Skip to main content
Log in

Solubility of Uranium Hexafluoride in Liquid Metal Penta- and Hexafluorides

  • Published:
Atomic Energy Aims and scope

The existence of a linear dependence of the mutual solubility of the higher fluorides of group-V and –VI metals on the atomic number of the solvent metal was established. The solubility of uranium hexafluoride in liquid metal pentafluorides is shown to be a linear function of the parameter α/r 6 of the solvent.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. I. G. Ryss, Chemistry of Fluorine and Its Inorganic Compounds, Goskhimizdat, Moscow (1956).

  2. W. Mears, “Removal of some volatile impurities from uranium hexafluoride,” Ind. Eng. Chem., 50, No. 12, 1771–1773 (1958).

    Article  Google Scholar 

  3. N. S. Nikolaev and A. T. Sadikova, “Solubility of the fluorides of some elements in liquid uranium hexafluoride,” At. Energ., 35, No. 5, 338–343 (1975).

    Google Scholar 

  4. H. Hyman, R. Vogel, and J. Katz, “Purification irradiated reactor fuel by hot methods of fractional distillation using uranium hexafluoride,” in: Chemistry of Nuclear Fuel: Reports by Foreign Scientists at the Int. Conf. on the Peaceful Uses of Atomic Energy, Geneva (1955), GNTI Khim. Lit., Moscow (1955), pp. 189–225.

  5. V. K. Ezhov, “Investigation of the system uranium hexafluoride – antimony pentafluoride,” Zh. Neorg. Khim., 17, No. 7, 2043–2045 (1972).

    Google Scholar 

  6. V. N. Prusakov and V. K. Ezhov, “Phase equilibrium liquid–solid mixture uranium hexafluoride–tungsten hexafluoride,” At. Energ., 25, No. 1, 64–65 (1968).

    Google Scholar 

  7. V. N. Prusakov and V. K. Ezhov, “Phase diagram of the system uranium hexafluoride–niobium pentafluoride,” At. Energ., 28, No. 6, 496–497 (1970).

    Article  Google Scholar 

  8. Chemist’s Handbook, Khimiya, Leningrad (1971), Vol. 1.

  9. B. Weinsnock and G. Goodman, “Vibrational properties of hexafluoride molecules,” Adv. Chem. Phys., 9, 169–172 (1965).

    Google Scholar 

  10. J. Hirshfelder, C. Curtis, and R. Bird, Molecular Theory of Gases and Liquids [Russian translation], Izd. Inostr. Lit., Moscow (1961).

    Google Scholar 

  11. V. K. Ezhov, “Comparative method for calculating the thermodynamic parameters of some uranium hexafluoride chloride solutions,” At. Energ., 120, No. 1, 37–43 (1965).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Atomnaya Énergiya, Vol. 123, No. 3, pp. 141–144, September, 2017.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ezhov, V.K. Solubility of Uranium Hexafluoride in Liquid Metal Penta- and Hexafluorides. At Energy 123, 173–176 (2018). https://doi.org/10.1007/s10512-018-0320-x

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10512-018-0320-x

Navigation