour, M. Deza, Goldberg–Coxeter construction for 3- and 4-valent plane graphs. Electron. J. Comb. 11(1). Research Paper 20, 49 (2004). http://www.combinatorics.org/Volume_11/Abstracts/v11i1r20.html

  10. M. Dutour Sikirić, Plot Oriented maps. http://github.com/MathieuDutSik/Plot_orientedmap

  11. M. Dutour Sikirić, Point Groups. http://mathieudutour.altervista.org/PointGroup/index.html

  12. N. Een, N. Sorensson, An extensible SAT-solver, in Theory and Applications of Satisfiability Testing, Lecture Notes in Computer Science, vol. 2919, ed. By E. Giunchiglia, A. Tacchella (pp. 502–518). CoLogNet; Univ Genova, DIST; IISI; Microsoft Res; MIUR, Springer, Berlin, heidelberger Platz3, 14197 Berlin, Germany (2004). 6th International Conference on Theory and Applications of Satisfiability Testing, Santa Margherita Ligure, Italy, May 05–08, (2003)

  13. N. Eén, N. Sörensson, MiniSat – A SAT solver with conflict-clause minimization. in Proceedings of the International Symposium on the Theory and Applications of Satisfiability Testing (2005)

  14. P. Fowler, D. Mitchell, G. Seifert, F. Zerbetto, Energetics of fullerenes with octagonal rings. Fuller. Sci. Technol. 5(4), 747–768 (1997). doi:10.1080/15363839708012229

    Article  Google Scholar 

  15. J.M. Galicia Hernandez, G. Hernandez Cocoletzi, E. Chigo Anota, DFT studies of the phenol adsorption on boron nitride sheets. J. Mol. Model. 18(1), 137–144 (2012). doi:10.1007/s00894-011-1046-z

  16. L.H. Gan, R. Li, J. An, The structures and stability of BnNn clusters with octagon(s). RSC Adv. 2(32), 12466–12473 (2012). doi:10.1039/c2ra21720a

    Article  CAS  Google Scholar 

  17. M. Goldberg, A class of multisymmetric polyhedra. Tohoku Math. J. 43, 104–108 (1937)

    Google Scholar 

  18. T. Harmuth, The Construction of Cubic Maps on Orientable Surfaces. PhD thesis. Bielefeld, University (2000)

  19. M. Homyonfer, Y. Feldman, L. Margulis, R. Tenne, Negative curvature in inorganic fullerene-like structure. Fuller. Sci. Technol. 6(1), 59–66 (1998). doi:10.1080/10641229809350185

    Article  CAS  Google Scholar 

  20. P. Kaski, O. Pottonen, Libexact user’s guide. HIIT. Tech. Rep. 1, 1–11 (2008)

    Google Scholar 

  21. J.W. Li, Y.Y. Liu, L.H. Xie, J.Z. Shang, Y. Qian, M.D. Yi, T. Yu, W. Huang, Revealing the interactions between pentagon-octagon-pentagon defect graphene and organic donor/acceptor molecules: a theoretical study. Phys. Chem. Chem. Phys. 17(7), 4919–4925 (2015). doi:10.1039/c4cp04900d

    Article  CAS  Google Scholar 

  22. V.W. Marek, Introduction to mathematics of satisfiability, in Chapman & Hall/CRC Studies in Informatics Series (CRC Press. Boca Raton (2009). doi:10.1201/9781439801741

    Google Scholar 

  23. D. Mehta, T. Chen, J.W.R. Morgan, D.J. Wales, Exploring the potential energy landscape of the Thomson problem via Newton homotopies. J. Chem. Phys. (2015). doi:10.1063/1.4921163

    Google Scholar 

  24. W.L. Miller, A. Cacciuto, Two-dimensional packing of soft particles and the soft generalized Thomson problem. Soft Matter 7(16), 7552–7559 (2011). doi:10.1039/c1sm05731f

    Article  CAS  Google Scholar 

  25. M.D. Sikirić, M. Knor, P. Potočnik, J. Širáň, R. Škrekovski, Hyperbolic analogues of fullerenes on orientable surfaces. Discrete Math. 312(4), 729–736 (2012). doi:10.1016/j.disc.2011.11.009

    Article  Google Scholar 

  26. A. Sorkin, B. Tay, H. Su, Three-stage transformation pathway from nanodiamonds to fullerenes. J. Phys. Chem. A 115(30), 8327–8334 (2011). doi:10.1021/jp200449f

    Article  CAS  Google Scholar 

  27. A.E. Xavier, J.L. Dorneles Faco, J.R. de Paula Junior, A novel contribution to the Tammes problem by the hyperbolic smoothing method. in ed. By L. Sakalauskas, GW Weber, EK Zavadskas 20th International conference, Euro mini conference continuous optimization and knowledge-based technologies,EUROPT’2008, pp. 31–35. European Assoc Operat Res Soc; Inst Math & Informat; Vilnius Gediminas Tech Univ; Lithuanian Operat Res Soc; EURO WG Continuous Optimizat; German OR Soc; European Chapter Metaheurist; European Chapter Combinatorial Optimizat; IBM Europe; Kaunas Univ Technol, Vilnius Gediminas Technical Univ Press, Technika, Sauletekio A1. 11, Vilnius-40, LT-10233, Lithuania (2008). 20th International Conference/Euro Mini Conference on Continuous Optimization and Knowledge-Based Technologies (EurOPT 2008), Neringa, Lithuania, May 20–23, 2008

  28. J. Zhang, W. Xie, X. Xu, S. Zhang, J. Zhao, Structural and electronic properties of interfaces in graphene and hexagonal Boron Nitride lateral heterostructures. Chem. Mater. 28(14), 5022–5028 (2016). doi:10.1021/acs.chemmater.6b01764

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Michel-Marie Deza.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Deza, MM., Sikirić, M.D. Lego-like spheres and tori. J Math Chem 55, 752–798 (2017). https://doi.org/10.1007/s10910-016-0706-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10910-016-0706-8

Keywords

Navigation