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ZnO nanosheet-promoted synthesis of 1,3-oxathiol-2-ylidene derivatives using alkyl bromides in water

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Chemistry of Heterocyclic Compounds Aims and scope

The N-(1,3-oxathiol-2-ylidene)carboxamides have been synthesized in excellent yield in the reaction between alkyl bromide, acid chloride, and ammonium thiocyanate in the presence of catalytic amount of ZnO nanosheets (15 mol %) in water as a solvent at room temperature. The separation of product from the reaction mixture is very simple. Using NS-ZnO as a catalyst considerably improves the yield of the desired product in comparison with performing these reactions without catalyst. The catalyst shows good reusability.

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Authors and Affiliations

  1. Department of Chemistry, Gorgan Branch, Islamic Azad University, Gorgan, Iran

    Ali Varasteh Moradi

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  1. Ali Varasteh Moradi
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Correspondence to Ali Varasteh Moradi.

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Published in Khimiya Geterotsiklicheskikh Soedinenii, 2015, 51(9), 834–837

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Moradi, A.V. ZnO nanosheet-promoted synthesis of 1,3-oxathiol-2-ylidene derivatives using alkyl bromides in water. Chem Heterocycl Comp 51, 834–837 (2015). https://doi.org/10.1007/s10593-015-1783-5

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  • DOI: https://doi.org/10.1007/s10593-015-1783-5

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