Abstract
Two Co(II)-based coordination polymers: {Co(L1)(bimb)·H2O·OH}n (1) and [Co(L2)(bidpe)]n (2) (H2L1 = 4-mercaptobenzoic acid, H2L2 = 4,4′-bis(thiomethylene) dibenzoic acid, bimb = 1,4-bis(imidazol-1-ylmethyl)benzene), bidpe = 4,4′-bis(imidazolyl)diphenyl ether), were synthesized under the condition of solvothermal and characterized by X-ray single-crystal diffraction, elemental analysis, IR spectra and thermogravimetric analysis (TGA). X-ray single-crystal diffraction analysis exhibits that 1 and 2 belong to the monoclinic crystal system, space group P21 and Cc. Complex 1 adopts a tetrahedron {CoN2O2} coordination geometry and complex 2 possesses a distorted trigonal bipyramid {CoN2O3} coordination geometry. Topology analysis results show that complex 1 and 2 possess a uninodal 4-connected 2D (two-dimensional) sql topology framework with the Schläfli symbol (44·62). Furthermore, the photocatalytic degradation property and mechanism of 1 and 2 for methylene blue (MB) were investigated. The results show that the band gap (Eg) of 1–2 is 2.69 eV and 2.60 eV, and the equipotential point (pHpzc) of 1–2 is 4.47 and 4.40. Complex 1–2 show excellent photocatalytic degradation for MB. ·OH is the main active substance causing MB degradation.
Similar content being viewed by others
References
C.C. Wang, J. Zhang, P. Wang, H. Wang, H. Yan, Desalin. Water Treat. (2014). https://doi.org/10.1080/19443994.19442013.19873881
N.M. Mahmoodi, R. Salehi, M. Arami, Desalination 272, 187 (2011)
X.J. Li, F.Y. Qian, M. Li, Environ. Chem. 3, 396 (2012)
N. Peng, K.F. Wang, C.Q. Tu, Environ. Prot. Chem. Ind. 5, 464 (2011)
L.L. Fan, R.W. Lu, W.P. Chen, Environ. Sci. Technol. S1, 19 (2009)
C. Chen, P. Gunawan, R. Xu, J. Mater. Chem. 21, 1218 (2011)
M. Fang, F. Mishima, Y. Akiyama, Physica C 470, 1827 (2010)
M. Zhou, H. Sarkka, M. Sillanpaa, Sep. Purif. Technol. 78, 290 (2011)
Y. Yao, K. Li, S. Chen, Chem. Eng. J. 187, 29 (2012)
S.I. Lim, W.I. Chu, S.M. Phang, Bioresour. Technol. 101, 7314 (2010)
B. Liang, Q. Yao, H. Cheng, Environ. Sci. Pollut. R. 19, 1385 (2012)
L.S. Cui, J.R. Meng, Y.L. Gan, Y.C. Li, Inorg. Nano-Metal Chem. 47, 1537 (2017)
L.S. Cui, X.M. Meng, Y.H. Fan, X. Li, C.F. Bi, J. Inorg. Organomet. Polym. 25, 1490 (2015)
X.M. Meng, Y.C. Li, K.R. Huang, J.Q. Long, L.S. Cui, Inorg. Chim. Acta 482, 284 (2018)
D.S. Liu, W.T. Chen, G.M. Ye, J.Q. Liu, Y. Sui, Inorg. Chim. Acta 477, 84 (2018)
L.S. Cui, X.M. Meng, Y.G. Li, K.R. Huang, Y.C. Li, J.Q. Long, P.F. Yao, CrystEngComm 21, 3798 (2019)
R. Bagade, R.G. Chaudhary, A. Potbhare, A. Mondal, M. Desimone, K. Dadure, R. Mishra, H. Juneja, ChemistrySelect 4, 6233 (2019)
R.G. Chaudhary, H.D. Juneja, M.P. Gharpure, J. Therm. Anal. Calorim. 112, 637 (2013)
R.G. Chaudhary, H.D. Juneja, M.P. Gharpure, J. Chin. Adv. Mater. Soc. 1, 121 (2013)
