Abstract
Carbon felt is a potential material for electrochemical reduction of chromates. Very dilute solutions may be efficiently treated due to its large specific surface area and high porosity. In this work, the up-scaling of this technology is investigated using a new type of separated cell and once-through flow of industrial rinse water. A significant enhancement of the process is obtained due to copper deposition during long-term operation. The co-deposition and re-solution of copper occurs depending on the inlet chromate concentration. When previously deposited copper is present a current-free reduction of chromate takes place resulting in current efficiencies apparently above 100%. Very high space time yields are obtained even for effluents at low concentration and optimised conditions (high flow rates and pH 2). The economic feasibility of the technology is also considered. Continuous, single-pass operation results in lower energy requirements than batch processing. The economic potential of the process is also evaluated in comparison with chemical detoxification of chromate. The operating costs for the electrochemical treatment of very dilute effluents on a carbon felt electrode are 30% lower than for the chemical method.
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Kolthoff I.M., Shams El Din A.M. (1956). J. Phys. Chem. 60(11): 1564
Robertson P.M., Schwager F., Ibl N. (1975). J. Electroanal. Chem. 65(2): 883
Chaudhary A.J., Goswami N.C., Grimes S.M. (2003). J. Chem. Tech. & Biotech. 78(8): 877
Ibl N., Frei A.M. (1964). Galvanotech. & Oberflächenschutz 5(6): 117 (in German)
Kimmerl P., Schade H., Blatt W., Schneider L. (1994). Galvanotech. 85(12): 4131 (in German)
Wijnbelt E.C.W., Janssen L.J.J. (1994). J. Appl. Electrochem. 24: 1028
Njau K.N., Janssen L.J.J. (1999). J. Appl. Electrochem. 29: 411
S. Reussard, J.F. Benezech and G. Lacoste, Removal of hexavalent chromium converting to chromium hydroxide by treatment in an electrochemical reactor, in “Electrochemical Engineering and the environment 1992” (1992) 97
Langefeld E. (1992). Galvanotech. 83(11): 3859
Dziewinski J., Marczak S., Nuttall E., Purdy G., Smith W., Taylor J., Zhou C. (1998). Waste Manag. 18: 257
Kongsricharoern N., Polprasert C. (1995). Wat. sci. & techn. 31(9): 109
Kongsricharoern N., Polprasert C. (1996). Wat. sci. tech. 34(9): 109–116
Barrera-Díaz C., Palomar-Pardave M., Romero-Romo M., Martínez S. (2003). J. Appl. Electrochem. 33: 61
Golub D., Oren Y. (1989). J. Appl. Electrochem. 19: 311
Abda M., Gavra Z., Oren Y. (1991). J. Appl. Electrochem. 21: 734
Roberts E.P.L., Yu H. (2002). J. Appl. Electrochem. 32: 1091–1099
Varenzov V.K. (2002). Galvanotech. obrab. poverchnosti (Russia) 10(1): 29 (in Russian)
Vilar E.O., Cavalcanti E.B., Carvalho H.R., Sousa F.B. (2003). Braz. J. Chem. Engin. 20(3): 291
González-García J., Bonete P., Expósito E., Montiel V., Aldaz A., Torregrosa-Maciá R. (1999). J. Mat. Chem. 9(2): 419
I.M. Dalrymple, S.J.G. and M. Hendou, The Recovery and Recycling of Cr(VI) from Dilute Waste Solutions. Canmet/Cari/European Commission Joint Workshop on “Environmental Technologies for a Sustainable Production and Consumption” (Vancouver, Canada, 2003).
F. Walsh, A first course in electrochemical engineering, the Electrochemical Consultancy (1993).
Daniel-Bek V.S. (1948). J. Phys. Chem. (UdSSR) 22(6): 697 (in Russian)
Varenzov V.K. (1988) Use of voluminous porous flow-through electrodes for increased performance of electrochemical processes in hydrometallurgy, in “Increasing performance of electrochemical processes. Collection of scientific studies”. In: Tomilov A.P. (eds) Academy of Science of UdSSR Institute for Electrochemistry “AN Frunkin”. Nauka, Moscow, p. 94 (in Russian)
F. Walsh, Electrode Potential and Current Density Distribution, in ‘A first course in electrochemical engineering’. The Electrochemical Consultancy (1993) 235
Simmrock K.H. (1968). Chem. Ingen. Techn. 40: 875 (in German)
Kreysa G. (1978). Chem.-Ing.-Tech. 50(5): 332 (in German)
Wendt H., Kreysa G. (1999) Electrochemical Engineering: science and technology in chemical and other industries. Heidelberg, Springer-Verlag
Podlaha E.J., Fenton J.M. (1995). J. Appl. Electrochem. 25: 299
Acknowledgements
The authors thank FuMA-Tech GmbH for financial support, Jörg Balster for making the SEM photographs, Hartchrom GmbH, Karlsruhe, Germany for support during pilot experiments and Dr. Norbert Berg (SGL TECHNOLOGIES GmbH, Meitingen, Germany) for the carbon felt.
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Frenzel, I., Holdik, H., Barmashenko, V. et al. Electrochemical reduction of dilute chromate solutions on carbon felt electrodes. J Appl Electrochem 36, 323–332 (2006). https://doi.org/10.1007/s10800-005-9074-y
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DOI: https://doi.org/10.1007/s10800-005-9074-y