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Synthesis of Im3[Mo3(μ3-S)(μ-S2)3Br6]Br (Im = 1-ethyl-3-methylimidazolium) in Ionic Liquid: A New Way of Breaking Up Chalcogenide Cluster Coordination Polymers

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Abstract

Reaction of 1D cluster coordination polymer Mo3S7Br4 with an ionic liquid composed of 1-ethyl-3-methylimidazolium bromide (ImBr) and AlBr3 in 2:1 molar ratio affords Im3[Mo3(μ3-S)(μ-S2)3Br6]Br (1) in high yield. X-ray structure of 1·CH 3 CN is reported.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Russian Academy of Sciences, pr. Lavrentyeva 3, Novosibirsk, 630090, Russia

    M. N. Sokolov, A. V. Rogachev, A. V. Virovets, D. A. Piryazev & V. P. Fedin

  2. Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia

    M. N. Sokolov & V. P. Fedin

Authors
  1. M. N. Sokolov
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  2. A. V. Rogachev
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  3. A. V. Virovets
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  4. D. A. Piryazev
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  5. V. P. Fedin
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Correspondence to M. N. Sokolov.

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Sokolov, M.N., Rogachev, A.V., Virovets, A.V. et al. Synthesis of Im3[Mo3(μ3-S)(μ-S2)3Br6]Br (Im = 1-ethyl-3-methylimidazolium) in Ionic Liquid: A New Way of Breaking Up Chalcogenide Cluster Coordination Polymers. J Clust Sci 26, 33–40 (2015). https://doi.org/10.1007/s10876-014-0739-8

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