Abstract
A novel environmentally friendly type of scale inhibitor acrylic acid–allylpolyethoxy carboxylate (AQn) was synthesized. The antiscale property of the AQn copolymer towards Ca3(PO4)2 in the artificial cooling water was studied through static scale inhibition tests, The observation shows that Ca3(PO4)2 inhibition increases with increasing the degree of polymerization of AQn from 5 to 15, and the dosage of AQn plays an important role on Ca3(PO4)2 inhibition. The effect on the formation of Ca3(PO4)2 was investigated with combination of scanning electronic microscopy, transmission electron microscopy, X-ray powder diffraction analysis, respectively. Inhibition mechanism is proposed that the interactions between calcium ions and polyethylene glycol are the fundamental impetus to restrain the formation of the scale in cooling water systems.
Similar content being viewed by others
References
Al-Hamzah AA, Fellows CM (2015) A comparative study of novel scale inhibitors with commercial scale inhibitors used in seawater desalination. Desalination 359:22–25
Amjad Z (1989) Constant-composition study of dicalcium phosphatedihydrate crystallite growth in the presence of poly (acrylic acids). Langmuir 5:1222–1225
Can HK, Üner G (2015) Water-soluble anhydride containing alternating copolymers as scale inhibitors. Desalination 355:225–232
Du K, Zhou Y, Wang Y (2009) Fluorescent-tagged no phosphate and nitrogen free calcium phosphate scale inhibitor for cooling water systems. J Appl Polym Sci 113:1966–1974
Fu CE, Zhou YM, Xie HT, Sun W, Wu WD (2010) Double-hydrophilic block copolymers as precipitation inhibitors for calcium phosphate and Iron(III). Ind Eng Chem Res 49:20–8926
Harad A, Kataoka K (2003) Switching by pulse electric field of the elevated enzymatic reaction in the core of polyion complex micelles. J Am Chem Soc 121:15306–15307
Harada A, Kataoka K (2003) Effect of charged segment length on physicochemical properties of core–shell type polyion complex micelles from block ionomers. Macromolecules 36:4995–5001
Huang J, Liu G, Zhou Y, Yao Q, Yang Y, Ling L, Wang H, Cao K, Liu Y, Zhang P, Wu W, Sun W (2013) Acrylic acid–allylpolyethoxy carboxylate copolymer as an environmentally friendly calcium carbonate and iron(III) scale inhibitor. Clean Techn Environ Policy 15:677–685
Kessler SM (2003) Analyses the performance of a next generation phosphate inhibitor for industrial water application. Hydrocarb Eng 8:66–72
Liu Y, Zou C, Li C, Lin L, Chen W (2016) Evaluation of β-cyclodextrin-polyethylene glycol as green scale inhibitors for produced-water in shale gas well. Desalination 377:28–33
Marina P, Emilia O, Amedeo L, Dino M (2009) Gypsum scale control by nitrilotrimethylenephosphonic acid. Ind Eng Chem Res 48:10877–10883
Reddy MM, Nancollas GH (1973) Calcite crystal growth inhibition by phosphonates. Desalination 12:61–73
Rudloff J, Colfen H (2004) Superstructures of temporarily stabilized nanocrystalline CaCO3 particles: morphological control via water surface tension variation. Langmuir 20:991–996
Saleah AO, Basta AH (2008) Evaluation of some organic-based biopolymers as green inhibitors for calcium sulfate scales. Environmentalist 28:421–428
Senthilmurugan B, Ghosh B, Sanker S (2011) High performance maleic acid based oil well scale inhibitors: development and comparative evaluation. J Ind Eng Chem 17:415–420
Suharso B, Syaiful B, Teguh E (2011) Gambier extracts as an inhibitor of calcium carbonate (CaCO3) scale formation. Desalination 265:102–106
Yanovska A, Kuznetsov V, Stanislavov A, Danilchenko S, Danilchenko L (2012) Synthesis and characterization of hydroxyapatite based coatings for medical implants obtained on chemically modified Ti6Al4V substrates. Mat Sci Eng 32:883–1887
Yu S, Colfen H, Antonietti M (2003) Polymer-controlled morphosynthesis and mineralization of metal carbonate superstructures. J Phys Chem B 107:7396–7405
Zhang B, Zhang L, Hannam PM (2010) Testing the formation of Ca–phosphonate precipitates and evaluating the anionic polymers as Ca–phosphonate precipitates and CaCO3 scale inhibitor in simulated cooling water. Corros Sci 52:3883–3890
Zhang H, Luo X, Lin X, Tang P, Lu X, Yang M, Tang Y (2016) Biodegradable carboxymethyl inulin as a scale inhibitor for calcite crystal growth: molecular level understanding. Desalination 381:1–7
Acknowledgments
The National Natural Science Foundation of China (No. 51077013), China Postdoctoral Science Foundation (No. 2014M560381), Jiangsu Planned Projects for Postdoctoral Research Funds (No. 1401033B), The Project of Young Scientist Foundation of Nanjing Xiaozhuang University (No. 2013NXY89). The Municipal Key Subjects of Environmental Science and Engineering, Nanjing Xiaozhuang University, Nanjing. University Student Technology Innovation Project of Jiangsu Province (No. 201611460008Z). University Student Technology Innovation Project of Jiangsu Province (School-enterprise cooperation) (201611460085H).
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
About this article
Cite this article
Liu, G., Xue, M., Liu, Q. et al. Acrylic acid–allylpolyethoxy carboxylate copolymer as a environmentally friendly scale inhibitor (part II). Clean Techn Environ Policy 19, 917–924 (2017). https://doi.org/10.1007/s10098-016-1258-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10098-016-1258-0