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Nano oxides incorporated sulfonated poly(ether ether ketone) membranes with improved selectivity and stability for vanadium redox flow battery

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Abstract

Three kinds of sulfonated poly(ether ether ketone) (SPEEK)/nano oxide (Al2O3, SiO2, and TiO2) composite membranes are fabricated for vanadium redox flow battery (VRFB) application. The composite membranes with 5 wt% of Al2O3, SiO2, and TiO2 (S/A-5 %, S/S-5 %, and S/T-5 %) exhibit excellent cell performance in VRFB. Incorporation of nano oxides (Al2O3, SiO2, and TiO2) in SPEEK membrane improves in aspect of thermal, mechanical, and chemical stabilities due to the hydrogen bonds’ interaction between SPEEK matrix and nano oxides. The energy efficiencies (EEs) of composite membranes are higher than that of Nafion 117 membrane, owing to the good balance between proton conductivity and vanadium ion permeability. The discharge–capacity retentions of composite membranes also overwhelm that of Nafion 117 membrane after 200 cycles, indicating their good stability in VRFB system. These low-cost SPEEK/nano oxide composite membranes exhibit great potential for the application in VRFB.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (21576154), Natural Science Foundation of Guangdong Province (2015A030313894), and Basic Research Project of Shenzhen City (JCYJ20130402145002403 and JCYJ20150331151358143).

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Authors and Affiliations

  1. Institute of Green Chemistry and Energy, Graduate School at Shenzhen, Tsinghua University, Shenzhen, 518055, China

    Bibo Yin, Bo Jiang & Jingyu Xi

  2. Shenzhen Key Laboratory of Special Functional Materials, College of Materials Science and Engineering, Shenzhen University, Shenzhen, 518060, China

    Bibo Yin & Lei Wang

  3. School of Applied Chemistry and Biological Technology, Shenzhen Polytechnic, Shenzhen, 518055, China

    Lihong Yu

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  1. Bibo Yin
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  2. Lihong Yu
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  3. Bo Jiang
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  4. Lei Wang
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Correspondence to Lei Wang or Jingyu Xi.

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Yin, B., Yu, L., Jiang, B. et al. Nano oxides incorporated sulfonated poly(ether ether ketone) membranes with improved selectivity and stability for vanadium redox flow battery. J Solid State Electrochem 20, 1271–1283 (2016). https://doi.org/10.1007/s10008-016-3121-y

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  • DOI: https://doi.org/10.1007/s10008-016-3121-y

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