Abstract
The effect of the addition of Al on the detonation velocity of bis(2,2,2-trinitroethyl) nitramine (BTNEN) was studied experimentally. It is shown that the dependence of the detonation velocity of BTNEN on the initial density is nearly linear, and a 75/25 BTNEN/Al mixture is characterized by an increase in the slope of the dependence with increasing density. The addition of Al decreases the detonation velocity of BTNEN. The density range characterized by a maximum decrease in the detonation velocity is determined. A comparison of experimental detonation velocities of BTNEN/Al mixtures with literature data obtained by calculations taking into account a possible change in the phase state of Al2O3 showed that the thermodynamic model used in the calculations needs to be improved.
Similar content being viewed by others
References
S. B. Victorov, “The effect of Al2O3 phase transitions on detonation properties of aluminized explosives,” in: Proc. of the 12th Int. Detonation Symp., San Diego, August 11–16 (2002), pp. 369–376; http://www.sainc.com/onr/detsymp2002/technicalProgram.htm.
S. B. Victorov, S. A. Gubin, I. V. Maklashova, and I. I. Revyakin, “Thermodynamic TDS code: Application to detonation properties of condensed explosives,” in: Proc. 32nd Annual Conf. of ICT, Karlsruhe, Germany (2001), pp. 69(1–15).
M. F. Gogulya, A. Yu. Dolgoborodov, M. N. Makhov, et al., “Detonation performance of aluminized compositions based on BTNEN,” in: Proc. of the 12th Int. Detonation Symp., San Diego, August 11–16 (2002); pp. 249–255. http://www.sainc.com/onr/detsymp2002/ technicalProgram.htm.
M. F. Gogulya, M. N. Makhov, A. Yu. Dolgoborodov, et al., “Mechanical sensitivity and detonation parameters of aluminized explosives,” Combust., Expl., Shock Waves, 40, No. 4, 445–457 (2004).
M. N. Makhov, M. F. Gogulya, A. Yu. Dolgoborodov, et al., “Acceleration ability and heat of explosive decomposition of aluminized explosives,” Ibid., pp. 458–466.
M. J. Kamlet and H. Hurwitz, “Chemistry of detonations IV. Evaluation of a simple predictional method for detonation velocities of C-H-N-O explosives,” J. Chem. Phys., 48, No. 8, 3685–3692 (1968).
B. P. Zhukov (ed.), Energetic Condensed Systems [in Russian], Yanus, Moscow (2000).
M. A. Cook, A. S. Filler, R. T. Keyes, et al., “Aluminized explosives,” J. Phys. Chem., 61, No. 2, 189–196 (1957).
Author information
Authors and Affiliations
Additional information
__________
Translated from Fizika Goreniya i Vzryva, Vol. 42, No. 4, pp. 125–130, July–August, 2006.
Rights and permissions
About this article
Cite this article
Gogulya, M.F., Makhov, M.N., Brazhnikov, M.A. et al. Detonation velocity of BTNEN/Al. Combust Explos Shock Waves 42, 480–485 (2006). https://doi.org/10.1007/s10573-006-0078-7
Received:
Issue Date:
DOI: https://doi.org/10.1007/s10573-006-0078-7