Y.B. He, W. Zhou, G. Qian, Chem. Soc. Rev. 43, 5657 (2014)
J.A. Mason, M. Veenstra, J.R. Long, Chem. Sci. 5, 32 (2014)
W. Zhou, D.D. Huang, Y.P. Wu, J. Zhao, T. Wu, J. Zhang, D.S. Li, C.H. Sun, P.Y. Peng, X.H. Bu, Angew. Chem. Int. Ed. 58, 4227 (2019)
J.W. Tian, Y.P. Wu, Y.S. Li, J.H. Wei, J.W. Yi, S. Li, J. Zhao, D.S. Li, Inorg. Chem. 58, 5837 (2019)
D.D. Huang, S. Li, Y.P. Wu, J.H. Wei, J.W. Yi, H.M. Ma, Q.C. Zhang, Y.L. Liu, D.S. Li, Chem. Commun. 55, 4570 (2019)
J. Ye, L. Zhao, R.F. Bogale, Chem. A Eur. J. 21, 2029 (2015)
W.P. Lustig, S. Mukherjee, N.D. Rudd, Chem. Soc. Rev. 46, 3242 (2017)
T. Yamada, M. Sadakiyo, A. Shigematsu, Bull. Chem. Soc. Jpn. 89, 1 (2015)
S.S. Bao, G.K.H. Shimizu, L.M. Zheng, Coordin. Chem. Rev. 378, 577 (2017)
V.A. Blatov, IUCrCompComm Newsletter 7, 4 (2006)
O.D. Friedrichs, Program SYSTRE 1.14 beta (2007)
G.M. Sheldrick, SHELXTL NT, version 5.1, Program for Solution, Refinement of Crystal Structures, University of GÖttingen, GÖttingen, Germany (1997).
Bruker, SMART, version 5.0, SAINT-plus version 6, SHELXTL, version 6.1, SADABS version 2.03, Bruker AXS Inc.: Madison, WI (2000).
J. Lü, J.X. Lin, X.L. Zhao, R. Cao, Chem. Commun. 48, 669 (2012)
X.L. Wang, C.H. Gong, J.W. Zhang, G.C. Liu, X.M. Kan, N. Xu, CrystEngComm 17, 4179 (2015)
R.G. Chaudhary, P. Ali, N.V. Gandhare, J.A. Tanna, H.D. Juneja, Arab. J. Chem. (2016). https://doi.org/10.1016/j.arabjc.2016.03.008
Y. Gong, T. Wu, J. Lin, CrystEngComm 14, 3727 (2012)
H.S. Liu, Y.Q. Lan, S.L. Li, Cryst. Growth Des. 10, 5221 (2010)
J. Guo, J.F. Ma, B. Liu, W.Q. Kan, J. Yang, Cryst. Growth Des. 11, 3609 (2011)
N. Zaghbani, A. Hahiane, M. Dhahbi, Sep. Purif. Technol. 55, 117 (2007)
J.L. Gong, B. Wang, G.M. Zeng, C.P. Yang, C.G. Niu, Q.Y. Niu, W.J. Zhou, Y. Liang, J. Hazard. Mater. 164, 1517 (2009)
T.T. Li, Y.M. He, H.J. Lin, J. Cai, L.Z. Dong, X.X. Wang, M.F. Luo, L.H. Zhao, X.D. Yi, W.Z. Weng, Appl. Catal. B 138, 95 (2013)
Y.H. Liang, S.L. Lin, L. Liu, J.S. Hu, W.Q. Cui, Appl. Catal. B 164, 192 (2015)
H.X. Yang, T.F. Liu, M.N. Cao, H.F. Li, S.Y. Gao, R. Cao, Chem. Commun. 46, 2429 (2010)
X.M. Meng, C.B. Fan, C.F. Bi, Z.A. Zong, X. Zhang, Y.H. Fan, CrystEngComm 18, 2901 (2016)
Acknowledgements
This research was supported by the Guangxi Natural Science Foundation to P. F. Yao (2018GXNSFBA281197, 2018GXNSFAA294060) and the university-level scientific research project of Baise University in 2018 to L. S. Cui (2018KN17).
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Zuo, W., Fan, Y., Yang, L. et al. Synthesis, Structure and Photocatalytic Dye Degradation Ability of Co(II)-Based Coordination Polymers. J Inorg Organomet Polym 30, 2105–2113 (2020). https://doi.org/10.1007/s10904-019-01356-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10904-019-01356-0