Abstract
Multivariate statistical techniques were employed for monitoring of ground-surface water interactions in rivers. The river Varuna is situated in the Indo-Gangetic plain and is a small tributary of river Ganga. The study area was monitored at seven sampling sites for 3 years (2010–12), and eight physio-chemical parameters were taken into account for this study. The data obtained were analysed by multivariate statistical techniques so as to reveal the underlying implicit information regarding proposed interactions for the relevant area. The principal component analysis (PCA) and cluster analysis (CA), and the results of correlations were also studied for all parameters monitored at every site. Methods used in this study are essentially multivariate statistical in nature and facilitate the interpretation of data so as to extract meaningful information from the datasets. The PCA technique was able to compress the data from eight to three parameters and captured about 78.5 % of the total variance by performing varimax rotation over the principal components. The varifactors, as yielded from PCA, were treated by CA which grouped them convincingly into three groups having similar characteristics and source of contamination. Moreover, the loading of variables on significant PCs showed correlations between various ground water and surface water (GW-SW) parameters. The correlation coefficients calculated for various physiochemical parameters for ground and surface water established the correlations between them. Thus, this study presents the utility of multivariate statistical techniques for evaluation of the proposed interactions and effective future monitoring of potential sites.
Similar content being viewed by others
References
Anibas, C., Buis, K., Verhoeven, R., Meire, P., & Batelaan, O. (2011). A simple thermal mapping method for seasonal spatial patterns of ground water-surface water interaction. Journal of Hydrology, 397(1–2), 93–104.
APHA (1998) Standard methods for the examination of water and wastewater, American Public Health Association Washington D.C., Ed.19.
Arslan, H. (2013). Application of multivariate statistical techniques in the assessment of groundwater quality in seawater intrusion area in Bafra Plain, Turkey. Environmental Monitoring and Assessment, 185(3), 2439–2452.
Barai, S. R., & Kumar, S. (2013). Evaluation of the physio-chemical characterestics of river Varuna at Varanasi, India. Journal of Environmental Biology, 34, 259–265.
Chaturvedi, R. K., & Raghubanshi, A. S. (2015). Assessment of carbon density and accumulation in mono-and multi-specific stands in Teak and Sal forests of a tropical dry region in India. Forest Ecology and Management 339, 11–21.
Harveya, W. J., Newlina, T. J., & Krupab, L. S. (2006). Modeling decadal timescale interactions between surface water and ground water in the Central Everglades, Florida, USA. Journal of Hydrology, 320, 400–420.
Helena, B., Pardo, R., Vega, M., Barrado, E., Fernandez, J. M., & Fernandez, L. (2000). Temporal evolution of groundwater composition in an alluvial aquifer (Pisuerga River, Spain) by principal component analysis. Water Research, 34(3), 807–816.
House, W. A. (1999). The physico-chemical conditions for the precipitation of phosphate with calcium. Environmental Technology, 20(7), 727–733.
Hutton, L. G. (1983). Field testing of water in developing countries. Medmenham, England: Water Research Center.
Isa, N. M., Aris, A. Z., & Sulaiman, W. A. N. W. (2012). Extent and severity of groundwater contamination based on hydrochemistry mechanism of sandy tropical coastal aquifer. Science of the Total Environment, 438, 414–425.
Kikuchi, C. P., Ferre, T. P. A., & Welker, J. M. (2012). Spatially telescoping measurements for improved characterization of ground water-surface water interactions. Journal of Hydrology, 446–447, 1–12.
Kumar, S., Mishra, P.K., Singh, N.L., Singh, K.K. & Srivastava, P. (2012). Water Quality of River Varuna in Varanasi City, Uttarpradesh, India. Asian Journal of Biochemical and Pharmaceutical Research (2).
Lu, X., Zhou, Z., & Wang, J. (2011). Analysis on interactions among atmosphere, surface and ground water using EARTH model in the unsaturated zone. Procedia Environmental Sciences, 8, 134–139.
Mencio, A., & Mas-Pla, J. (2008). Assessment by multivariate analysis of groundwater-surface water interactions in urbanized Mediterranean streams. Journal of Hydrology, 352(3–4), 355–366.
Mishra, A. (2010). Assessment of water quality using principal component analysis: a case study of the river Ganges. Journal of Water Chemistry and Technology, 32(4), 227–234.
Mishra, A. K. (2011). Impact of urbanization on the hydrology of Ganga Basin (India). Water Resources Management, 25(2), 705–719.
Otto, M. (1998). Multivariate methods. In R. Kellner, J. M. Mermet, M. Otto, & H. M. Widmer (Eds.), Analytical chemistry. Weinheim: WileyeVCH.
Pandey, D. S. (1993). Groundwater pollution studies in urban settlements of Varanasi city, UP, Annual work programme report, 1992–1993, (p 35). Allahabad: Central Groundwater Board.
Raju, N. J., Ram, P., & Dey, S. (2009). Groundwater quality in the Lower Varuna River Basin, Varanasi District, Uttar Pradesh. Journal of the Geological Society of India, 73(2), 178–192.
Selle, B., Schwientek, M., & Lischeid, G. (2013). Understanding processes governing water quality in catchments using principal component scores. Journal of Hydrology, 486, 31–38.
Sharma, D., & Kansal, A. (2011). Water quality analysis of river Yamuna using water quality index in the national capital territory, India (2000–2009). Applied Water Science, 1, 147–157.
