Abstract
The conditions and regimes of thermal ignition of a reactive porous layer are investigated under asymmetric conditions on its lateral surfaces and with an oxidizer supply to the layer by diffusion or filtration through the cold boundary. For a zero-order reaction, an analytical dependence of the critical value of the Frank-Kamenetskii parameter on the Zel’dovich parameter is obtained, which separates the regions of steady-state and unsteady regimes. A numerical analysis is made of the critical value of the Frank-Kamenetskii parameter on the Zel’dovich parameter, the Todes parameter, which determines the oxidizer consumption, and the parameter determining the oxidizer supply to the layer: the Lewis numbers or the filtration analog of the Peclet parameter.
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References
J. H. van’t Hoff, Studies of Chemical Dynamics, Williams and Norgate, London (1896).
N. N. Semenov, “Theory of combustion,” Zh. Russ. Fiz.-Khim. Obshch., Fizika, 60, 241–250 (1928).
D. A. Frank-Kamenetskii, Diffusion and Heat Transfer in Chemical Kinetics, Plenum, New York (1969).
A. G. Merzhanov, V. V. Barzykin, and V. G. Abramov, “Theory of thermal explosion: from N. N. Semenov to the present day,” Khim. Fiz., 15, No. 6, 3–44 (1996).
Ya. B. Zel’dovich, “Theory of reactions on porous or powder materials,” Zh. Fiz. Khim., 13, No. 2, 163–168 (1939).
E. A. Eremin and A. K. Kolesnikov, “Steady-state theory of thermal explosions,” Combust., Expl., Shock Waves, 14, No. 5, 658–660 (1978).
A. K. Kolesnikov, “Thermal explosion in a layer with boundaries at different temperature in the case of transverse reagent motion,” Combust., Expl., Shock Waves, 20, No. 3, 305–306 (1984).
N. E. Kolovertnykh, N. E. Khudyaev, and A. S. Shteinberg, “Characteristic conditions of an exothermic reaction in a porous body-gas system,” Combust., Expl., Shock Waves, 16, No. 4, 416–422 (1980).
N. E. Kolovertnykh, V. B. Ulybin, N. E. Khudyaev, and A. S. Shteinberg, “Conditions of exothermal conversion in a porous bed with diffusional supply of gaseous reagent,” Combust., Expl., Shock Waves, 18, No. 1, 59–64 (1982).
T. Takeno and K. Sato, “Effect of oxygen diffusion on ignition and extinction of self-heating porous bodies,” Combust. Flame, 38, No. 1, 75–87 (1980).
I. G. Dik, “Steady regimes of nonisothermal chemical reactions in a porous layer,” Combust., Expl., Shock Waves, 29, No. 6, 724–737 (1993).
A. A. Seleznev, D. A. Kreknin, and M. R. Maksimenko, “Calculation of the critical conditions for an exothermic reaction with a porous body,” Khim. Fiz., 6, No. 4, 538–542 (1987).
L. A. Zhukova and S. I. Khudyaev “Averaging method in calculations of the exothermal reaction in porous-body-gas systems,” Combust., Expl., Shock Waves, 25, No. 3, 305–310 (1989).
O. V. Matyukhina and V. I. Babushok, “Self-heating of a layer of coal,” Combust., Expl., Shock Waves, 28, No. 6, 573–580 (1992).
V. I. Babushok, V. M. Goldshetin, A. S. Romanov, and V. S. Babkin, “Thermal explosion in an inert porous medium,” Combust., Expl., Shock Waves, 28, No. 4, 319–325 (1992).
R. S. Burkina and E. G. Rogacheva, “Characteristics of thermal explosion in a porous layer with diffusion of a gaseous reactant,” Combust., Expl., Shock Waves, 32, No. 2, 204–210 (1996).
K. G. Shkadinskii and N. I. Ozerkovskaya, “Thermal explosion in porous medium-gas reactant-solid product systems,” Dokl. Ross. Akad. Nauk, 373, No. 1, 69–72 (2000).
K. G. Shkadinskii and N. I. Ozerkovskaya, and A. G. Merzhanov, “Postinduction processes in thermal explosion in porous medium-gas reactant-solid product systems,” Dokl. Ross. Akad. Nauk, 381, No. 6, 763–769 (2001).
A. G. Merzhanov, N. I. Ozerkovskaya, and K. G. Shkadinskii, “Thermal explosion as a technological method for high-temperature syntheses in inorganic systems (theory),” Khim. Fiz., 23, No. 8, 67–74 (2004).
N. I. Ozerkovskaya, and K. G. Shkadinskii, “Thermal explosion in porous bed + gas reactant + solid product systems with gas filtration,” in: Abstracts of XIII Symp. on Combustion and Explosion, CD ROM, Chenogolovka, February 7–11 (2005).
D. A. Vaganov, N. G. Samoilenko, V. N. Bloshenko, V. G. Shteinberg, and G. B. Manelis, “Peculiarities of ignition of porous systems for natural filtration of a gaseous oxidizer,” Combust. Flame, 126, 1803–1809 (2001).
A. V. Pivushkov, N. G. Peregudov, and N. G. Samoilenko, “Ignition regimes of heterogeneous systems,” Khim. Fiz., 24, No. 2, 82–87 (2005).
A. V. Pivushkov, N. G. Peregudov, and N. G. Samoilenko, “Ignition of a porous fuel under forced filtration of gaseous oxidizer,” in: Abstracts of XIII Symp. on Combustion and Explosion, CD ROM, Chenogolovka, February 7–11 (2005).
Ya. B. Zel’dovich, “Theory of ignition by a hot surface,” Zh. Èksp. Teor. Fiz., 9, No. 12, 1530–1534 (1939).
É. F. Konev, Physical Foundations of Combustion of Vegetative Materials [in Russian], Nauka, Novosibirsk (1977).
E. J. Anthony and D. Greaney, “The safety of hot self heating materials,” Combust. Sci. Technol., No. 1, 79–85 (1979).
R. S. Burkina and V. G. Gorban’, “Effect of diffusion of gaseous oxidizer on the ignition of a reactive porous layer,” in: Physics and Chemistry of High Energy Systems, Proc. Conf., Tomsk Univ., Tomsk (2003), pp. 61–62.
V. G. Prokofev and V. K. Smolyakov “Impact of structural factors on unsteady combustion modes of gasless systems,” Combust., Expl., Shock Waves, 39, No. 2, 167–176 (2003).
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Translated from Fizika Goreniya i Vzryva, Vol. 44, No. 3, pp. 50–60, May–June, 2008.
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Burkina, R.S., Prokof’ev, V.G. Critical conditions of thermal explosion of a porous layer. Combust Explos Shock Waves 44, 291–299 (2008). https://doi.org/10.1007/s10573-008-0037-6
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DOI: https://doi.org/10.1007/s10573-008-0037-6