Skip to main content
Log in

Critical conditions of thermal explosion of a porous layer

  • Published:
Combustion, Explosion, and Shock Waves Aims and scope

Abstract

The conditions and regimes of thermal ignition of a reactive porous layer are investigated under asymmetric conditions on its lateral surfaces and with an oxidizer supply to the layer by diffusion or filtration through the cold boundary. For a zero-order reaction, an analytical dependence of the critical value of the Frank-Kamenetskii parameter on the Zel’dovich parameter is obtained, which separates the regions of steady-state and unsteady regimes. A numerical analysis is made of the critical value of the Frank-Kamenetskii parameter on the Zel’dovich parameter, the Todes parameter, which determines the oxidizer consumption, and the parameter determining the oxidizer supply to the layer: the Lewis numbers or the filtration analog of the Peclet parameter.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. J. H. van’t Hoff, Studies of Chemical Dynamics, Williams and Norgate, London (1896).

    Google Scholar 

  2. N. N. Semenov, “Theory of combustion,” Zh. Russ. Fiz.-Khim. Obshch., Fizika, 60, 241–250 (1928).

    Google Scholar 

  3. D. A. Frank-Kamenetskii, Diffusion and Heat Transfer in Chemical Kinetics, Plenum, New York (1969).

    Google Scholar 

  4. A. G. Merzhanov, V. V. Barzykin, and V. G. Abramov, “Theory of thermal explosion: from N. N. Semenov to the present day,” Khim. Fiz., 15, No. 6, 3–44 (1996).

    Google Scholar 

  5. Ya. B. Zel’dovich, “Theory of reactions on porous or powder materials,” Zh. Fiz. Khim., 13, No. 2, 163–168 (1939).

    Google Scholar 

  6. E. A. Eremin and A. K. Kolesnikov, “Steady-state theory of thermal explosions,” Combust., Expl., Shock Waves, 14, No. 5, 658–660 (1978).

    Google Scholar 

  7. A. K. Kolesnikov, “Thermal explosion in a layer with boundaries at different temperature in the case of transverse reagent motion,” Combust., Expl., Shock Waves, 20, No. 3, 305–306 (1984).

    MathSciNet  Google Scholar 

  8. N. E. Kolovertnykh, N. E. Khudyaev, and A. S. Shteinberg, “Characteristic conditions of an exothermic reaction in a porous body-gas system,” Combust., Expl., Shock Waves, 16, No. 4, 416–422 (1980).

    Article  Google Scholar 

  9. N. E. Kolovertnykh, V. B. Ulybin, N. E. Khudyaev, and A. S. Shteinberg, “Conditions of exothermal conversion in a porous bed with diffusional supply of gaseous reagent,” Combust., Expl., Shock Waves, 18, No. 1, 59–64 (1982).

    Article  Google Scholar 

  10. T. Takeno and K. Sato, “Effect of oxygen diffusion on ignition and extinction of self-heating porous bodies,” Combust. Flame, 38, No. 1, 75–87 (1980).

    Article  Google Scholar 

  11. I. G. Dik, “Steady regimes of nonisothermal chemical reactions in a porous layer,” Combust., Expl., Shock Waves, 29, No. 6, 724–737 (1993).

    Article  Google Scholar 

  12. A. A. Seleznev, D. A. Kreknin, and M. R. Maksimenko, “Calculation of the critical conditions for an exothermic reaction with a porous body,” Khim. Fiz., 6, No. 4, 538–542 (1987).

    Google Scholar 

  13. L. A. Zhukova and S. I. Khudyaev “Averaging method in calculations of the exothermal reaction in porous-body-gas systems,” Combust., Expl., Shock Waves, 25, No. 3, 305–310 (1989).

    Article  Google Scholar 

  14. O. V. Matyukhina and V. I. Babushok, “Self-heating of a layer of coal,” Combust., Expl., Shock Waves, 28, No. 6, 573–580 (1992).