Shrestha, S., & Kazama, F. (2007). Assessment of surface water quality using multivariate statistical techniques: a case study of the Fuji river basin. Environmental Modelling & Software, 22(4), 464–475.
Shukla, U. K., & Raju, J. N. (2008). Migration of the Ganga river and its implication on hydro-geological potential of Varanasi area, U.P., India. Journal of Earth System Science, 117(4), 489–498.
Simeonova, P., Simeonov, V., & Andreev, G. (2003). Environmetric analysis of the Struma River water quality. Central European Journal of Chemistry, 2, 121–126.
Singh, S. J., & Dwivedi, A. K. (2007). Numerical interdependence in pH, acidity and alkalinity of a polluted river water. Journal of Environmental Biology, 30(5), 773–775.
Singh, S., & Singh, K. N. (2010). Physio-chemical analysis of sewage discharged into Varunariver at Varanasi. Current World Environment, 5(1), 201–203.
Singh, K. P., Malik, A., & Sinha, S. (2005a). Water quality assessment and apportionment of pollution sources of Gomti river (India) using multivariate statistical techniques a case study. Analytica Chimica Acta, 538(1–2), 355–374.
Singh, K. P., Malik, A., Singh, V. K., Mohan, D., & Sinha, S. (2005b). Chemometric analysis of groundwater quality data of alluvial aquifer of Gangetic plain, North India. Analytica Chimica Acta, 550(1–2), 82–91.
Singh, K. P., Malik, A., Sinha, S., Singh, V. K., & Murthy, R. C. (2005c). Estimation of source of heavy metal contamination in sediments of Gomti River (India) using principal component analysis. Water, Air, and Soil Pollution, 166(1–4), 321–341.
Singh, K. P., Gupta, S., & Mohan, D. (2014). Evaluating influences of seasonal variations and anthropogenic activities on alluvial groundwater hydrochemistry using ensemble learning approaches. Journal of Hydrology, 511, 254–266.
Sojka, M., Siepak, M., Ziola, A., Frankowski, M., Murat-Blazejwska, S., & Siepak, J. (2008). Application of multivariate statistical techniques to evaluation of water quality in the Mala Welna River (Welna Poland). Environmental Monitoring and Assessment, 147, 159–170.
Sophocleous, M. (2002). Interactions between ground water and surface water: the state of the science. Hydrogeology Journal, 10, 52–67.
Soulsby, C., Gibbins, C., Wade, A. J., Smart, R., & Helliwell, R. (2002). Water quality in the Scottish uplands: a hydrological perspective on catchment hydrochemistry. Science of the Total Environment, 294(1–3), 73–94.
Stigter, T. Y., Carvalho Dill, A. M. M., Ribeiro, L., & Reis, E. (2006). Impact of the shift from groundwater to surface water irrigation on aquifer dynamics and hydrochemistry in a semi-arid region in the south of Portugal. Agricultural Water Management, 85, 121–132.
Sundaray, K. S., Panda, C. U., Nayak, B. B., & Bhatta, D. (2006). Multivariate statistical techniques for the evaluation of spatial and temporal variations in water quality of the Mahanadi river-estuarine system (India) a case study. Environmental Geochemistry and Health, 28, 317–330.
Valett H.M., & Sheibley, R.W. (2009).Ground water and surface water interactions. Reference Module in Earth Systems and Environmental Sciences, from Encyclopedia of Inland Waters, 691–702.
Varol, M., Gokot, B., Bekleyen, A., & Sen, B. (2013). Geochemistry of the Tigris River basin, Turkey: spatial and seasonal variations of major ion compositions and their controlling factors. Quaternary International, 304, 22–32.
Vega, M., Pardo, R., Barrado, E., & Deban, L. (1998). Assessment of seasonal and polluting effects on the quality of river water by exploratory data analysis. Water Research, 32(12), 3581–3592.
Wade, J. A., Butterfield, D., & Whitehead, G. P. (2006). Towards an improved understanding of the nitrate dynamics in lowland, permeable river-systems: applications of INCA-N. Journal of Hydrology, 330(1–2), 185–203.
Woocay, A., & Walton, J. (2008). Multivariate analysis of water chemistry: surface and ground water interactions. Ground Water, 46(3), 437–449.
Wunderlin, D. A., Diaz, M. P., Ame, M. V., Pesce, S. F., Hued, A. C., & Bistoni, M. A. (2001). Pattern recognition techniques for the evaluation of spatial and temporal variations in water quality. A case study: Suquia river basin (Cordoba, Argentina). Water Research, 35, 2881–2894.
Yu, Y. J., Guan, J., Ma, Y. W., Yu, S. X., Guo, H. C., & Bao, L. Y. (2010). Aquatic environmental quality variation in Lake Dianchi watershed. Procedia Environmental Sciences 2, 76–81.
Acknowledgments
Pardeep Singh and Rishikesh Singh thank University Grants Commission and Council of Scientific and Industrial Research, Govt. of India for funding support. Pardeep Singh also thanks Indian Institute of Technology (Banaras Hindu University) for funding support. R.K. Chaturvedi thanks Council of Scientific and Industrial Research, Govt. of India for funding support. D.D. Giri thanks University Grants Commission, Govt. of India for funding support. Authors also thank the two anonymous reviewers for reviewing the manuscript and offering helpful suggestions.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Singh, P., Chaturvedi, R.K., Mishra, A. et al. Assessment of ground and surface water quality along the river Varuna, Varanasi, India. Environ Monit Assess 187, 170 (2015). https://doi.org/10.1007/s10661-015-4382-0
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s10661-015-4382-0