    Article  Google Scholar 

  15. V. I. Babushok, V. M. Goldshetin, A. S. Romanov, and V. S. Babkin, “Thermal explosion in an inert porous medium,” Combust., Expl., Shock Waves, 28, No. 4, 319–325 (1992).

    Article  Google Scholar 

  16. R. S. Burkina and E. G. Rogacheva, “Characteristics of thermal explosion in a porous layer with diffusion of a gaseous reactant,” Combust., Expl., Shock Waves, 32, No. 2, 204–210 (1996).

    Article  Google Scholar 

  17. K. G. Shkadinskii and N. I. Ozerkovskaya, “Thermal explosion in porous medium-gas reactant-solid product systems,” Dokl. Ross. Akad. Nauk, 373, No. 1, 69–72 (2000).

    MATH  Google Scholar 

  18. K. G. Shkadinskii and N. I. Ozerkovskaya, and A. G. Merzhanov, “Postinduction processes in thermal explosion in porous medium-gas reactant-solid product systems,” Dokl. Ross. Akad. Nauk, 381, No. 6, 763–769 (2001).

    Google Scholar 

  19. A. G. Merzhanov, N. I. Ozerkovskaya, and K. G. Shkadinskii, “Thermal explosion as a technological method for high-temperature syntheses in inorganic systems (theory),” Khim. Fiz., 23, No. 8, 67–74 (2004).

    Google Scholar 

  20. N. I. Ozerkovskaya, and K. G. Shkadinskii, “Thermal explosion in porous bed + gas reactant + solid product systems with gas filtration,” in: Abstracts of XIII Symp. on Combustion and Explosion, CD ROM, Chenogolovka, February 7–11 (2005).

  21. D. A. Vaganov, N. G. Samoilenko, V. N. Bloshenko, V. G. Shteinberg, and G. B. Manelis, “Peculiarities of ignition of porous systems for natural filtration of a gaseous oxidizer,” Combust. Flame, 126, 1803–1809 (2001).

    Article  Google Scholar 

  22. A. V. Pivushkov, N. G. Peregudov, and N. G. Samoilenko, “Ignition regimes of heterogeneous systems,” Khim. Fiz., 24, No. 2, 82–87 (2005).

    Google Scholar 

  23. A. V. Pivushkov, N. G. Peregudov, and N. G. Samoilenko, “Ignition of a porous fuel under forced filtration of gaseous oxidizer,” in: Abstracts of XIII Symp. on Combustion and Explosion, CD ROM, Chenogolovka, February 7–11 (2005).

  24. Ya. B. Zel’dovich, “Theory of ignition by a hot surface,” Zh. Èksp. Teor. Fiz., 9, No. 12, 1530–1534 (1939).

    Google Scholar 

  25. É. F. Konev, Physical Foundations of Combustion of Vegetative Materials [in Russian], Nauka, Novosibirsk (1977).

    Google Scholar 

  26. E. J. Anthony and D. Greaney, “The safety of hot self heating materials,” Combust. Sci. Technol., No. 1, 79–85 (1979).

    Google Scholar 

  27. R. S. Burkina and V. G. Gorban’, “Effect of diffusion of gaseous oxidizer on the ignition of a reactive porous layer,” in: Physics and Chemistry of High Energy Systems, Proc. Conf., Tomsk Univ., Tomsk (2003), pp. 61–62.

    Google Scholar 

  28. V. G. Prokofev and V. K. Smolyakov “Impact of structural factors on unsteady combustion modes of gasless systems,” Combust., Expl., Shock Waves, 39, No. 2, 167–176 (2003).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to R. S. Burkina.

Additional information

__________

Translated from Fizika Goreniya i Vzryva, Vol. 44, No. 3, pp. 50–60, May–June, 2008.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Burkina, R.S., Prokof’ev, V.G. Critical conditions of thermal explosion of a porous layer. Combust Explos Shock Waves 44, 291–299 (2008). https://doi.org/10.1007/s10573-008-0037-6

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10573-008-0037-6

Key words

Navigation